Soil organic carbon (SOC) has great impacts on global warming, land degradation and food security. Classic statistical and geostatistical methods were used to characterize and compare the spatial heterogeneity of SOC ...Soil organic carbon (SOC) has great impacts on global warming, land degradation and food security. Classic statistical and geostatistical methods were used to characterize and compare the spatial heterogeneity of SOC and related factors, such as topography, soil type and land use, in the Liudaogou watershed on the Loess Plateau of North China. SOC concentrations followed a log-normal distribution with an arithmetic and geometric means of 23.4 and 21.3 g kg-1, respectively, were moderately variable (CV = 75.9%), and demonstrated a moderate spatial dependence according to the nugget ratio (34.7%). The experimental variogram of SOC was best-fitted by a spherical model, after the spatial outliers had been detected and subsequently eliminated. Lower SOC concentrations were associated with higher elevations. Warp soils and farmland had the highest SOC concentrations, while aeolian sand soil and shrublands had the lowest SOC values. The geostatistical characteristics of SOC for the different soil and land use types were different. These patterns were closely related to the spatial structure of topography, and soil and land use types.展开更多
To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in ...To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in the centralpart of the Loess Plateau, China. Results showed that during the 150 years of local vegetation rehabilitation SOC increasedsignificantly (P < 0.05) over time in the initial period of 55-59 years, but slightly decreased afterwards. Average SOCdensities for the 0-100 cm layer of farmland, grassland, shrubland and forest were 4.46, 5.05, 9.95, and 7.49 kg C m-3,respectively. The decrease in SOC from 60 to 150 years of abandonment implied that the soil carbon pool was a sink forCO2 before the shrubland stage and became a source in the later period. This change resulted from the spatially variedcomposition and structure of the vegetation. Vegetation recovery had a maximum effect on the surface (0-20 cm) SOCpool. It. was concluded that vegetation recovery on the Loess Plateau could result in significantly increased sequestrationof atmospheric CO2 in soil and vegetation, which was ecologically important for mitigating the increase of atmosphericconcentration of CO2 and for ameliorating the local eco-environment.展开更多
A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by consideri...A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by considering more than one kind of ion adsorption on the soil surface.It was compared with the Langmuir model using different conditions, and it was found that CAIM,which was suitable for competitive ion adsorption at the soil solid-liquid surface,had more advantages than the Langmuir model.The new competitive adsorption isothermal model was used to fit the data of heavy metal(Zn and Cd)competitive adsorption by a yellow soil at two temperatures.The results showed that CAIM was appropriate for the competitive adsorption of heavy metals on the soil surface at different temperatures.The fitted parameters of CAIM had explicit physical meaning.The model allowed for the calculation of the standard molar Gibbs free energy change,the standard molar enthalpy change,and the standard molar entropy change of the competitive adsorption of the heavy metals,Zn and Cd,by the yellow soil at two temperatures using the thermodynamic equilibrium constants.展开更多
基金Project supported by the National Key Basic Research Program (973 Program) of China (No.2007CB106803)the National Programs for Science and Technology Development of China (No.2006BAD09B06)the Scientific ResearchInnovation Team Support Program of the Northwest A&F University, China
文摘Soil organic carbon (SOC) has great impacts on global warming, land degradation and food security. Classic statistical and geostatistical methods were used to characterize and compare the spatial heterogeneity of SOC and related factors, such as topography, soil type and land use, in the Liudaogou watershed on the Loess Plateau of North China. SOC concentrations followed a log-normal distribution with an arithmetic and geometric means of 23.4 and 21.3 g kg-1, respectively, were moderately variable (CV = 75.9%), and demonstrated a moderate spatial dependence according to the nugget ratio (34.7%). The experimental variogram of SOC was best-fitted by a spherical model, after the spatial outliers had been detected and subsequently eliminated. Lower SOC concentrations were associated with higher elevations. Warp soils and farmland had the highest SOC concentrations, while aeolian sand soil and shrublands had the lowest SOC values. The geostatistical characteristics of SOC for the different soil and land use types were different. These patterns were closely related to the spatial structure of topography, and soil and land use types.
基金the National Key Basic Research Support Foundation of China (No. 2002CB111502), the NationalNatural Science Foundation of China (Nos. 40371074 and 40025106) and the China Postdoctoral Science Foundation(No. 2003033023).
文摘To probe the processes and mechanisms of soil organic carbon (SOC) changes during forest recovery, a 150-yearchronosequence study on SOC was conducted for various vegetation succession stages at the Ziwuling area, in the centralpart of the Loess Plateau, China. Results showed that during the 150 years of local vegetation rehabilitation SOC increasedsignificantly (P < 0.05) over time in the initial period of 55-59 years, but slightly decreased afterwards. Average SOCdensities for the 0-100 cm layer of farmland, grassland, shrubland and forest were 4.46, 5.05, 9.95, and 7.49 kg C m-3,respectively. The decrease in SOC from 60 to 150 years of abandonment implied that the soil carbon pool was a sink forCO2 before the shrubland stage and became a source in the later period. This change resulted from the spatially variedcomposition and structure of the vegetation. Vegetation recovery had a maximum effect on the surface (0-20 cm) SOCpool. It. was concluded that vegetation recovery on the Loess Plateau could result in significantly increased sequestrationof atmospheric CO2 in soil and vegetation, which was ecologically important for mitigating the increase of atmosphericconcentration of CO2 and for ameliorating the local eco-environment.
基金Project supported by the Program for Changjiang Scholars and Innovative Research Team in University of China(No.IRT0749)
文摘A new competitive adsorption isothermal model(CAIM)was developed for the coexistent and competitive binding of heavy metals to the soil surface.This model extended the earlier adsorption isothermal models by considering more than one kind of ion adsorption on the soil surface.It was compared with the Langmuir model using different conditions, and it was found that CAIM,which was suitable for competitive ion adsorption at the soil solid-liquid surface,had more advantages than the Langmuir model.The new competitive adsorption isothermal model was used to fit the data of heavy metal(Zn and Cd)competitive adsorption by a yellow soil at two temperatures.The results showed that CAIM was appropriate for the competitive adsorption of heavy metals on the soil surface at different temperatures.The fitted parameters of CAIM had explicit physical meaning.The model allowed for the calculation of the standard molar Gibbs free energy change,the standard molar enthalpy change,and the standard molar entropy change of the competitive adsorption of the heavy metals,Zn and Cd,by the yellow soil at two temperatures using the thermodynamic equilibrium constants.