Methyl isobutyl ketone(MIBK) is widely used as extraction agent in hydrometallurgy. As it has a definite solubility in water, so when using MIBK as extraction agent, there will be MIBK in stripping solutions inevitabl...Methyl isobutyl ketone(MIBK) is widely used as extraction agent in hydrometallurgy. As it has a definite solubility in water, so when using MIBK as extraction agent, there will be MIBK in stripping solutions inevitably, which not only pollutes working conditions, but also affects the quality of ultimate product. In order to remove MIBK from aqueous solutions, the means of flat vacuum membrane distillation(VMD) is studied in the paper. The area of the membrane used in the study is 0.02 m 2, the initial volume of feed is 2 L, each experiment was conducted over a time period of 60 120 min. The influences of the factors such as temperature(34.8 55.0 ℃); pressure in the permeate side(10.67 14.67 kPa) and feed flow rate(27.8 69.4 mL/s) were experimentally studied. Increasing the temperature or reducing the pressure in the permeate side results in a faster removal of MIBK; however there is a decrease in removal factor β , increasing the feed flow rate results in a faster removal of MIBK and an increase of removal factor β , especially in the range of lower flow rate. The study indicates that the aim of MIBK removal and recycle from dilute aqueous solutions can be achieved by VMD.展开更多
In order to develop an effective MIBK removal method of H 2TaF 7 solution in tantalum extraction process, MIBK removal from aqueous solution by the aeration method was investigated by using an aeration column with the...In order to develop an effective MIBK removal method of H 2TaF 7 solution in tantalum extraction process, MIBK removal from aqueous solution by the aeration method was investigated by using an aeration column with the dimensions of 78 mm in inner diameter and 1 100 mm in length. The effects of aeration conditions on aerating efficiency were investigated in the ranges of temperature 303 333 K, airflow rate 50 300 L/h,volume of solution 1 600 3 200 mL. Aerating efficiency increases with the increase of temperature and airflow rate. MIBK in aqueous solution can be removed from 0.058 mol/L to 0.002 mol/L at 50 ℃,airflow rate 200 L/h, volume of solution 2 400 mL and aeration time 1h. The experimental results show that MIBK can be removed effectively from aqueous solution by the aeration method.展开更多
By comparing the adsorption capacity of several kinds of resins, D363 resin is regarded as the most suitable one for removing lead from nickel sulphate electrolyte. The effects of pH, temperature and contact time on e...By comparing the adsorption capacity of several kinds of resins, D363 resin is regarded as the most suitable one for removing lead from nickel sulphate electrolyte. The effects of pH, temperature and contact time on exchange adsorption during removing trace lead from industrial nickel sulphate solution with D363 large pore weak alkali anion exchange resin are discussed. Optimum conditions of adsorption of lead from nickel electrolyte by D363 resin are at room temperature, pH 1 2, contact time 30 min.展开更多
In the process of nickel production by diaphragm electrolysis, the quality of the product has been tremendously affec ted by the content of zinc in the nickel electrolyte. Removing zinc from nickel electrolyte by ion ...In the process of nickel production by diaphragm electrolysis, the quality of the product has been tremendously affec ted by the content of zinc in the nickel electrolyte. Removing zinc from nickel electrolyte by ion exchange is studied in the paper. Resin D201 is selected as the resin for zinc removing. Effects of the operative parameters, such as temperature, pH value and the contact time on zinc adsorption are observed and the desorption feature of the zinc loaded resin is inspected. The results show that macroporous anion exchange resin D201 has excellent adsorption and desorption properties. Its breakthrough capacity and saturation capacity in zinc adsorption reach 0.81 g/L of zinc and 1.16 g/L of zinc respectively, when the operative temperature is 60 ℃ and the contact time is only 5 min. In addition, compared with gel type IER 201×7 used industrially nowadays, this resin has better wearability and greater intensity.展开更多
文摘Methyl isobutyl ketone(MIBK) is widely used as extraction agent in hydrometallurgy. As it has a definite solubility in water, so when using MIBK as extraction agent, there will be MIBK in stripping solutions inevitably, which not only pollutes working conditions, but also affects the quality of ultimate product. In order to remove MIBK from aqueous solutions, the means of flat vacuum membrane distillation(VMD) is studied in the paper. The area of the membrane used in the study is 0.02 m 2, the initial volume of feed is 2 L, each experiment was conducted over a time period of 60 120 min. The influences of the factors such as temperature(34.8 55.0 ℃); pressure in the permeate side(10.67 14.67 kPa) and feed flow rate(27.8 69.4 mL/s) were experimentally studied. Increasing the temperature or reducing the pressure in the permeate side results in a faster removal of MIBK; however there is a decrease in removal factor β , increasing the feed flow rate results in a faster removal of MIBK and an increase of removal factor β , especially in the range of lower flow rate. The study indicates that the aim of MIBK removal and recycle from dilute aqueous solutions can be achieved by VMD.
文摘In order to develop an effective MIBK removal method of H 2TaF 7 solution in tantalum extraction process, MIBK removal from aqueous solution by the aeration method was investigated by using an aeration column with the dimensions of 78 mm in inner diameter and 1 100 mm in length. The effects of aeration conditions on aerating efficiency were investigated in the ranges of temperature 303 333 K, airflow rate 50 300 L/h,volume of solution 1 600 3 200 mL. Aerating efficiency increases with the increase of temperature and airflow rate. MIBK in aqueous solution can be removed from 0.058 mol/L to 0.002 mol/L at 50 ℃,airflow rate 200 L/h, volume of solution 2 400 mL and aeration time 1h. The experimental results show that MIBK can be removed effectively from aqueous solution by the aeration method.
基金The Key Program of the 10th Five year Plan of Jinchuan Non-ferrous Metals Company(No.2000.1)
文摘By comparing the adsorption capacity of several kinds of resins, D363 resin is regarded as the most suitable one for removing lead from nickel sulphate electrolyte. The effects of pH, temperature and contact time on exchange adsorption during removing trace lead from industrial nickel sulphate solution with D363 large pore weak alkali anion exchange resin are discussed. Optimum conditions of adsorption of lead from nickel electrolyte by D363 resin are at room temperature, pH 1 2, contact time 30 min.
文摘In the process of nickel production by diaphragm electrolysis, the quality of the product has been tremendously affec ted by the content of zinc in the nickel electrolyte. Removing zinc from nickel electrolyte by ion exchange is studied in the paper. Resin D201 is selected as the resin for zinc removing. Effects of the operative parameters, such as temperature, pH value and the contact time on zinc adsorption are observed and the desorption feature of the zinc loaded resin is inspected. The results show that macroporous anion exchange resin D201 has excellent adsorption and desorption properties. Its breakthrough capacity and saturation capacity in zinc adsorption reach 0.81 g/L of zinc and 1.16 g/L of zinc respectively, when the operative temperature is 60 ℃ and the contact time is only 5 min. In addition, compared with gel type IER 201×7 used industrially nowadays, this resin has better wearability and greater intensity.
