NdCl_(3)-BaCl_(2)-NaCl三元体系相图的研究

借助于DTA和X射线衍射分析方法,研究了NdCl_(3)-BaCl_(2)-NaCl三元体系相图,发现本体系存在对应于NdCl_(3)、NaCl、α-BaCl_(2)、β-BaCl_(2)和Ba_(3)NdCl_(9)的5个液相面。6条二次结晶线,1个三元低共熔点E和三元转熔点P及一固相下形成的化合物。

新建构主义理论下的户外实践教学研究

在应用型大学建设的背景下,实践课程教学改革应根据新的教育环境和学情变化开展。在新建构理论指导下,提出新建构主义户外教学参与模式,构建户外实践教学生态系统,分析其结构和运行规律。在引导学生有效获得最大知识并促进学生成才目的基础之上,推进新建构主义理论延伸至教师成长和学生成才双重目的。针对户外实践教学问题,搭建“钉钉”户外实践教学互动系统,应用于旅游景区管理协同实践教学,为户外实践教学提供理论支持和实践指导。

Impact of Holocene environmental change on temporal-spatial distribution of Neolithic sites in Huaihe River Basin, Anhui Province

The Huaihe River basin of Anhui is not only a transitional zone of physical geography, but also a convergent area of many cultures in China. It is one of the sensitive ecotones to global changes and the birthplace of Chinese civilization. Using the field archaeological data and the sporo-pollens and the age data of the drilling cores, we analysed Neolithic cultural development and environmental evolution in the Huaihe River basin of Anhui. According to the combination of some research results in archaeology with environmental evolution research, this paper discusses the relationship between culture and environment in the Huaihe River basin of Anhui. The Neolithic cultural development was strongly impacted by the environmental change. The primitive culture （Shishanzi） was developed in the beginning of the Holocene Megathermal Period with distinct regional feature of the culture. From 6.5 kaBP to 5.5 kaBP, the climate changed warmer and wetter. The frequent occurrence of flood and waterlog due to such a climate regime and high sea level caused the earth＇s surface environment deteriorated in the Huaihe River basin of Anhui and the interruption of the Neolithic cultural development, hence a lack of archaeological sites. From 5.5 kaBP to 4.0 kaBP, the climate changed from wet to dry, the natural environment was propitious to human survival. Dawenkou Culture and Longshan Culture flourished in this period. The Neolithic cultural development, the number of the sites and their distribution characteristics of the sites in the study area differed apparently from those in Central China and Shandong Province.

Rise and decline of ancient salt industry revealed by Na and Ca concentrations in sediments at Zhongba site, Chongqing

Based on dynastic period division and AMS ^14 C dating performed on the sedimentary layers at Zhongba and Yuxi sites,and also the analysis of Na,Ca and Mg of 201 sedimentary samples from Zhongba site and that of Ca and Na in 47 sedimentary samples from Yuxi by using an inductively coupled plasma-mass spectrometry（ICP）,we found that there were 35 time periods when the contents of Ca and Na were reversely correlated,i.e.whenever the content of Ca was the highest,the content of Na was the lowest,and vice versa. Among them,there were 21 time periods when the content of Ca was the highest,and Na was the lowest,indicating that there were about 21 prosperous periods of ancient salt production at Zhongba site since 3000BC.Other 14 time periods with the peak values of Na while the low values of Ca indicate 14 declined periods of salt production at Zhongba site since 3000BC.The conclusion obtained from the reverse relationship between Ca and Na contents in this paper is consistent with that＂the salt production at Zhongba site started in the new stone age,developed in the Xia and Shang dynasties,reached at the heyday in periods from the Western Zhou to the Han Dynasties,maintained stable to develop in the Tang and the Song dynasties,and gradually declined after the Song Dynasty because the sea salt were conveyed into Sichuan region,however,still had production in the 1970s-1980s＂,educed from archeological exploration.All the above mentioned results indicate that there is a reverse relationship obviously between the contents of Na and Ca in sediments at Zhongba site for ancient salt production,which can be used to reveal the process of rise and decline of ancient salt industry at Zhongba site.

Environmental archaeology on Longshan Culture （4500-4000 aBP） at Yuhuicun Site in Bengbu, Anhui Province

Based on the samples collected from the west wall of the ABYT2004 at Yuhuicun Site in Bengbu, Anhui Province, the multi-environmental substitute indexes such as the grain-size, Rb/Sr, zircon crystal morphology and magnetic susceptibility were analyzed. The age of archaeological strata was determined by AMS^14C dating. According to the results, combined with the information of the ancient human activities and the cultural heritage data obtained from the Longshan cultural archaeological strata, it can be concluded that （1） Before 4500 aBP, the climate was humid and water level was high in the Huaihe River and its tributaries, the drainage basin and its surrounding areas were even flooded, so the site area was submerged and there were no human activities around the site. （2） About 4500 aBP, the climate began to become drier and water level of the Huaihe River and its tributaries began to decline, thus floodplain gradually appeared, Yuhuicun Site and Longshan Culture began to appear. （3） Around 4100 aBP, the climate was humid and rainfall was abundant, which resulted in frequent flood disasters in the whole Huaihe River Basin. （4） After 4100 aBP, the climate gradually transited to be cold and dry, agricultural production was constrained to reduce the food source, Yuhuicun Site was almost abandoned. （5） The environmental information in sedimentary strata and historical records based on ancient books agree with each other. In addition, Yuhuicun Site was related to Dayu Zhishui （Yu the Great in taming the floods） in ancient books.

Danxia landform genesis of the Qiyun Mountain, Anhui Province

The Danxia landform of Qiyun Mountain is mainly developed on the red granule conglomerates named Xiaoyan Group （K2x^1） of middle Cretaceous series, which is controlled mainly by three faulted zones, namely, Jingdezhen-Qimen faulted zone, Jiangwan-Jiekou compressional faulted zone and Kaihua-Chun＇an folding faulted zone. During the Cretaceous period, this area firstly experienced massif subsidence to become a continental faulted basin, then having thick Cretaceous red sediments accumulated on it. In the supervened neotectonism, this area experienced an uplifting process, which made the thick Cretaceous sediments into a mountain with an altitude of 500-600 m. After undergoing the processes of vertical joint development, weathering, denudation and transportation, as well as evidently differential weathering and denudation influenced by lithology and structure between sandstone and conglomerate, the grand Danxia landscape consisting of peak forests, steep cliffs, caves, mesas, castellated peaks, natural bridges and so on formed. The three nick points located respectively at 585 m, 400 m and 150 m generally reflect the three dominated uplifting processes during the neotectonism.

LIQUIDUS OF TERNARY SYSTEM LaCl_3-MgCl_2-LiCl

Two surfaces correponding to LaCl_3 and α-solid solution(MgCl_2.LiCl) respectively: and one secondary crystallization curve with a minimum M at 63.8 wt-％ LaCl_3,2.0 wt-％ MgCl_2,34.2 wt-％ LiCl and 492℃ were fonud by means of DTA.In combination with liquidus determination.an approach was also made to the alteration in LnCl_3-MgCl_2-LiCl svstem,where Lu denotes La.Ce.Pr or Nd.

Study on the NaCl-CaCl_2 Binary System

By use of micro-DTA technique as well as ambient and high temperature X-ray analysis the phase diagram of NaCl-CaCl_2 has been checked.It is.a simple eutectic system with a solid solubility in the sodium chloride side.The eutectic point is at 773K,49 mol% NaCl.The experimental results,especially those of the X-ray diffraction studies have showed that the incongruent compound 4NaCl-CaCl_2 does not exist in the NaCl-CaCl_2 system.

Climate changes in East China since the Late-glacial inferred from high-resolution mountain peat humification records

High-resolution peat humification records were obtained from Dajiuhu of the Shennongjia Mountains and Qianmutian of the Tianmu Mountains to study climate changes in East China.The analyses of pollen,organic matters,TOC,and Rb/Sr indicate a high degree of peat humification and thus strong decomposition of organic matter when climate was dry.Conversely,when climate was humid,the degree of humification is low because peat was preserved in a waterlogged condition.Peat humification from Dajiuhu occurred not only during the Younger Dryas(about 11.4-12.6 cal ka BP),the Blling-Allerd Warm Period(12.6-15.2 cal ka BP),and the Oldest Dryas(about 15.2-16.0 cal ka BP),but also during the early Holocene(about 11.4-9.4 cal ka BP),the 8.2 cal ka BP cold event,and the Holocene Optimum(about 7.0-4.2 cal ka BP).Both peat humification records since nearly 5 ka BP are consistent,showing that mountain peatland has synchronous responses to the East Asia monsoon-induced precipitation.The LOI data confirm the above observation.The monsoon precipitation since nearly 5 ka BP recorded in these two peat profiles can be divided into three phases.During 4.9-3.5 ka BP,precipitation amount was high but fluctuated greatly.During 3.5-0.9 ka BP,precipitation amount was low.During 0.9-0 ka BP,degree of humification reduced gradually,indicating the increase of monsoon precipitation.Contrast to other high-resolution records from East China monsoon region shows that the monsoon precipitation records of the two peat profiles since nearly 16 ka BP are controlled by a common forcing mechanism of summer solar radicalization in the Northern Hemisphere.

Characteristics of paleoflood deposits archived in unit T0403 of Yuxi Site in the Three Gorges reservoir areas,China

Based on the detailed analyses,multi-proxies such as AMS 14 C dating,grain size,component and morphology of heavy minerals,micromorphology of zircon,magnetic susceptibility,Rb/Sr and Hg content are used to research the paleoflood sediments archived in the Yuxi Site.The research indicates that, since 7.6 kaBP,at least 16 times of paleoflood with water level above Wusong Elevation 147.024 m(a.s.l.) left deposits in the Neolithic layers of unit T0403 from the Yuxi Site.The results are induced from the following aspects:(1)The plaeoflood sediments take on great similarities with modern flood sediments in the Yuxi Site and Zhongba Site in probability cumulative curves which mainly show a pattern of 3 segments in fluvial pattern.(2)There is some resemblance between the heavy mineral components and the zircon shape characteristics of paleoflood deposits and those of modern flood deposits.(3) Magnetic susceptibility values(40.44―70.10SI)are lower than those of sediments from cultural layers (59.59―188.68SI).(4)Hg values(290.71―742.51 ng/g)are lower than those of sediments from cultural layers(344.16―10518.17 ng/g).(5)Rb/Sr values are higher than those of sediments from cultural layers, while those of the 4th,5th,6th,7th,8th cultural layers are high,which shows that they are inundated by paleoflood.The reason for many flood deposits existing is related to the site situated on the first terrace where the Yuxi River joins with the Yangtze River.As there are some similarities between the plaeoflood sediments and those of the Zhongba Site,it is feasible to confirm the existence of paleoflood sediments based on the above points.

Identifying paleoflood deposits archived in Zhongba Site,the Three Gorges reservoir region of the YangtzeRiver,China

Based on the principle that the present is the key to the past , detailed analyses, such as AMS 14C dating, grain size, component and morphology of heavy minerals, micro-morphology of zircon, Rb/Sr, magnetic susceptibility and total organic carbon (TOC), were conducted to identify paleoflood sediments archived in Zhongba Site. The results indicate that the plaeoflood sediments bear great similarities with modern flood sediments in the following aspects: (1) probability cumulative curves mainly show a pattern of 3―4 segments; (2) grain-size distribution of suspended matter ranges between 3 and 10Ф; (3) the sediments are well-sorted, most of which are suspended matter (>50%); (4) the same species, quantity and morphology of heavy minerals; (5) scanning electronic microscope images show that shapes of zircon are mainly oval and nearly spheral, rounded due to long-distance transport; (6) higher Rb/Sr values (0.55―0.66)than those of sediments from cultural layers (0.03―0.26); (7) magnetic susceptibility values (133.73―433.05 10-6m3/kg) are lower than those of sediments from cultural layers (959.25―2442.44 10?6 m3/kg); (8) TOC (0.14%―0.33%) are lower than those of sediments from cultural lay-ers (1.13%―2.95%). Our results demonstrate that, except for the 1981 flood, there are at least six paleoflood events that occurred during the Qing Dynasty, the middle of Song Dy-nasty, the early Warring States (400BC―350BC), the West Zhou Dynasty (920BC―900BC), the Xia Dynasty (2070BC―1600BC), and the late Neolithic Age (3000BC―2300BC), respectively .

High-resolution geochemistry records of climate changes since late-glacial from Dajiuhu peat in Shennongjia Mountains,Central China

A peat core with depths of 297 cm was obtained from the Dajiuhu Basin(31°29′27″N,109°59′45″E,1760 m)in Hubei Province,Central China.10 AMS ages provide a time control and reveal that this core spans the past about 16.0 kaBP(calibrated age)(1 4C age:13.3 kaBP).Multi-proxy indexes analysis of geochemistry shows the following character of climate and environmental changes since about 16 kaBP:(1) The climate during the late-glacial period was cold and wet as a whole,but fluctuated continually.11.4- 12.6 cal.kaBP,12.6-15.2 cal.kaBP and 15.2-16 kaBP were corresponding respectively to the Younger Drays,Bφlling-Allerφd Warm Period and the Oldest Drays.(2)Inheriting the some climate characteristics of the late-glacial,the climate during the early-Holocene was wet and temperature increased gradually,during which an obvious dry event around 10.6 cal.kaB appeared.(3)The climate during the mid-Holocene was genarally warm and wet.During 9.2-7.5 kaBP,temperature increased gradually, precipitation was less comparatively and the 8.2 kaBP cold event which might be representative in the globe was reflected markedly.Then,multi-proxy records were relatively stable during 6.7-4.2 kaBP, which shows the best water and thermal condition in the Holocene Optimum.(4)Around 4.2 kaBP,the climate and environment transform from warm and wet to cool and dry,which may result in the collapse of the Neolithic Culture and midwifery the civilization of Xia Dynasty in this region.After 0.9 kaBP,the climate turned cool and wet.Climate and environmental changes archived in Dajiuhu peat respond to the global changes since the late-glacial period and can be contrasted to the changes recorded in other high-resolution archives from the East Asia Monsoon region,which take on the variety model that the monsoon strengthened abruptly after the late-glacial,was strong during the early Holocene,subse- quently declined and became weak after the middle Holocene with dry climate.According to our analysis,the driving mechanism should be the response of solar radiation changes in the East Asia Monsoon region at middle latitudes.

Impact of Holocene climate change on the prehistoric cultures of Zhejiang region, East China

The temporal-spatial distribution features of prehistoric cultures since the Holocene in Zhejiang region were comparatively analyzed based on GIS spatial analysis. Results show that the prehistoric cultures expanded gradually in this region before 4000 cal. a BP. The notable expansions occurred twice, one in the Majiabang-Hemudu cultural period, the other in the Liangzhu cultural period. Meanwhile, the prehistoric cultures were disseminated from west to east coast along river valleys. After 4000 cal. a BP, as represented by the Maqiao Culture, the distributed area of each prehistoric culture contracted. This is obviously due to the termination of spreading trends to east coast, which was simultaneously accompanied by two different modes of production and economic transitions in the north and south Zhejiang region respectively. The distribution of prehistoric cultures was closely related with Holocene sea-level fluctuations, especially on the banks of Hangzhou Bay, where the distribution changes of prehistoric cultural sites were greatly affected by sea-level changes, with the closest relationships between them. After 7000 cal. a BP, the process of lowered sea-level and regression-epeirogenesis provided wider terrestrial living spaces for prehistoric inhabi- tants. Based on the comparative analyses of the changes of prehistoric cultures and the en- vironmental evolution information recorded in the Qianmutian subalpine peat of Mt. Tianmu and muddy area on the inner shelf of the East China Sea, it is indicated that the changes of prehistoric cultures were synchronized with environmental changes in Zhejiang region. Before 4000 cal. a BP, the eastward expansion of prehistoric cultures in Zhejiang occurred under the background of the Holocene Optimum, and was the expansion and extension under the joint influences of agricultural civilization and maritime civilization. However, after 4000 cal. a BP, the qeographical contraction of prehistoric cultures in ZheiianQ occurred under the back-ground of dry-cold climate trend and deterioration of coastal marine environment. It is evidenced from the above fact that the development, expansion and contraction of prehistoric cultures are positively correlated to environmental change. The change of the climatic environment is just the underlying reason for these changes and transitions of production modes and economic forms. Therefore, the climatic environment is the dominant factor of prehistoric culture vicissitudes in Zhejiang region, which has exerted great influence on distribution, dissemination, expansion and transmutation of the culture.

Spatial pattern and temporal trend of prehistoric human sites and its driving factors in Henan Province, Central China

The Yangshao Culture （approx. 6.9-5.5 ka BP） and the Longshan Culture （approx. 4.6-4.0 ka BP） played important roles in Henan＇s Neolithic Period. Due to spatial distribution of the Yangshao cultural sites, they had a river-oriented trend in comparison with those in the Longshan Period. Apart from terrain factors, distribution of the sites in both periods is subject to paleo-environmental changes. The Yangshao Culture originated in Holocene Optimum Period, and the Longshan Culture started in climatic fluctuations prior to Neolithic ending. But the latter owned more sites and wider scopes than the former did. Both the Cultures devel- oped fast in rich rainfall and warm periods, and withered for abrupt cooling events in 5.4 ka BP and 4.0 ka BP respectively. Therefore, the sustainability of Henan＇s Neolithic Cultures is not good as expected. Whilst, the ancient farming acted an irreplaceable part in distribution of human sites, and the need for farming space prompted human sites to expand from the western hilly areas towards the eastern plain of Henan. Moreover, the neighboring cultures poured into Henan and complicated the cultural patterns. Besides, characteristics of the sites in the Erlitou Period suggest that some social factors disturbed the spatial pattern at the end of Neolithic age in Henan.