Mn-based layered transition metal oxides are promising cathode materials for sodium-ion batteries(SIBs)because of their high theoretical capacities,abundant raw materials,and environment-friendly advantages.However,th...Mn-based layered transition metal oxides are promising cathode materials for sodium-ion batteries(SIBs)because of their high theoretical capacities,abundant raw materials,and environment-friendly advantages.However,they often show insufficient performance due to intrinsic issues including poor structural stability and dissolution of Mn^(3+).Atomic doping is an effective way to address these structural degradation issues.Herein,we reported a new synthesis strategy of a Cu-doped layered cathode by directly calcinating a pure metal-organic framework.Benefiting from the unique structure of MOF with atomic-level Cu doping,a homogeneous Cu-doped layered compound P2-Na_(0.674)Cu_(0.01)Mn_(0.99)O_(2) was obtained.The Cu substitution promotes the crystal structural stability and suppresses the dissolution of Mn,thus preventing the structure degradation of the layered cathode materials.A remarkably enhanced cyclability is realized for the Cu-doped cathode compared with that without Cu doping,with 83.8%capacity retention after 300 cycles at 100 mA·g^(-1).Our findings provide new insights into the design of atomic-level doping layered cathode materials constructed by MOFs for high-performance SIBs.展开更多
Metasurfaces have great potential for flexible manipulation of electromagnetic wave polarizations and wavefronts.Here, we propose a general method for achieving independent wavefront manipulation in a single polarizat...Metasurfaces have great potential for flexible manipulation of electromagnetic wave polarizations and wavefronts.Here, we propose a general method for achieving independent wavefront manipulation in a single polarizationmultiplexing transmissive metasurface. As a proof of concept, we design a transmission-type anisotropic metasurface for independent wavefront manipulation in full-polarization channels. An x-polarized wave transmitted through such a metasurface could be converted into four outgoing beams with delicately designed polarization states that converge to specific positions for holographic imaging. The measured results are in good agreements with simulated ones, verifying the independent wavefront manipulations with arbitrary polarization conversions.Compared with the existing traditional meta-devices with single-polarization modulation, we achieve polarization-multiplexed metasurfaces with mixed polarization and phase control, which can greatly improve the functional richness of the system.展开更多
基金This work was supported by the National Key Research and Development Program of China(2019YFE0118800).
文摘Mn-based layered transition metal oxides are promising cathode materials for sodium-ion batteries(SIBs)because of their high theoretical capacities,abundant raw materials,and environment-friendly advantages.However,they often show insufficient performance due to intrinsic issues including poor structural stability and dissolution of Mn^(3+).Atomic doping is an effective way to address these structural degradation issues.Herein,we reported a new synthesis strategy of a Cu-doped layered cathode by directly calcinating a pure metal-organic framework.Benefiting from the unique structure of MOF with atomic-level Cu doping,a homogeneous Cu-doped layered compound P2-Na_(0.674)Cu_(0.01)Mn_(0.99)O_(2) was obtained.The Cu substitution promotes the crystal structural stability and suppresses the dissolution of Mn,thus preventing the structure degradation of the layered cathode materials.A remarkably enhanced cyclability is realized for the Cu-doped cathode compared with that without Cu doping,with 83.8%capacity retention after 300 cycles at 100 mA·g^(-1).Our findings provide new insights into the design of atomic-level doping layered cathode materials constructed by MOFs for high-performance SIBs.
基金National Natural Science Foundation of China(62071291)
文摘Metasurfaces have great potential for flexible manipulation of electromagnetic wave polarizations and wavefronts.Here, we propose a general method for achieving independent wavefront manipulation in a single polarizationmultiplexing transmissive metasurface. As a proof of concept, we design a transmission-type anisotropic metasurface for independent wavefront manipulation in full-polarization channels. An x-polarized wave transmitted through such a metasurface could be converted into four outgoing beams with delicately designed polarization states that converge to specific positions for holographic imaging. The measured results are in good agreements with simulated ones, verifying the independent wavefront manipulations with arbitrary polarization conversions.Compared with the existing traditional meta-devices with single-polarization modulation, we achieve polarization-multiplexed metasurfaces with mixed polarization and phase control, which can greatly improve the functional richness of the system.
