精选“三特色”素材推进“有机化学”课程思政

当前在“有机化学”中开展课程思政已卓有成效,但教学中存在素材不丰富、缺乏新鲜感、学生审美疲劳、师生共鸣性差等困扰。为解决这些问题,提出了与时俱进,选择具有学校特色、本地特色、时代特色的思政素材,打造特色课堂。分享了在教学实践中的三个典型案例。教学实践表明,学生对“三特色”素材接受度高,反响较好。该方法有助于增强学生的主人翁意识,强化学生的教学主体观念,增强学生的课堂参与性,有利于深入推进课程思政。

Novel Substitution Reactions of 5-(4-Nitrophenyl)-10,15,20-Triphenyl- Porphyrin with Nucleophilic Reagents

Substitution reactions of 5-（4-nitrophenyl）-10, 15,20-triphenylporphyrin （NO2 TPP） and its metal complexes with different nucleophilic reagents were studied for preparing asymmetric porphyrin. The reaction products are different with the nucleophilic reagents changing, and three different products were found. The first obtaining product was diporphyrin when NO2 TPP reacted with sodium phenoxide or diphenoxide in DMF solution; The second was reduced product 5-（4-aminophenyl）-10, 15, 20-triphenylporphrin-M （Ⅱ） when the metal （Ni,Zn） complex of NO2 TPP reacted with above nucleophilic reagents, as well as NO2 TPP reacted with lithium mercaptoethanolate or lithium thiophenolate; The third product CNTPP was achieved with the substitution of nitro group by cyanic anion when NO2 TPP reacted with radium cyanide. Above results were explained with reduction and single electron transfer reaction respectively.

浅谈有机化学课堂教学中生活艺术的运用

本文着眼于在有机化学课堂教学中引入生活中的艺术,以达到加深学生对生涩难懂的知识点的理解,增加课堂教学的趣味性,提高课堂教学的效率和效果的目的。重点阐述了该过程的实施模式,并用具有良好教学效果的实例对该过程做了详细说明,旨在提出新的课堂教学实施过程,供教学工作者探讨,共同为提高课堂教学的质量出谋划策。