Improvement the Corrosion Resistance for the Galvanized Steel by Adding Sn

The chemical composition of the zinc bath can strongly influence on the hot-dip galvanized coatings. In this work, the effects of tin addition on the surface morphology, and the corrosion resistance of hot-dip galvanized steel were investigated. The corrosion behavior of steel samples galvanized with zinc and Zn-Sn alloys containing different wt% Sn was analyzed by various corrosion tests such as potentiodynamic polarization Tafel lines and electrochemical impedance spectroscopy (EIS) techniques. Salt spray test was employed in order to study the corrosion products of the specimens. Surface morphology, the composition of coating layers and nature of the corrosion products were also investigated using field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray analysis (EDX) and X-Ray diffraction (XRD) techniques, respectively. The results indicated that the addition of small amounts of Sn (0.1 wt%) to the molten zinc galvanizing bath can improve the corrosion resistance of hot-dip galvanized steel.

碳电极上电沉积的Ni–MgO纳米复合物催化甲醇和乙醇电氧化反应（英文）

在细小MgO增强颗粒的存在下,采用电沉积法在碳阳极上经瓦特镍制得Ni–MgO纳米复合物,考察了它在碱性介质中电催化氧化甲醇和乙醇反应性能,并与碳涂覆的纯Ni催化剂(Ni/C)性能进行了比较.运用能量散射谱、X射线衍射和扫描电镜分别表征了沉积的纳米复合物的化学组成、相结构和表面形貌,并采用循环伏安法(CV)、计时电流法和电化学阻抗谱(EIS)等电化学技术考察了所制电催化剂阳极的催化活性.结果表明,Ni/C催化剂在电氧化反应中表现出很低的催化活性和稳定性,而MgO的引入显著增加了Ni催化剂在醇氧化反应中的催化活性和抗中毒性能.EIS和CV结果证实Ni–MgO/C纳米复合物电极具有比Ni/C更低的电荷转移阻力和更高的抗中毒性能.