A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals ...A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm, b=1.93224（11） nm, c=1.36798（10） nm, V=4.7763（5） nm3 and R1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and π-π interactions. Compound 1 was further characterized by powder X-ray diffraction（PXRD）, infrared（IR） spectroscopy, thermogravimertic analysis（TG） and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.21204034, 21301024） and the Fundamental Research Funds for the Central Universities of China（No.N120305003）.
文摘A cobalt（II） coordination polymer, [Co（dimto）2（H2O）2]·4H2O[1, dimto=4,6-di（1-imidazolyl）-1,3,5- triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca（No.73） with a=1.80696（12） nm, b=1.93224（11） nm, c=1.36798（10） nm, V=4.7763（5） nm3 and R1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and π-π interactions. Compound 1 was further characterized by powder X-ray diffraction（PXRD）, infrared（IR） spectroscopy, thermogravimertic analysis（TG） and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.
