Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [RF-(CH2CHSi(OMe)3)n-RF;RF = CF(CF3)OCF7, n = 2, 3;RF-(VM)n-RF] was applied to the preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α-, β-, ...Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [RF-(CH2CHSi(OMe)3)n-RF;RF = CF(CF3)OCF7, n = 2, 3;RF-(VM)n-RF] was applied to the preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α-, β-, γ-cyclodextrin polymers (α-, β-, γ-CDPs) composites [RF-(VM-SiO2)n-RF/α-, β-, γ-CDPs] by the sol-gel reaction of the corresponding oligomer in the presence of the α-, β-, γ-CDPs under alkaline conditions. The RF-(VM-SiO2)n-RF/α-, β-, γ-CDPs composites thus obtained were found to give a good dispersibility toward the traditional organic media except for water, and were applied to the surface modification of glass to provide a sueperoleophilic/superhydrophobic characteristic on the modified surface, although the corresponding RF-(VM-SiO2)n-RF nanocomposites can give a usual oleophobic/superhydrophobic property on the surface. These composites powders were also found to be applicable to the packing material for the column chromatography to separate the mixture of oil/water and the water in oil (W/O) emulsions. More interestingly, these composite powders were found to have a higher adsorption ability toward not only low-molecular weight aromatic compounds such as bisphenol A and bisphenol AF but also volatile organic compounds, compared to that of the pristine α-, β-, γ-CDPs.展开更多
文摘Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [RF-(CH2CHSi(OMe)3)n-RF;RF = CF(CF3)OCF7, n = 2, 3;RF-(VM)n-RF] was applied to the preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomer/α-, β-, γ-cyclodextrin polymers (α-, β-, γ-CDPs) composites [RF-(VM-SiO2)n-RF/α-, β-, γ-CDPs] by the sol-gel reaction of the corresponding oligomer in the presence of the α-, β-, γ-CDPs under alkaline conditions. The RF-(VM-SiO2)n-RF/α-, β-, γ-CDPs composites thus obtained were found to give a good dispersibility toward the traditional organic media except for water, and were applied to the surface modification of glass to provide a sueperoleophilic/superhydrophobic characteristic on the modified surface, although the corresponding RF-(VM-SiO2)n-RF nanocomposites can give a usual oleophobic/superhydrophobic property on the surface. These composites powders were also found to be applicable to the packing material for the column chromatography to separate the mixture of oil/water and the water in oil (W/O) emulsions. More interestingly, these composite powders were found to have a higher adsorption ability toward not only low-molecular weight aromatic compounds such as bisphenol A and bisphenol AF but also volatile organic compounds, compared to that of the pristine α-, β-, γ-CDPs.
文摘Fluoroalkyl end-capped vinyltrimethoxysilane-<i><span style="font-family:Verdana;">N</span></i><span><span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i></span><span style="font-family:Verdana;">-dimethylacrylamide cooli</span><span style="font-family:;" "=""><span style="font-family:Verdana;">gomer [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(CH</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">-CHSi(OMe)</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(CH</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">-CHC(=O)NMe</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">;R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;"> = CF(CF</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">)OC</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">F</span><sub><span style="font-family:Verdana;">7</span></sub><span style="font-family:Verdana;">:</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;"> R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] was synthesized by reaction of fluoroalkanoyl peroxide [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-C(=O)O-O(O=)C-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] with vinyltrimethoxysilane (VM) and </span><i><span style="font-family:Verdana;">N</span></i><span><span style="font-family:Verdana;">,</span><i><span style="font-family:Verdana;">N</span></i></span><span style="font-family:Verdana;">-</span></span><span style="font-family:Verdana;">dimethylacrylamide (DMAA). The modified glass surface treated with the</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> cooligomeric nanoparticles [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] prepared under the sol-gel reaction of the cooligomer under alkaline conditions was found to exhibit an oleophobic/superhydrophilic property, although the corresponding fluorinated homooligomeric nanoparticles [R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">] afforded an </span><span style="font-family:Verdana;">oleophobic/hydrophobic property on the modified surface under similar </span><span style="font-family:Verdana;">con</span><span><span style="font-family:Verdana;">ditions. R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/</span><b><i><span style="font-family:Verdana;">PSt</span></i></b><span style="font-family:Verdana;"> (micro-sized</span></span> <span style="font-family:Verdana;">polystyrene particles) composites, which were prepared by the sol-gel reac</span><span style="font-family:Verdana;">tions of the corresponding homooligomer and cooligomer in the presence of </span><b><i><span style="font-family:Verdana;">PSt </span></i></b><span style="font-family:Verdana;">particle under alkaline conditions, provided an oleophobic/superhydrophilic </span><span style="font-family:Verdana;">property on the modified surface. However, it was demonstrated that the</span><span><span style="font-family:Verdana;"> surface wettability on the modified surface treated with the R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-</span></span><span><span style="font-family:Verdana;">SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM-SiO</span><sub><span style="font-family:Verdana;">3/2</span></sub><span style="font-family:Verdana;">)</span><i><sub><span style="font-family:Verdana;">x</span></sub></i><span style="font-family:Verdana;">-(DMAA)</span><i><sub><span style="font-family:Verdana;">y</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">/</span><b><i><span style="font-family:Verdana;">PSt</span></i></b><span style="font-family:Verdana;"> composites changes dramatically from oleophobic/superhydrophilic to superoleophilic/superhydrophilic </span><span style="font-family:Verdana;">and superoleophilic/superhydrophobic characteristics, increasing with </span><span style="font-family:Verdana;">greater </span><span><span style="font-family:Verdana;">feed ratios (mg/mg) of the R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;">-(VM)</span><i><sub><span style="font-family:Verdana;">n</span></sub></i><span style="font-family:Verdana;">-R</span><sub><span style="font-family:Verdana;">F</span></sub><span style="font-family:Verdana;"> homooligomer in homooligo</span></span><span style="font-family:Verdana;">mer/cooligo</span></span><span style="font-family:Verdana;">mer from 0 to 100 in the preparation of the composites. Such controlled surfac</span>