The effect of particle size on the density and resistivity of ITO green bodies and targets was systematically investigated.The experimental results show that the relative density of ITO green bodies decreases with the...The effect of particle size on the density and resistivity of ITO green bodies and targets was systematically investigated.The experimental results show that the relative density of ITO green bodies decreases with the increase of ITO particle size.When the particle size is 10.7 nm,the relative density of ITO green bodies rises to the maximum value of 56.6%.The resistivity declines exponentially with the increase of particle size,which satisfies the exponential equation of R=exp(-41.823 × d).When the particle size is 41.6 nm,the resistivity reaches the minimum value of 0.8 Ω·cm.The relative density of ITO target decreases with the increase of particle size.Fine particles can increase the driving force of densification in initial stage.Electron mobility,caused by grain boundary scattering,will increase due to the increase of particle size or the decrease of grain boundary potential.When the particle size is 10.7 nm,the target with compact grain stacking and low porosity shows a maximum relative density of 99.25%,and the resistivity reaches the minimum value of 0.34×10^-3 Ω·cm.展开更多
The electrical and optical effects of particles on the nano aluminum film deposited by thermal evaporation was investigated. From the characterization results of scanning electron microscope（SEM）, the accumulation i...The electrical and optical effects of particles on the nano aluminum film deposited by thermal evaporation was investigated. From the characterization results of scanning electron microscope（SEM）, the accumulation in tens of nanometers had been observed. The current-voltage（I-V） curve of the sample indicates its nonlinear electrical characters expecting the corresponding nonlinear optical properties. By the theoretical calculation, nonlinear conduction of the carrier transportation may result from the barrier-well-barrier structure, where negative resistance and Coulomb blockade effect appears. The simulation results are approximately matched with the experimental results. By testing the fluorescence emission spectrum of the sample, peaks were found to be located at 420 and 440 nm. In addition, the full width at half maximum（FWHM） had been obviously broadened by means of adding 2, 5-diphenyloxazole（DPO）. Therefore, discrete energy levels could be estimated inside those particles.展开更多
基金Funded by the Beijing Municipal Natural Science Foundation (No. 2192041)。
文摘The effect of particle size on the density and resistivity of ITO green bodies and targets was systematically investigated.The experimental results show that the relative density of ITO green bodies decreases with the increase of ITO particle size.When the particle size is 10.7 nm,the relative density of ITO green bodies rises to the maximum value of 56.6%.The resistivity declines exponentially with the increase of particle size,which satisfies the exponential equation of R=exp(-41.823 × d).When the particle size is 41.6 nm,the resistivity reaches the minimum value of 0.8 Ω·cm.The relative density of ITO target decreases with the increase of particle size.Fine particles can increase the driving force of densification in initial stage.Electron mobility,caused by grain boundary scattering,will increase due to the increase of particle size or the decrease of grain boundary potential.When the particle size is 10.7 nm,the target with compact grain stacking and low porosity shows a maximum relative density of 99.25%,and the resistivity reaches the minimum value of 0.34×10^-3 Ω·cm.
基金Supported by the 973 Program(No.2014CB932103)the 863 Program(No.2013AA032501)the National Natural Science Foundation of China(NSFC No.21676015)
文摘The electrical and optical effects of particles on the nano aluminum film deposited by thermal evaporation was investigated. From the characterization results of scanning electron microscope（SEM）, the accumulation in tens of nanometers had been observed. The current-voltage（I-V） curve of the sample indicates its nonlinear electrical characters expecting the corresponding nonlinear optical properties. By the theoretical calculation, nonlinear conduction of the carrier transportation may result from the barrier-well-barrier structure, where negative resistance and Coulomb blockade effect appears. The simulation results are approximately matched with the experimental results. By testing the fluorescence emission spectrum of the sample, peaks were found to be located at 420 and 440 nm. In addition, the full width at half maximum（FWHM） had been obviously broadened by means of adding 2, 5-diphenyloxazole（DPO）. Therefore, discrete energy levels could be estimated inside those particles.
