The technology of drilling tests makes it possible to obtain the strength parameter of rock accurately in situ. In this paper, a new rock cutting analysis model that considers the influence of the rock crushing zone(R...The technology of drilling tests makes it possible to obtain the strength parameter of rock accurately in situ. In this paper, a new rock cutting analysis model that considers the influence of the rock crushing zone(RCZ) is built. The formula for an ultimate cutting force is established based on the limit equilibrium principle. The relationship between digital drilling parameters(DDP) and the c-φ parameter(DDP-cφ formula, where c refers to the cohesion and φ refers to the internal friction angle) is derived, and the response of drilling parameters and cutting ratio to the strength parameters is analyzed. The drillingbased measuring method for the c-φ parameter of rock is constructed. The laboratory verification test is then completed, and the difference in results between the drilling test and the compression test is less than 6%. On this basis, in-situ rock drilling tests in a traffic tunnel and a coal mine roadway are carried out, and the strength parameters of the surrounding rock are effectively tested. The average difference ratio of the results is less than 11%, which verifies the effectiveness of the proposed method for obtaining the strength parameters based on digital drilling. This study provides methodological support for field testing of rock strength parameters.展开更多
Deep underground projects(e.g., coal mines), are often faced with complex conditions such as high stress and extremely soft rock. The strength and rigidity of the traditional support system are often insufficient,whic...Deep underground projects(e.g., coal mines), are often faced with complex conditions such as high stress and extremely soft rock. The strength and rigidity of the traditional support system are often insufficient,which makes it difficult to meet the requirements of ground control under complex conditions. As a new support form with high strength and rigidity, the confined concrete arch plays an important role in controlling the rock deformation under complex conditions. The section shape of the tunnel has an important impact on the mechanical properties and design of the support system. However, studies on the mechanical properties and influence mechanism of the new confined concrete arch are rarely reported. To this end, the mechanical properties of traditional U-shaped steel and new confined concrete arches are compared and comparative tests on arches of circular and straight-leg semicircular shapes in deep tunnels are conducted. A large mechanical testing system for underground engineering support structure is developed. The mechanical properties and influence mechanism of confined concrete arches with different section shapes under different loading modes and cross-section parameters are systematically studied. Test results show that the bearing capacity of the confined concrete arch is 2.10 times that of the U-shaped steel arch, and the bearing capacity of the circular confined concrete arch is 2.27 times that of the straight-leg semicircular arch. Among the various influencing factors and their engineering parameters,the lateral stress coefficient has the greatest impact on the bearing capacity of the confined concrete arch,followed by the steel pipe wall thickness, steel strength, and core concrete strength. Subsequently, the economic index of bearing capacity and cost is established, and the optimization design method for the confined concrete arch is proposed. Finally, this design method is applied to a high-stress tunnel under complex conditions, and the deformation of the surrounding rock is effectively controlled.展开更多
Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient...Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient approach to construct a bifunctional oxygen reduction reaction(ORR)/oxygen evolution reaction(OER)electrocatalyst composed of N-doped porous carbon nanosheet flowers decorated with Fe Co nanoparticles(Fe Co/N-CF).Rational design of this catalyst is achieved by designing Schiff-base polymer with unique molecular structure via hydrogen bonding of cyanuramide and terephthalaldehyde polycondensate in the presence of metal cations.It exhibits excellent activity and stability for electrocatalysis of ORR/OER,enabling ZAB with a high peak power density of 172 m W cm^(-2)and a large specific capacity of 811 m A h g^(-1)Znat large current.The rechargeable ZAB demonstrates excellent durability for 1000 h with slight voltage decay,far outperforming a couple of precious Pt/Ir-based catalysts.Density functional theory(DFT)calculations reveal that high activity of bimetallic Fe Co stems from enhanced O_(2)and OH-adsorption and accelerated O_(2)dissociation by OAO bond activation.展开更多
The changes in the mechanical properties of collapsing walls under the influence of natural factors in the hilly area of southern China need to be determined.We systematically studied the influence of the interaction ...The changes in the mechanical properties of collapsing walls under the influence of natural factors in the hilly area of southern China need to be determined.We systematically studied the influence of the interaction of dry densityρ(1.0,1.1,1.2,1.3,1.4 g/cm3)and moisture content w(0.05,0.1,0.15,0.2,0.25 g/g)on the stability of four soil layers in a collapsing wall.The soil cohesion decreased with increasing soil depth.The cohesion force initially increased and then decreased with increasingωand increased with increasingρ;the internal friction angle was mainly affected byωand decreased with increasingω.The cohesion could be used to effectively characterize the stability of the collapsing wall.The shear strength index was modeled based on interaction between the dry density and moisture content(R2>0.95).The optimal combination of moisture content and dry density was obtained,and the collapsing wall was in the most stable state at a moisture content of 0.12-0.19 g/g and a dry density of 1.40 g/cm3.Based on the analysis of the critical height and safety factor(FS),the FS values of the sandy layer(C)was 0.53 and 0.57 forωvalues of 0.25 g/g and 0.05 g/g,respectively.In the alternating process of soil wetting and drying,the basic properties of the soil changed;caused traceback erosion,and thereby affected the stability of the collapsing wall.Our study provides a theoretical basis for the investigation of the factors influencing the stability of collapsing walls.展开更多
A permanent collapsing gully,locally called Benggang,formed on slopes with deep granite red soil and is a type of unique gully erosion widely prevalent in southern China.Three different soil configurations(SC),ie,red-...A permanent collapsing gully,locally called Benggang,formed on slopes with deep granite red soil and is a type of unique gully erosion widely prevalent in southern China.Three different soil configurations(SC),ie,red-transition-sandy(SC I,the transition is the soil layer between the red soil and the sandy soil layer),transition-sandy(SC II)or sandy(SC III)are usually present in the soil profile of the Benggang slope.However,little attention has been paid to impacts of SCs on the triggering of Benggang erosion.In this study,we aimed to explore the relationships between soil water content(SWC)and triggering of Benggang erosion under different SC conditions.The soil properties of different soil layers were measured and the SWC at depths of 20,40,60,and 80 cm were monitored at 5-min intervals along a typical Benggang(SC I)during 2016-2018.The SWC of Benggang slopes with different SCs were simulated by VADOSE/W model.Results showed that the red soil layer had a higher water retention capacity and shear strength than the sandy soil layer.Even if the SWC is higher(e.g.,0.42 cm^(3)/cm^(3))at red soil layer or transition layer,the corresponding shear strength is greater than that of sandy soil layer with a lower SWC(e.g.,032 cm^(3)/cm^(3)).Relationships between shear strength and SWC of different soil layers indicate that Benggang erosion is triggered by an increase in the SWC in the deep sandy layer.Results also showed that differences exist in the SWC distribution among the different SCs.The SWC is higher in topsoil than in deeper soil in SC I and SC II,while in SC III,the opposite trend is observed.These results revealed that the presence of the red soil or transition layer can reduce the infiltration of rainwater into the deep sandy layer,thus can reduce the possibility of collapse.Our results show that the SC affects the stability of the headwall,and results provide great significances to guide the mitigation of Benggang erosion.展开更多
This study focuses on the collapsing gullies in tuffaceous sandstone area and investigates the slope di-rection and morphological characteristics of the main and branch gullies. Furthermore, we assess the structural c...This study focuses on the collapsing gullies in tuffaceous sandstone area and investigates the slope di-rection and morphological characteristics of the main and branch gullies. Furthermore, we assess the structural characteristics of the rock joints within this area, including their strike, dip direction and dip angle. The results show that there are 405 collapsing gullies in the study area. The slope directions associated with collapsing gullies and the directions of the main gullies largely fall within the ranges of NE20°-NE90°, SE90°-SE160°, SW240°-SW270°, and NW270°-NW290°. The collapsing gullies include 1103 branch gullies in total, most of which have directions that fall within the ranges of NE20°-NE40°, NE50°-NE70°, NW280°-NW300°, and NW330°-NW350°. The joints in the bedrock are directional and regional, and they can be divided into two main groups. The number of southward dip directions is greater than the number of northward dip directions, and most of the measured dip angles are greater than 60°. The mean dip angle is greatest for joints with measured strike values of NW280°-NW290°, with a value of 85.2°. The development of collapse gullies is affected by both the slope direction and joints. The slope direction determines the direction of the main gullies, with a correlation coefficient of 0.809 (P<0.01). The branch gullies are mainly affected by joints, with a correlation coefficient of 0.876 (P<0.01). The joint structure also influences the degree of development of the collapsing gullies, and the average depth of the gullies that parallel the dominant joint orientation is significantly larger than that of gullies with other directions. Moreover, the average depth of the gullies associated with the dip angle of 85.2° measured relative to the joint strike is 6.89 m, which is significantly greater than that associated with lower dip angles. The dip angles of joints have an important effect on the infiltration of water, and high dip angles accelerate the erosion associated with collapsing gullies.展开更多
基金supported by the National Key Research and Development Program of China(No.2023YFC2907600)the National Natural Science Foundation of China(Nos.42077267,42277174 and 52074164)+2 种基金the Natural Science Foundation of Shandong Province,China(No.ZR2020JQ23)the Opening Project of State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology(No.KFJJ21-02Z)the Fundamental Research Funds for the Central Universities,China(No.2022JCCXSB03).
文摘The technology of drilling tests makes it possible to obtain the strength parameter of rock accurately in situ. In this paper, a new rock cutting analysis model that considers the influence of the rock crushing zone(RCZ) is built. The formula for an ultimate cutting force is established based on the limit equilibrium principle. The relationship between digital drilling parameters(DDP) and the c-φ parameter(DDP-cφ formula, where c refers to the cohesion and φ refers to the internal friction angle) is derived, and the response of drilling parameters and cutting ratio to the strength parameters is analyzed. The drillingbased measuring method for the c-φ parameter of rock is constructed. The laboratory verification test is then completed, and the difference in results between the drilling test and the compression test is less than 6%. On this basis, in-situ rock drilling tests in a traffic tunnel and a coal mine roadway are carried out, and the strength parameters of the surrounding rock are effectively tested. The average difference ratio of the results is less than 11%, which verifies the effectiveness of the proposed method for obtaining the strength parameters based on digital drilling. This study provides methodological support for field testing of rock strength parameters.
基金supported by the National Natural Science Foundation of China (Nos. 42277174, 42077267, and 52074164)the Natural Science Foundation of Shandong Province, China (No. ZR2020JQ23)+2 种基金Major Scientific and Technological Innovation Project of Shandong Province, China (No. 2019SDZY04)the Project of Shandong Province Higher Educational Youth Innovation Science and Technology Program, China (No. 2019KJG013)the opening project of State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology (No. KFJJ21-02Z)。
文摘Deep underground projects(e.g., coal mines), are often faced with complex conditions such as high stress and extremely soft rock. The strength and rigidity of the traditional support system are often insufficient,which makes it difficult to meet the requirements of ground control under complex conditions. As a new support form with high strength and rigidity, the confined concrete arch plays an important role in controlling the rock deformation under complex conditions. The section shape of the tunnel has an important impact on the mechanical properties and design of the support system. However, studies on the mechanical properties and influence mechanism of the new confined concrete arch are rarely reported. To this end, the mechanical properties of traditional U-shaped steel and new confined concrete arches are compared and comparative tests on arches of circular and straight-leg semicircular shapes in deep tunnels are conducted. A large mechanical testing system for underground engineering support structure is developed. The mechanical properties and influence mechanism of confined concrete arches with different section shapes under different loading modes and cross-section parameters are systematically studied. Test results show that the bearing capacity of the confined concrete arch is 2.10 times that of the U-shaped steel arch, and the bearing capacity of the circular confined concrete arch is 2.27 times that of the straight-leg semicircular arch. Among the various influencing factors and their engineering parameters,the lateral stress coefficient has the greatest impact on the bearing capacity of the confined concrete arch,followed by the steel pipe wall thickness, steel strength, and core concrete strength. Subsequently, the economic index of bearing capacity and cost is established, and the optimization design method for the confined concrete arch is proposed. Finally, this design method is applied to a high-stress tunnel under complex conditions, and the deformation of the surrounding rock is effectively controlled.
基金supported by the National Science Foundation of China(21805235)the Opening Foundation of Creative Platform of the Key Laboratory of the Education Department of Hunan Province(20K131)the Construct Program of the Key Discipline in Hunan Province。
文摘Rational design and exploration of low-cost and robust bifunctional oxygen electrocatalysts are vitally important for developing high-performance zinc-air batteries(ZABs).Herein,we reported a facile yet cost-efficient approach to construct a bifunctional oxygen reduction reaction(ORR)/oxygen evolution reaction(OER)electrocatalyst composed of N-doped porous carbon nanosheet flowers decorated with Fe Co nanoparticles(Fe Co/N-CF).Rational design of this catalyst is achieved by designing Schiff-base polymer with unique molecular structure via hydrogen bonding of cyanuramide and terephthalaldehyde polycondensate in the presence of metal cations.It exhibits excellent activity and stability for electrocatalysis of ORR/OER,enabling ZAB with a high peak power density of 172 m W cm^(-2)and a large specific capacity of 811 m A h g^(-1)Znat large current.The rechargeable ZAB demonstrates excellent durability for 1000 h with slight voltage decay,far outperforming a couple of precious Pt/Ir-based catalysts.Density functional theory(DFT)calculations reveal that high activity of bimetallic Fe Co stems from enhanced O_(2)and OH-adsorption and accelerated O_(2)dissociation by OAO bond activation.
基金the financial support for the Special Projects of the Central Government Guiding Local Science and Technology Development in China(Guike.ZY21195022)the research provided by Guangxi Natural Science Foundation(2021GXNSFBA075017)+1 种基金the National Natural Science Foundation of China(No.42007055 and 42107350)the Guangxi Training Program of Innovation and Entrepreneurship for Undergraduates(No.S202210593236).
文摘The changes in the mechanical properties of collapsing walls under the influence of natural factors in the hilly area of southern China need to be determined.We systematically studied the influence of the interaction of dry densityρ(1.0,1.1,1.2,1.3,1.4 g/cm3)and moisture content w(0.05,0.1,0.15,0.2,0.25 g/g)on the stability of four soil layers in a collapsing wall.The soil cohesion decreased with increasing soil depth.The cohesion force initially increased and then decreased with increasingωand increased with increasingρ;the internal friction angle was mainly affected byωand decreased with increasingω.The cohesion could be used to effectively characterize the stability of the collapsing wall.The shear strength index was modeled based on interaction between the dry density and moisture content(R2>0.95).The optimal combination of moisture content and dry density was obtained,and the collapsing wall was in the most stable state at a moisture content of 0.12-0.19 g/g and a dry density of 1.40 g/cm3.Based on the analysis of the critical height and safety factor(FS),the FS values of the sandy layer(C)was 0.53 and 0.57 forωvalues of 0.25 g/g and 0.05 g/g,respectively.In the alternating process of soil wetting and drying,the basic properties of the soil changed;caused traceback erosion,and thereby affected the stability of the collapsing wall.Our study provides a theoretical basis for the investigation of the factors influencing the stability of collapsing walls.
基金Financial support for this research was provided by the National Natural Science Foundation of China(No.41571258,42007055 and 41630858).
文摘A permanent collapsing gully,locally called Benggang,formed on slopes with deep granite red soil and is a type of unique gully erosion widely prevalent in southern China.Three different soil configurations(SC),ie,red-transition-sandy(SC I,the transition is the soil layer between the red soil and the sandy soil layer),transition-sandy(SC II)or sandy(SC III)are usually present in the soil profile of the Benggang slope.However,little attention has been paid to impacts of SCs on the triggering of Benggang erosion.In this study,we aimed to explore the relationships between soil water content(SWC)and triggering of Benggang erosion under different SC conditions.The soil properties of different soil layers were measured and the SWC at depths of 20,40,60,and 80 cm were monitored at 5-min intervals along a typical Benggang(SC I)during 2016-2018.The SWC of Benggang slopes with different SCs were simulated by VADOSE/W model.Results showed that the red soil layer had a higher water retention capacity and shear strength than the sandy soil layer.Even if the SWC is higher(e.g.,0.42 cm^(3)/cm^(3))at red soil layer or transition layer,the corresponding shear strength is greater than that of sandy soil layer with a lower SWC(e.g.,032 cm^(3)/cm^(3)).Relationships between shear strength and SWC of different soil layers indicate that Benggang erosion is triggered by an increase in the SWC in the deep sandy layer.Results also showed that differences exist in the SWC distribution among the different SCs.The SWC is higher in topsoil than in deeper soil in SC I and SC II,while in SC III,the opposite trend is observed.These results revealed that the presence of the red soil or transition layer can reduce the infiltration of rainwater into the deep sandy layer,thus can reduce the possibility of collapse.Our results show that the SC affects the stability of the headwall,and results provide great significances to guide the mitigation of Benggang erosion.
基金Financial support for this research was provided by the National Natural Science Foundation of China(41630858)the Na-tional Key Research and Development Program of China(2017YFC0505402)
文摘This study focuses on the collapsing gullies in tuffaceous sandstone area and investigates the slope di-rection and morphological characteristics of the main and branch gullies. Furthermore, we assess the structural characteristics of the rock joints within this area, including their strike, dip direction and dip angle. The results show that there are 405 collapsing gullies in the study area. The slope directions associated with collapsing gullies and the directions of the main gullies largely fall within the ranges of NE20°-NE90°, SE90°-SE160°, SW240°-SW270°, and NW270°-NW290°. The collapsing gullies include 1103 branch gullies in total, most of which have directions that fall within the ranges of NE20°-NE40°, NE50°-NE70°, NW280°-NW300°, and NW330°-NW350°. The joints in the bedrock are directional and regional, and they can be divided into two main groups. The number of southward dip directions is greater than the number of northward dip directions, and most of the measured dip angles are greater than 60°. The mean dip angle is greatest for joints with measured strike values of NW280°-NW290°, with a value of 85.2°. The development of collapse gullies is affected by both the slope direction and joints. The slope direction determines the direction of the main gullies, with a correlation coefficient of 0.809 (P<0.01). The branch gullies are mainly affected by joints, with a correlation coefficient of 0.876 (P<0.01). The joint structure also influences the degree of development of the collapsing gullies, and the average depth of the gullies that parallel the dominant joint orientation is significantly larger than that of gullies with other directions. Moreover, the average depth of the gullies associated with the dip angle of 85.2° measured relative to the joint strike is 6.89 m, which is significantly greater than that associated with lower dip angles. The dip angles of joints have an important effect on the infiltration of water, and high dip angles accelerate the erosion associated with collapsing gullies.