A new complex has been synthesized by the reaction of CuBr and 1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene. The crystal structure of the resulting complex, [Cu3（1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene）Br3]n（1）...A new complex has been synthesized by the reaction of CuBr and 1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene. The crystal structure of the resulting complex, [Cu3（1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene）Br3]n（1）, has been determined by single-crystal X-ray diffraction analysis. Complex 1 is of monoclinic system, space group P21/c with a = 10.983（7）, b = 6.294（4）, c = 17.606（10） ?, β = 102.465（6）°, V = 1188.4（3） ?3 and Mr = 577.52. Structural analyses revealed complex 1 shows a three-dimensional（3 D） framework. The thermal stability and luminescent properties of the complex are also investigated.展开更多
The organic olefin ligand 2,5-dimethyl-1-(4-vinyl-benzyl)-piperazine reacts with CuX(X = Cl, Br) to obtain two novel olefin-copper(I) coordination polymers [C_(15)H_(22)N_2Cu_2Cl_3]n(1) and [C_(15)H_(20)N_2Cu_2Br_2]n(...The organic olefin ligand 2,5-dimethyl-1-(4-vinyl-benzyl)-piperazine reacts with CuX(X = Cl, Br) to obtain two novel olefin-copper(I) coordination polymers [C_(15)H_(22)N_2Cu_2Cl_3]n(1) and [C_(15)H_(20)N_2Cu_2Br_2]n(2). There are two types of CuX warp structures that have never been seen before in the presence of methanol under solvothermal conditions. The new olefin-copper(I) coordination complex crystallizes in the monoclinic space group P21/c to obtain compounds 1 and 2. Its unique green fluorescence effect can be applied to the LED field.展开更多
文摘A new complex has been synthesized by the reaction of CuBr and 1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene. The crystal structure of the resulting complex, [Cu3（1,4-bis（2-allyl-2 H-tetrazol-5-yl）benzene）Br3]n（1）, has been determined by single-crystal X-ray diffraction analysis. Complex 1 is of monoclinic system, space group P21/c with a = 10.983（7）, b = 6.294（4）, c = 17.606（10） ?, β = 102.465（6）°, V = 1188.4（3） ?3 and Mr = 577.52. Structural analyses revealed complex 1 shows a three-dimensional（3 D） framework. The thermal stability and luminescent properties of the complex are also investigated.
基金financially supported by the National Natural Science Foundation of China(21671084)Six Talent Peaks Project in Jiangsu Province(2014-XCL-008)the Qing Lan Project of Jiangsu Province and the Foundation of Jiangsu Educational Committee(16KJB430011)
文摘The organic olefin ligand 2,5-dimethyl-1-(4-vinyl-benzyl)-piperazine reacts with CuX(X = Cl, Br) to obtain two novel olefin-copper(I) coordination polymers [C_(15)H_(22)N_2Cu_2Cl_3]n(1) and [C_(15)H_(20)N_2Cu_2Br_2]n(2). There are two types of CuX warp structures that have never been seen before in the presence of methanol under solvothermal conditions. The new olefin-copper(I) coordination complex crystallizes in the monoclinic space group P21/c to obtain compounds 1 and 2. Its unique green fluorescence effect can be applied to the LED field.
