Improved power conversion efficiency(PCE)and stability of organic bulk heterojunction(BHJ)solar cells based on poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene)(MEH-PPV)and methanofullerene[6,6]-phenyl C_(61)-...Improved power conversion efficiency(PCE)and stability of organic bulk heterojunction(BHJ)solar cells based on poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene)(MEH-PPV)and methanofullerene[6,6]-phenyl C_(61)-butyric acid methyl ester(PCBM)blends are obtained by using ditert butyl peroxide(DTBP)as an additive.The effect of the DTBP contents on the performance of photovoltaic cells is investigated.The results reveal that efficiency enhancement of MEH-PPV:PCBM solar cells can be realized by carefully tuning the contents of DTBP.Compared to the control device,the optimized device with 0.5wt%DTBP additive exhibits enhanced performance with Jsc of(3.51±0.21)mA/cm^(2),FF of(44.45±0.71)%,and PCE of(1.31±0.08)%,increased by 9.3%,8.0%and 22.4%,respectively.The stability of the device is found to be improved by adding 0.5wt%of DTBP.展开更多
基金Supported by the National Natural Science Foundation of China(60876046,60976048)Key Project of the Ministry of Education of China(209007)+2 种基金Tianjin Natural Science Foundation(10ZCKFGX01900,12JCQNJC01300 and 10SYSYJC28100)Scientific Developing Foundation of Tianjin Education Commission(20100723)the Tianjin Key Discipline of Material Physics and Chemistry.
文摘Improved power conversion efficiency(PCE)and stability of organic bulk heterojunction(BHJ)solar cells based on poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene)(MEH-PPV)and methanofullerene[6,6]-phenyl C_(61)-butyric acid methyl ester(PCBM)blends are obtained by using ditert butyl peroxide(DTBP)as an additive.The effect of the DTBP contents on the performance of photovoltaic cells is investigated.The results reveal that efficiency enhancement of MEH-PPV:PCBM solar cells can be realized by carefully tuning the contents of DTBP.Compared to the control device,the optimized device with 0.5wt%DTBP additive exhibits enhanced performance with Jsc of(3.51±0.21)mA/cm^(2),FF of(44.45±0.71)%,and PCE of(1.31±0.08)%,increased by 9.3%,8.0%and 22.4%,respectively.The stability of the device is found to be improved by adding 0.5wt%of DTBP.