A soil survey was conducted in Zhangzhou City, an important agricultural region in south of the Fujian Province, China. 93 surface soil samples were collected in the paddy fields, vegetable lands, orchards and tea pla...A soil survey was conducted in Zhangzhou City, an important agricultural region in south of the Fujian Province, China. 93 surface soil samples were collected in the paddy fields, vegetable lands, orchards and tea plantations from Zhangzhou City. An additional soil profile was sampled in a paddy field as previous research had indicated high concentrations of organochlorine pesticides （OCPs） in the paddy fields. Dichlorodiphenyltrichloroethanes （DDTs） ranged from 0.64 78.07 ng g-1 dry weight and hexachlorocyclohexanes （HCHs） ranged from 0.72-30.16 ng g-1 dry weight in the surface soil of the whole study region. Ratios of a-HCH/-γ-HCH 〈 4 and o,p′-DDT/p,p′-DDT 〉 1 in all soil samples suggested that lindane and dicofol were widely applied in this region in the past. Concentrations of HCHs and DDTs in soils from the four land use types followed the orders： paddy fields 〉 vegetable lands 〉 tea plantations 〉 orchards and tea plantations 〉 orchards 〉 paddy fields 〉 vegetable lands, respectively. Analyses of the data showed no correlation （r 〈 0.1） between elevation and OCPs contents in paddy fields, orchards and vegetable lands, indicated no significantly different features in distribution of HCHs and DDTs in the soils from low lying plains and mountains and the unsystematic usage of OCPs, and highlighted the fragmented nature of agricultural production in Zhangzhou, as well as the reemission of OCPs from the soils, where high OCPs concentrations were found, in Longhai of Zhangzhou. In addition, no obvious relationship between the OCPs and total organic carbon （TOC） （r 〈 0.3） was observed in the soil profile. The mean contribution of dicofol in total DDTs was 66% in the whole Zhangzhou region. The approximate burdens of HCHs and DDTs in the surface layer of 0-20 em were 0.44 and 1.55 t, respectively. The storage of both HCHs and DDTs in soil surface layer （0-20 cm） accounts for 40% burden of the soil layer of 0 50 cm （1.10 t HCHs and 3.87 t DDTs）, in which the highest concentrations of OCPs were observed in soil profile.展开更多
Soft reduction is known to be one of the best ways to improve the internal quality of slab castings such as center segregation, center porosity, centerline or triangular zone cracks, which is based on a proper adoptio...Soft reduction is known to be one of the best ways to improve the internal quality of slab castings such as center segregation, center porosity, centerline or triangular zone cracks, which is based on a proper adoption of the amount of reduction upon the given final solidification zone through roll gap adjustments. The synchronization of the clamping cylinders for roll gap adjustments should be very important to the application of soft reduction, including the synchronization of the clamping cylinders adjustments in the same and different segments. The synchronization of clamping cylinders adjustments is mainly affected by the adjustable accuracy of the four position-controlled clamping cylinders mounted in the upper frames of the segments according to a predetermined transformation relationship between the signals of displacement sensors and aimed roll gap, which, however, is also influenced by the installation accuracy, the precision of displacement sensors, the deformation of the segment frames and/or its bearing pedestals. Due to the actual asynchronous adjustments of the four clamping cylinders, the dynamic soft reduction operation is normally applied at non-ideal mechanical conditions. Here 7 possible situations of asynchronous adjustments of the local segments which may induce gap deviation have been presented. The roll gap deviation in the soft reduction region of a slab casting has been studied by a 3-D visco-elastic plastic FEM model, through which the additional inter-roll bulging, the related triangular cracks induced by one kind of the possible asynchronous adjustment situation and the effectiveness of soft reduction have been analyzed. A critical tolerance for the gap adjustments has been proposed for better contribution of soft reduction to the internal quality of slabs.展开更多
基金Supported by the National Natural Science Foundation of China(No.41073070)the Research Fund for the Doctoral Program of Higher Education of China(No.20090145110004)
文摘A soil survey was conducted in Zhangzhou City, an important agricultural region in south of the Fujian Province, China. 93 surface soil samples were collected in the paddy fields, vegetable lands, orchards and tea plantations from Zhangzhou City. An additional soil profile was sampled in a paddy field as previous research had indicated high concentrations of organochlorine pesticides （OCPs） in the paddy fields. Dichlorodiphenyltrichloroethanes （DDTs） ranged from 0.64 78.07 ng g-1 dry weight and hexachlorocyclohexanes （HCHs） ranged from 0.72-30.16 ng g-1 dry weight in the surface soil of the whole study region. Ratios of a-HCH/-γ-HCH 〈 4 and o,p′-DDT/p,p′-DDT 〉 1 in all soil samples suggested that lindane and dicofol were widely applied in this region in the past. Concentrations of HCHs and DDTs in soils from the four land use types followed the orders： paddy fields 〉 vegetable lands 〉 tea plantations 〉 orchards and tea plantations 〉 orchards 〉 paddy fields 〉 vegetable lands, respectively. Analyses of the data showed no correlation （r 〈 0.1） between elevation and OCPs contents in paddy fields, orchards and vegetable lands, indicated no significantly different features in distribution of HCHs and DDTs in the soils from low lying plains and mountains and the unsystematic usage of OCPs, and highlighted the fragmented nature of agricultural production in Zhangzhou, as well as the reemission of OCPs from the soils, where high OCPs concentrations were found, in Longhai of Zhangzhou. In addition, no obvious relationship between the OCPs and total organic carbon （TOC） （r 〈 0.3） was observed in the soil profile. The mean contribution of dicofol in total DDTs was 66% in the whole Zhangzhou region. The approximate burdens of HCHs and DDTs in the surface layer of 0-20 em were 0.44 and 1.55 t, respectively. The storage of both HCHs and DDTs in soil surface layer （0-20 cm） accounts for 40% burden of the soil layer of 0 50 cm （1.10 t HCHs and 3.87 t DDTs）, in which the highest concentrations of OCPs were observed in soil profile.
文摘Soft reduction is known to be one of the best ways to improve the internal quality of slab castings such as center segregation, center porosity, centerline or triangular zone cracks, which is based on a proper adoption of the amount of reduction upon the given final solidification zone through roll gap adjustments. The synchronization of the clamping cylinders for roll gap adjustments should be very important to the application of soft reduction, including the synchronization of the clamping cylinders adjustments in the same and different segments. The synchronization of clamping cylinders adjustments is mainly affected by the adjustable accuracy of the four position-controlled clamping cylinders mounted in the upper frames of the segments according to a predetermined transformation relationship between the signals of displacement sensors and aimed roll gap, which, however, is also influenced by the installation accuracy, the precision of displacement sensors, the deformation of the segment frames and/or its bearing pedestals. Due to the actual asynchronous adjustments of the four clamping cylinders, the dynamic soft reduction operation is normally applied at non-ideal mechanical conditions. Here 7 possible situations of asynchronous adjustments of the local segments which may induce gap deviation have been presented. The roll gap deviation in the soft reduction region of a slab casting has been studied by a 3-D visco-elastic plastic FEM model, through which the additional inter-roll bulging, the related triangular cracks induced by one kind of the possible asynchronous adjustment situation and the effectiveness of soft reduction have been analyzed. A critical tolerance for the gap adjustments has been proposed for better contribution of soft reduction to the internal quality of slabs.
