Two new inorganic-organic hybrid manganese(II)halide crystals,namely[BMMIm]2[MnCl4](1,BMMIm=1-butyl-2,3-dimethylimidazolium)and[BMMIm]2[MnBr4](2),have been obtained simply by heating/stirring with nearly 100%yield.Sin...Two new inorganic-organic hybrid manganese(II)halide crystals,namely[BMMIm]2[MnCl4](1,BMMIm=1-butyl-2,3-dimethylimidazolium)and[BMMIm]2[MnBr4](2),have been obtained simply by heating/stirring with nearly 100%yield.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in triclinic space group of P with a=10.0176(7),b=14.9603(11),c=12.9086(8)Å,a=91.060(4)°,β=110.204(5)°,g=92.361(4)°,V=1235.19(12)Å^(3),Z=2,Dc=1.353 g·cm^(-3),F(000)=526,μ=0.978 mm^(-1),R=0.0410 and wR=0.0690(I>2σ(I))and M_(r)=503.23;2 belongs to orthorhombic space group of P212121 with a=10.0176(7),b=14.9603(11),c=17.4450(14)Å,V=2614.4(3)Å^(3),Z=4,Dc=1.730 g·cm^(-3),F(000)=1340,μ=6.629 mm^(-1),R=0.0440 and wR=0.0520(I>2σ(I))and Mr=681.07.The ionic compounds 1 and 2 are composed of mononuclear tetrahedral[MnX4]2-anion and two ionic liquid cations of[BMMIm]+.The photoluminescence(PL)of 1 and 2 was characterized and the influence of halogen atom types on PL was investigated.展开更多
Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%an...Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%and 72%,respectively.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in monoclinic,space group Pn with a=15.2988(12),b=13.6388(10),c=15.6761(13)A,β=98.677(7)°,V=3233.5(4)A^(3),Z=4,D_(c)=1.459 g·cm^(-3),F(000)=1440,μ=1.370 mm^(-1),R=0.0589 and wR=0.1366(I>2σ(I));2 crystallizes in the hexagonal space group of P63 with a=27.7471(6),b=27.7471(6),c=8.9811(2)A,V=5988.2(3)A^(3),Z=6,D_(c)=1.391 g·cm^(-3),F(000)=2592,μ=1.121 mm^(-1),R=0.0420 and wR=0.0726(I>2σ(I)).The photophysical properties of the title compounds were studied by solid-state optical absorption,photoluminescent excitation/emission(PLE/PL),PL decay spectra and photoluminescent quantum yield(PLQY).1 and 2 exhibit PL peaks at 627 and 607 nm,Stokes shifts of 257 and 242 nm,and PLQY of 32.5%and 49.2%,respectively.The distinct photo physical characteristics of 1 and 2 are highly related to the distortion extent of the[SbCl_(6)]^(3-)unit.展开更多
基金the National Natural Science Foundation of China(No.21671187)the Natural Science Foundation of Fujian Province(No.2020J01118)。
文摘Two new inorganic-organic hybrid manganese(II)halide crystals,namely[BMMIm]2[MnCl4](1,BMMIm=1-butyl-2,3-dimethylimidazolium)and[BMMIm]2[MnBr4](2),have been obtained simply by heating/stirring with nearly 100%yield.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in triclinic space group of P with a=10.0176(7),b=14.9603(11),c=12.9086(8)Å,a=91.060(4)°,β=110.204(5)°,g=92.361(4)°,V=1235.19(12)Å^(3),Z=2,Dc=1.353 g·cm^(-3),F(000)=526,μ=0.978 mm^(-1),R=0.0410 and wR=0.0690(I>2σ(I))and M_(r)=503.23;2 belongs to orthorhombic space group of P212121 with a=10.0176(7),b=14.9603(11),c=17.4450(14)Å,V=2614.4(3)Å^(3),Z=4,Dc=1.730 g·cm^(-3),F(000)=1340,μ=6.629 mm^(-1),R=0.0440 and wR=0.0520(I>2σ(I))and Mr=681.07.The ionic compounds 1 and 2 are composed of mononuclear tetrahedral[MnX4]2-anion and two ionic liquid cations of[BMMIm]+.The photoluminescence(PL)of 1 and 2 was characterized and the influence of halogen atom types on PL was investigated.
基金the National Natural Science Foundation of China(No.21671187)the Natural Science Foundation of Fujian Province(No.2020J01118)。
文摘Two new hybrid chloroantimonates,namely,[Prmim]_(3)SbCl_(6)(1,Prmim=1-propyl-3-methylimidazolium)and[Hmim]_(3)SbCl_(6)(2,Hmim=1-hexyl-3-methylimidazolium),were synthesized in ionic liquids(ILs)with the yields of 97%and 72%,respectively.Single-crystal X-ray diffraction(SCXRD)study reveals that 1 crystallizes in monoclinic,space group Pn with a=15.2988(12),b=13.6388(10),c=15.6761(13)A,β=98.677(7)°,V=3233.5(4)A^(3),Z=4,D_(c)=1.459 g·cm^(-3),F(000)=1440,μ=1.370 mm^(-1),R=0.0589 and wR=0.1366(I>2σ(I));2 crystallizes in the hexagonal space group of P63 with a=27.7471(6),b=27.7471(6),c=8.9811(2)A,V=5988.2(3)A^(3),Z=6,D_(c)=1.391 g·cm^(-3),F(000)=2592,μ=1.121 mm^(-1),R=0.0420 and wR=0.0726(I>2σ(I)).The photophysical properties of the title compounds were studied by solid-state optical absorption,photoluminescent excitation/emission(PLE/PL),PL decay spectra and photoluminescent quantum yield(PLQY).1 and 2 exhibit PL peaks at 627 and 607 nm,Stokes shifts of 257 and 242 nm,and PLQY of 32.5%and 49.2%,respectively.The distinct photo physical characteristics of 1 and 2 are highly related to the distortion extent of the[SbCl_(6)]^(3-)unit.
