Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces. The structure of the multi-laye...Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces. The structure of the multi-layer coatings was characterized by XRD and SEM analyses. High temperature oxidation behavior of the multi-layer coatings coated C/C composites was investigated. Results show that SiC/2SiO2 Y2O3/1.5SiO2 Y203/ SiO2 Y2O3/glass multi-layer coating has better high temperature oxidation resistance, protecting carbon/ carbon composites from oxidation at 1 773 K in air for 164 h with the weight loss of 1.65%. The oxidation weight loss of the coated C/C with time accorded with parabolic rule in the temperature range 1 573 K-1 873 K; and the corresponding oxidation activation energy of the coated carbon/carbon composites is 132.2 kJ/mol.展开更多
The thermal fatigue behavior of C/C composites coated with the SiC/MBAS glass (MoSi2 particle-containing boron aluminosilicate glass) coating, prepared by the two-step process of the pack cementation and procoating-si...The thermal fatigue behavior of C/C composites coated with the SiC/MBAS glass (MoSi2 particle-containing boron aluminosilicate glass) coating, prepared by the two-step process of the pack cementation and procoating-sintering, was investigated in present paper. The experimental results indicated that the SiC/MBAS glass coating had an excellent thermal shock resistance in air at temperature up to 1873 K. During quick thermal cycle between 1873K and room temperature in air, the decrease of mass and mechanical property of the coated C/C composites was all slight. After thermal cycle for 50 times, the mass loss of the SiC/MBAS glass coated sample was only 0.22%; additionally, the remaining ratio of strength and modulus was no less than 95.2% and 99.4%, respectively. The decrease of the mechanical property during the thermal cycle was primarily due to the damnification of the fiber/matrix interfaces and the oxidation of the coated samples with oxygen.展开更多
One of the most important factors that limits the use of LiFePO 4 as cathode material for lithium ion batteries is its low electronic conductivity.In order to solve this problem,LiFePO 4 in situ vapor-grown carbon fib...One of the most important factors that limits the use of LiFePO 4 as cathode material for lithium ion batteries is its low electronic conductivity.In order to solve this problem,LiFePO 4 in situ vapor-grown carbon fiber (VGCF) composite cathode material has been prepared in a single step through microwave pyrolysis chemical vapor deposition.The phase,microstructure,and electrochemical performance of the composites were investigated.Compared with the cathodes without in situ VGCF,the initial discharge capacity of the composite electrode increases from 109 to 144 mA h g-1 at a 0.5-C rate,and the total electric resistance decreases from 538 to 66.The possible reasons for these effects are proposed.展开更多
基金Supported by National Natural Science Foundation of China(No.50772063)the Program for New Century Excellent Talents in University(No.NCET-06-0893)
文摘Different compositions of yttrium silicates coatings were deposited on SiC-C/C by plasma spraying and an outer borosilicate glass was applied on the yttrium silicates coatings surfaces. The structure of the multi-layer coatings was characterized by XRD and SEM analyses. High temperature oxidation behavior of the multi-layer coatings coated C/C composites was investigated. Results show that SiC/2SiO2 Y2O3/1.5SiO2 Y203/ SiO2 Y2O3/glass multi-layer coating has better high temperature oxidation resistance, protecting carbon/ carbon composites from oxidation at 1 773 K in air for 164 h with the weight loss of 1.65%. The oxidation weight loss of the coated C/C with time accorded with parabolic rule in the temperature range 1 573 K-1 873 K; and the corresponding oxidation activation energy of the coated carbon/carbon composites is 132.2 kJ/mol.
基金the National Natural Science Foundation of China (No. 50672059)the China Postdoctoral Science Foundation funded Project (No. 20070420771)+1 种基金the Project of 2007 Non-common-understanding Innovation on Sci-Technology of Shenzhen in China (natural person)the Project 200703 supported by SZU R/D Fund
文摘The thermal fatigue behavior of C/C composites coated with the SiC/MBAS glass (MoSi2 particle-containing boron aluminosilicate glass) coating, prepared by the two-step process of the pack cementation and procoating-sintering, was investigated in present paper. The experimental results indicated that the SiC/MBAS glass coating had an excellent thermal shock resistance in air at temperature up to 1873 K. During quick thermal cycle between 1873K and room temperature in air, the decrease of mass and mechanical property of the coated C/C composites was all slight. After thermal cycle for 50 times, the mass loss of the SiC/MBAS glass coated sample was only 0.22%; additionally, the remaining ratio of strength and modulus was no less than 95.2% and 99.4%, respectively. The decrease of the mechanical property during the thermal cycle was primarily due to the damnification of the fiber/matrix interfaces and the oxidation of the coated samples with oxygen.
基金supported by the National Natural Science Foundation of China (50672059)
文摘One of the most important factors that limits the use of LiFePO 4 as cathode material for lithium ion batteries is its low electronic conductivity.In order to solve this problem,LiFePO 4 in situ vapor-grown carbon fiber (VGCF) composite cathode material has been prepared in a single step through microwave pyrolysis chemical vapor deposition.The phase,microstructure,and electrochemical performance of the composites were investigated.Compared with the cathodes without in situ VGCF,the initial discharge capacity of the composite electrode increases from 109 to 144 mA h g-1 at a 0.5-C rate,and the total electric resistance decreases from 538 to 66.The possible reasons for these effects are proposed.
