The relaxation paths for triphenylamine（TPA）-2,3-dicyanopyrazino phenanthrene（DCPP）, which has a pull-push structure, were investigated via steady-state, time-resolved spectroscopy involving transient absorption a...The relaxation paths for triphenylamine（TPA）-2,3-dicyanopyrazino phenanthrene（DCPP）, which has a pull-push structure, were investigated via steady-state, time-resolved spectroscopy involving transient absorption and time-correlated single photon counting. By changing the solvent polarity we found that an intramolecular charge transfer（ICT） state acting as a ＂bright＂ state was responsible for the fluorescence character of TPA-DCPP. Meanwhile, a ＂dark＂ state gradually appeared and competed with the ICT state. This was likely to be responsible for the polarity-dependent evolution of fluorescence intensity and fluorescence lifetime. The temperature-dependent fluorescence character of the TPA-DCPP in toluene exhibited ICT processes at high temperatures prior to the relaxation path from the initial excited state to the ground state. Our results provide useful insight into the optoelectronic properties of these kinds of molecules.展开更多
A series of three-dimensional opal photonic crystals based on the polymer was synthesized and applied inthe field of photo-induced birefringence. The data show that the photo-induced birefringence（PIB） of pure Sudan...A series of three-dimensional opal photonic crystals based on the polymer was synthesized and applied inthe field of photo-induced birefringence. The data show that the photo-induced birefringence（PIB） of pure Sudan IIIfilm could be enhanced by increasing the thickness of azo films. When Sudan III was distributed on thethree-dimensional opal photonic crystals, the photo-induced birefringence process could be modulated. In addition,the data also exhibit that the PIB processes with different pumping polarization directions are sensitive to the role ofphotonic crystals. The results could be beneficial to further understanding the photo-induced birefringence and uti-lizing the photonic crystals.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.51502109, 21573094, 11274142, 11474131）, the Science and Technology Projects in the 13th Five-year Plan in the Education Department of Jilin Province, China（No.2016-402）, the National Fund for Fostering Talents of Basic Science, China（No.J1103202） and the Chinese Scholarship Council for Providing Financial Support During Visiting University of California at Irvine, USA.
文摘The relaxation paths for triphenylamine（TPA）-2,3-dicyanopyrazino phenanthrene（DCPP）, which has a pull-push structure, were investigated via steady-state, time-resolved spectroscopy involving transient absorption and time-correlated single photon counting. By changing the solvent polarity we found that an intramolecular charge transfer（ICT） state acting as a ＂bright＂ state was responsible for the fluorescence character of TPA-DCPP. Meanwhile, a ＂dark＂ state gradually appeared and competed with the ICT state. This was likely to be responsible for the polarity-dependent evolution of fluorescence intensity and fluorescence lifetime. The temperature-dependent fluorescence character of the TPA-DCPP in toluene exhibited ICT processes at high temperatures prior to the relaxation path from the initial excited state to the ground state. Our results provide useful insight into the optoelectronic properties of these kinds of molecules.
文摘A series of three-dimensional opal photonic crystals based on the polymer was synthesized and applied inthe field of photo-induced birefringence. The data show that the photo-induced birefringence（PIB） of pure Sudan IIIfilm could be enhanced by increasing the thickness of azo films. When Sudan III was distributed on thethree-dimensional opal photonic crystals, the photo-induced birefringence process could be modulated. In addition,the data also exhibit that the PIB processes with different pumping polarization directions are sensitive to the role ofphotonic crystals. The results could be beneficial to further understanding the photo-induced birefringence and uti-lizing the photonic crystals.
