The forming ability of quasicrystal phase has a relationship with the atomic bond factors based on differences in atom size and electron factors.Usually,those factors or their combination are used to describe the form...The forming ability of quasicrystal phase has a relationship with the atomic bond factors based on differences in atom size and electron factors.Usually,those factors or their combination are used to describe the forming ability,stability of alloys,etc.In this paper,the quasicrystal alloy forming abilities for the fifth and sixth transition metals(Y,Zr,Nb,Mo,Ru,Rh,Pd and La,Hf,Ta,W,Re,Os,Ir,Pt) based alloys have been studied by the size factor and the atomic parametric function.It has been found that an ellipse curve can be used to separate the quasicrystal formed area from the informed area in the size factor and atomic parameters functional graph.The ellipse curve can be defined by an equation(x-m)2/c2+(y?n)2/d2=1.The overall reliabilities for the model are up to 97.4% and 95.5% for the fifth and the sixth transition metals based quasicrystal alloys,respectively.Also,the ellipse parameters m,n,c and d can be paraphrased by some appropriate parameters for each host metal.展开更多
Based on the ideal solution approximation, the model for size-dependent melting temperature of pure metal nanoparticles is extended to binary alloy systems. The developed model, free of any adjustable parameter, demon...Based on the ideal solution approximation, the model for size-dependent melting temperature of pure metal nanoparticles is extended to binary alloy systems. The developed model, free of any adjustable parameter, demonstrates that the melting temperature is related to the size and composition of alloy nanoparticles. The melting temperature of CuNi, PbBi and SnIn binary alloy nanocrystals is found to be consistent with the experiments and molecular dynamics simulations. The research reveals that alloy nanocrystals have similar melting nature as pure metal.展开更多
基金Supported by the Scientific Research Fund of Hunan Provincial Education Department
文摘The forming ability of quasicrystal phase has a relationship with the atomic bond factors based on differences in atom size and electron factors.Usually,those factors or their combination are used to describe the forming ability,stability of alloys,etc.In this paper,the quasicrystal alloy forming abilities for the fifth and sixth transition metals(Y,Zr,Nb,Mo,Ru,Rh,Pd and La,Hf,Ta,W,Re,Os,Ir,Pt) based alloys have been studied by the size factor and the atomic parametric function.It has been found that an ellipse curve can be used to separate the quasicrystal formed area from the informed area in the size factor and atomic parameters functional graph.The ellipse curve can be defined by an equation(x-m)2/c2+(y?n)2/d2=1.The overall reliabilities for the model are up to 97.4% and 95.5% for the fifth and the sixth transition metals based quasicrystal alloys,respectively.Also,the ellipse parameters m,n,c and d can be paraphrased by some appropriate parameters for each host metal.
基金supported by the Scientific Research Fund of Hunan Provincial Science & Technology Department (Grant No. 2009FJ3153)
文摘Based on the ideal solution approximation, the model for size-dependent melting temperature of pure metal nanoparticles is extended to binary alloy systems. The developed model, free of any adjustable parameter, demonstrates that the melting temperature is related to the size and composition of alloy nanoparticles. The melting temperature of CuNi, PbBi and SnIn binary alloy nanocrystals is found to be consistent with the experiments and molecular dynamics simulations. The research reveals that alloy nanocrystals have similar melting nature as pure metal.
