机载激光雷达(LiDAR,light detection and ranging)数据能有效去除植被,获取真实的地表形态,从而为植被覆盖区的地质灾害风险评价提供新的方法和手段。汕尾火山嶂山体陡峻、植被茂密,是滑坡、崩塌和泥石流的易发地,本文首先采用高分辨率...机载激光雷达(LiDAR,light detection and ranging)数据能有效去除植被,获取真实的地表形态,从而为植被覆盖区的地质灾害风险评价提供新的方法和手段。汕尾火山嶂山体陡峻、植被茂密,是滑坡、崩塌和泥石流的易发地,本文首先采用高分辨率LiDAR数据生成高精度DEM数据以及坡度、坡向、曲率、起伏度、粗糙度和山体阴影等地形因子,综合高分一号遥感影像进行滑坡/崩塌解译共获得滑坡/崩塌44处;然后基于变维分形模型确定各解译因子对滑坡/崩塌形成的权重后计算获得每个解译滑坡/崩塌的确认概率,剔除概率较低的滑坡/崩塌3处;最后根据沟谷特征将火山嶂划分为6个子区,基于各个子区的地形特征、滑坡/崩塌密度和体量以及人类活动分布进行地质灾害风险评价。结果表明基于LiDAR数据生成的高精度地形因子可以有效地去除植被影响,是植被覆盖区地质灾害解译的有效手段。展开更多
To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut sh...To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.展开更多
文摘机载激光雷达(LiDAR,light detection and ranging)数据能有效去除植被,获取真实的地表形态,从而为植被覆盖区的地质灾害风险评价提供新的方法和手段。汕尾火山嶂山体陡峻、植被茂密,是滑坡、崩塌和泥石流的易发地,本文首先采用高分辨率LiDAR数据生成高精度DEM数据以及坡度、坡向、曲率、起伏度、粗糙度和山体阴影等地形因子,综合高分一号遥感影像进行滑坡/崩塌解译共获得滑坡/崩塌44处;然后基于变维分形模型确定各解译因子对滑坡/崩塌形成的权重后计算获得每个解译滑坡/崩塌的确认概率,剔除概率较低的滑坡/崩塌3处;最后根据沟谷特征将火山嶂划分为6个子区,基于各个子区的地形特征、滑坡/崩塌密度和体量以及人类活动分布进行地质灾害风险评价。结果表明基于LiDAR数据生成的高精度地形因子可以有效地去除植被影响,是植被覆盖区地质灾害解译的有效手段。
基金Funded by the General Project of Science and Technology Plan of Yunnan Science and Technology Department(Nos.202001AT070029,2019FB077)Open Fund of Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education(No.FMRUlab-20-4)。
文摘To study the modification mechanism of activated carbon(AC)by Fe and the low-temperature NH_(3)-selective catalytic reduction(SCR)denitration mechanism of Fe/AC catalysts,Fe/AC catalysts were prepared using coconut shell AC activated by nitric acid as the support and iron oxide as the active component.The crystal structure,surface morphology,pore structure,functional groups and valence states of the active components of Fe/AC catalysts were characterised by X-ray diffraction,scanning electron microscopy,nitrogen adsorption and desorption,Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy,respectively.The effect of Fe loading and calcination temperature on the low-temperature denitration of NH_(3)-SCR over Fe/AC catalysts was studied using NH_(3)as the reducing gas at low temperature(150℃).The results show that the iron oxide on the Fe/AC catalyst is spherical and uniformly dispersed on the surface of AC,thereby improving the crystallisation performance and increasing the number of active sites and specific surface area on AC in contact with the reaction gas.Hence,a rapid NH_(3)-SCR reaction was realised.When the roasting temperature remains constant,the iron oxide crystals formed by increasing the amount of loading can enter the AC pore structure and accumulate to form more micropores.When the roasting temperature is raised from 400 to 500℃,the iron oxide is mainly transformed fromα-Fe_(2)O_(3)toγ-Fe_(2)O_(3),which improves the iron oxide dispersion and increases its denitration active site,allowing gas adsorption.When the Fe loading amount is 10%,and the roasting temperature is 500℃,the NO removal rate of the Fe/AC catalyst can reach 95%.According to the study,the low-temperature NH_(3)-SCR mechanism of Fe/AC catalyst is proposed,in which the redox reaction between Fe~(2+)and Fe~(3+)will facilitate the formation of reactive oxygen vacancies,which increases the amount of oxygen adsorption on the surface,especially the increase in surface acid sites,and promotes and adsorbs more reaction gases(NH_(3),O_(2),NO).The transformation from the standard SCR reaction to the fast SCR reaction is accelerated.
