Photoluminescence and Electroluminescence of the Blue Emission of Devices Based on Poly (p-Phenylenevinylene) Copolymers

Bright blue polymer light-emitting diodes have been fabricated by using the poly(pphenylenevinylene)-based copolymers with 10 C long aliphatic chains as the electroluminescent layers,PBD in PMMA and Alq_(3) as the electron-transporting layers,and aluminum as the cathode.The multilayer structure devices show 190cd/m^(2) light-emitting brightness at 460nm,15 V turn-on vol-tage.It is found that the intensities of photoluminescence and electroluminescence(EL)increase with increasing aliphatic chain length,the EL intensity and operation stability of these polymer light-emitting diodes can be improved by reasonable design of the structure.

2-甲硫基-2-噻唑啉合成工艺研究

替比培南酯是目前唯一一个可以口服的碳青霉烯类抗生素,2-甲硫基-2-噻唑啉是替比培南侧链中间体,2-甲硫基-2-噻唑啉质量是影响替比培南侧链关键因素;2-甲硫基-2-噻唑啉合成以2-巯基-2-噻唑啉为起始原料,甲醇为溶剂,碳酸钾作为缚酸剂,选用碘甲烷为经典甲基化试剂;反应温度25~30℃;反应时间4. 5 h最好;收率99%,纯度大于99%;操作简单,适合工业化生产。