With the high-temperature viscometer and magnetic susceptibility measurement device designed by our group,the viscosity and the magnetic susceptibility of the Cu65Sn35 melt were measured during the cooling process.An ...With the high-temperature viscometer and magnetic susceptibility measurement device designed by our group,the viscosity and the magnetic susceptibility of the Cu65Sn35 melt were measured during the cooling process.An anomalous change can be found in the curves of viscosity and magnetic susceptibility at a certain temperature.The structure of the melt was studied by the high-temperature X-ray diffractometer.The anomalous change also can be found in the pair distribution function,correlation radius,and coordination number at the approximate tem-perature,which shows the microstructural change of the Cu65Sn35 melt.From the results,it was confirmed that the Cu6Sn5 compound occurs in the melt,which leads to the structural change of the melt.展开更多
The liquid structure of Al71.6 Ge28.4 eutectic alloy was studied by X-ray diffractometer.For the liquid alloy Al71.6 Ge28.4,the structure has no change while the order increases with the decreasing temperature from 11...The liquid structure of Al71.6 Ge28.4 eutectic alloy was studied by X-ray diffractometer.For the liquid alloy Al71.6 Ge28.4,the structure has no change while the order increases with the decreasing temperature from 1150°C to 550°C.Meanwhile,the correlation between liquid structure and solid structure has also been analyzed by "the nanocrystal model".It is shown that the melt consists of 72.8% α clusters and 27.2% β clusters,but the liquid structure and solid structure have striking difference,which is one of the reasons to obtain a large undercooling easily for this alloy.展开更多
基金the National Natural Science Foundation of China (Grant Nos. 50395101and 50571052)
文摘With the high-temperature viscometer and magnetic susceptibility measurement device designed by our group,the viscosity and the magnetic susceptibility of the Cu65Sn35 melt were measured during the cooling process.An anomalous change can be found in the curves of viscosity and magnetic susceptibility at a certain temperature.The structure of the melt was studied by the high-temperature X-ray diffractometer.The anomalous change also can be found in the pair distribution function,correlation radius,and coordination number at the approximate tem-perature,which shows the microstructural change of the Cu65Sn35 melt.From the results,it was confirmed that the Cu6Sn5 compound occurs in the melt,which leads to the structural change of the melt.
基金supported by the National Natural Science Foundation of China (Grant Nos.50395101 and 50571052)
文摘The liquid structure of Al71.6 Ge28.4 eutectic alloy was studied by X-ray diffractometer.For the liquid alloy Al71.6 Ge28.4,the structure has no change while the order increases with the decreasing temperature from 1150°C to 550°C.Meanwhile,the correlation between liquid structure and solid structure has also been analyzed by "the nanocrystal model".It is shown that the melt consists of 72.8% α clusters and 27.2% β clusters,but the liquid structure and solid structure have striking difference,which is one of the reasons to obtain a large undercooling easily for this alloy.
