The ＂poly＂ chair is a combination of the excellent elements of traditional arts and crafts and modern materials. Some innovations have been made while respecting the lines and patterns of the traditional chair in th...The ＂poly＂ chair is a combination of the excellent elements of traditional arts and crafts and modern materials. Some innovations have been made while respecting the lines and patterns of the traditional chair in the design of the ＂poly＂ chair. The structure of the chair adopts the traditional pattern fish scale pattern, engraving it on the seat surface, which not only looks beautiful but also plays a supporting role; its transparent feeling gives a visual feast. In each of its structures, some of our traditional elements are properly applied to the chairs. Break the wooden structure of the past, the use of stainless steel material, the perfect combination of traditional and modern elements. So that ＂poly＂ chair is not only an ornamental handicrafts, but also a use of furniture, functional and decorative unity. In giving the feeling of light and transparent at the same time, gives a sense of grace. This design report details the selection of topics from research, to the design of the entire process.展开更多
Electrospray ionization （ESI） coupled with Fourier transform ion cyclotron resonance mass spectrometry （ FT-ICR MS） is a powerful technique capable of detecting heteroatom compounds, present in trace quantities in...Electrospray ionization （ESI） coupled with Fourier transform ion cyclotron resonance mass spectrometry （ FT-ICR MS） is a powerful technique capable of detecting heteroatom compounds, present in trace quantities in crude oil and its products without prior sample pretreatment. It enables the assignment of a unique elemental composition to each peak in the mass spectrum of petroleum samples.展开更多
This paper examined the bond dissociation behavior and aromatic ring architecture of basic nitrogen compounds in Sudan heavy petroleum fraction. Both broadband and quadrupole isolation modes positive-ion electrospray ...This paper examined the bond dissociation behavior and aromatic ring architecture of basic nitrogen compounds in Sudan heavy petroleum fraction. Both broadband and quadrupole isolation modes positive-ion electrospray ionization （ESI） Fourier transform ion cyclotron resonance mass spectrometry （FT-ICR MS） coupled with collision induced dissociation （CID） tech- niques were used to characterize a low sulfur crude oil derived vacuum residuum （VR）. The appropriate CID operating condi- tion was selected by comparing the molecular weight distributions of the basic nitrogen compounds under various CID operat- ing conditions. Both odd- and even-electron fragment ions were observed from the mass spectrum, indicating that the hetero- lyric and homolytic bond cleavages occurred simultaneously during the CID process. The odd-electron fragment ions were predominant in each class species, indicating preferential heterolytic bond cleavages. At the optimal CID condition, the alkyl groups decomposed deeply and just left the aromatic cores of the nitrogen compounds. No Significant variation in double bond equivalent （DBE） value was observed between the fragment and parent ions, revealing that the domination of single core structure.展开更多
A vacuum topped Canadian oilsands bitumen （VTB） was subjected to solvent precipitation and subsequently characterized by elemental analysis, gel permeation chromatograph （GPC）, IH-NMR spectroscopy and negative-ion...A vacuum topped Canadian oilsands bitumen （VTB） was subjected to solvent precipitation and subsequently characterized by elemental analysis, gel permeation chromatograph （GPC）, IH-NMR spectroscopy and negative-ion electrospray ionization （ESI） Fourier transform ion cyclotron resonance mass spectrometry （FT-ICR MS）. Effects of experimental conditions such as solvent types （n-Cs, n-C6, and n-C7）, solvent purity, and solvent washing time on asphaltenes yields, bulk composition, and molecular composition of detectable heteroatom compounds in ESI source were determined. Elemental nitrogen and sulfur were enriched in asphaltenes while elemental oxygen had comparable content in maltenes and asphaltenes. Molecular compo- sition of asphaltenes varies with separation conditions. The N1 and O1 species identified by ESI FT-ICR MS were enriched in maltenes. The 02 species exhibited two different double bond equivalents （DBE） distributions and solubility in normal paraffin solvents, indicating two types of molecular structures. Multi oxygen atom containing compounds mainly detected in asphal- tenes. Compound class distributions are similar for maltenes derived from n-Cs, n-C6, and n-C7 , as well as for asphaltenes. The cyclic paraffin impurities in normal paraffin solvents had a significant influence on asphaltenes yields and heteroatom molecu- lar composition. A portion of neutral N1 species and acidic 02 species adsorbed on asphaltenes could be dissolved by increas- ing washing time. Cautions should be exercised when interpreting the properties and composition of asphaltenes obtained with different experimental conditions.展开更多
Acephenanthrylene and aceanthrylene in aromatic fraction of aerosols were identified by means of online hydrogenation gas chromatography mass spectrometry(GCMS). Compared aerosols from vari- ous sources, acephenanthry...Acephenanthrylene and aceanthrylene in aromatic fraction of aerosols were identified by means of online hydrogenation gas chromatography mass spectrometry(GCMS). Compared aerosols from vari- ous sources, acephenanthrylene and aceanthrylene were ubiquitously present in urban aerosol. High concentration of acephenanthrylene and aceanthrylene were found in agricultural biomass and coal combustion particles. However, it is difficult to detect in exhaust from gasoline and diesel engine, dustfall, waste water, soil, and sediment. Combustion emissions were considered the major source of acephenanthrylene and aceanthrylene, which can be used as a potential molecular marker for the source pollution in urban aerosols.展开更多
文摘The ＂poly＂ chair is a combination of the excellent elements of traditional arts and crafts and modern materials. Some innovations have been made while respecting the lines and patterns of the traditional chair in the design of the ＂poly＂ chair. The structure of the chair adopts the traditional pattern fish scale pattern, engraving it on the seat surface, which not only looks beautiful but also plays a supporting role; its transparent feeling gives a visual feast. In each of its structures, some of our traditional elements are properly applied to the chairs. Break the wooden structure of the past, the use of stainless steel material, the perfect combination of traditional and modern elements. So that ＂poly＂ chair is not only an ornamental handicrafts, but also a use of furniture, functional and decorative unity. In giving the feeling of light and transparent at the same time, gives a sense of grace. This design report details the selection of topics from research, to the design of the entire process.
基金supported by China Postdoctoral Science Foundation funded project(No.2015M571226)
文摘Electrospray ionization （ESI） coupled with Fourier transform ion cyclotron resonance mass spectrometry （ FT-ICR MS） is a powerful technique capable of detecting heteroatom compounds, present in trace quantities in crude oil and its products without prior sample pretreatment. It enables the assignment of a unique elemental composition to each peak in the mass spectrum of petroleum samples.
基金supported by the National Basic Research Program of China(2010CB226901)the National Natural Science Foundation of China(U1162204 and 21236009)
文摘This paper examined the bond dissociation behavior and aromatic ring architecture of basic nitrogen compounds in Sudan heavy petroleum fraction. Both broadband and quadrupole isolation modes positive-ion electrospray ionization （ESI） Fourier transform ion cyclotron resonance mass spectrometry （FT-ICR MS） coupled with collision induced dissociation （CID） tech- niques were used to characterize a low sulfur crude oil derived vacuum residuum （VR）. The appropriate CID operating condi- tion was selected by comparing the molecular weight distributions of the basic nitrogen compounds under various CID operat- ing conditions. Both odd- and even-electron fragment ions were observed from the mass spectrum, indicating that the hetero- lyric and homolytic bond cleavages occurred simultaneously during the CID process. The odd-electron fragment ions were predominant in each class species, indicating preferential heterolytic bond cleavages. At the optimal CID condition, the alkyl groups decomposed deeply and just left the aromatic cores of the nitrogen compounds. No Significant variation in double bond equivalent （DBE） value was observed between the fragment and parent ions, revealing that the domination of single core structure.
基金supported by the National Natural Science Foundation of China(U1162204 and 21236009)
文摘A vacuum topped Canadian oilsands bitumen （VTB） was subjected to solvent precipitation and subsequently characterized by elemental analysis, gel permeation chromatograph （GPC）, IH-NMR spectroscopy and negative-ion electrospray ionization （ESI） Fourier transform ion cyclotron resonance mass spectrometry （FT-ICR MS）. Effects of experimental conditions such as solvent types （n-Cs, n-C6, and n-C7）, solvent purity, and solvent washing time on asphaltenes yields, bulk composition, and molecular composition of detectable heteroatom compounds in ESI source were determined. Elemental nitrogen and sulfur were enriched in asphaltenes while elemental oxygen had comparable content in maltenes and asphaltenes. Molecular compo- sition of asphaltenes varies with separation conditions. The N1 and O1 species identified by ESI FT-ICR MS were enriched in maltenes. The 02 species exhibited two different double bond equivalents （DBE） distributions and solubility in normal paraffin solvents, indicating two types of molecular structures. Multi oxygen atom containing compounds mainly detected in asphal- tenes. Compound class distributions are similar for maltenes derived from n-Cs, n-C6, and n-C7 , as well as for asphaltenes. The cyclic paraffin impurities in normal paraffin solvents had a significant influence on asphaltenes yields and heteroatom molecu- lar composition. A portion of neutral N1 species and acidic 02 species adsorbed on asphaltenes could be dissolved by increas- ing washing time. Cautions should be exercised when interpreting the properties and composition of asphaltenes obtained with different experimental conditions.
基金the National Major Basic Research Program of China (Grand No. 20030425007)
文摘Acephenanthrylene and aceanthrylene in aromatic fraction of aerosols were identified by means of online hydrogenation gas chromatography mass spectrometry(GCMS). Compared aerosols from vari- ous sources, acephenanthrylene and aceanthrylene were ubiquitously present in urban aerosol. High concentration of acephenanthrylene and aceanthrylene were found in agricultural biomass and coal combustion particles. However, it is difficult to detect in exhaust from gasoline and diesel engine, dustfall, waste water, soil, and sediment. Combustion emissions were considered the major source of acephenanthrylene and aceanthrylene, which can be used as a potential molecular marker for the source pollution in urban aerosols.
