载体ZrO_(2)的d带电子对Ni_(13)催化CH_(4)脱氢过程的影响

C−H键活化是甲烷转化的关键,分散于ZrO_(2)(111)表面的活性Ni_(13)微粒能实现这一过程。密度泛函理论结果表明,相比Ni_(13)催化过程,Ni_(13)-ZrO_(2)(111)更能活化CH_(4)逐步脱氢并稳定其解离物种;且在载体ZrO_(2)存在下,C−H键长增加,C−H断键活化能降低,放热量增多,达过渡态时,解离H与残留CH_(x)间距减小,因此,负载催化剂Ni_(13)-ZrO_(2)(111)具有更好的催化性。究其原因,对于Ni−C−H,ZrO_(2)丰富的d带电子使得Ni 3d电子密度增强,C 2p与Ni 3d轨道重叠增多,Ni−C键增强,C−H键减弱,基于此,CH_(x)吸附增强,C−H键活性亦增强。因此,载体ZrO_(2)的d带为Ni_(13)活化CH_(4)促进C−H键解离提供着电子。

超声波技术在肉品加工中的应用以及对肉品风味前体物质的影响

超声波加工技术属于非热加工的一种,其空化效应、热效应和机械作用在肉品加工领域的研究具有重要意义。本文综述了超声波技术和超声波在肉品的杀菌、腌制、嫩化、解冻、无损检测上的应用,及其对肉类风味前体物质氨基酸、脂肪酸的影响。最后简要展望超声波技术在肉品加工中的应用研究,为超声波在肉品加工中的高效应用以及增强肉的风味品质提供参考。

添加多糖和氯化钙对猪皮冻凝胶品质的优化

为了研究添加多糖(结冷胶和菊粉)和氯化钙对猪皮冻凝胶品质的影响,单因素实验以猪皮冻硬度、弹性、熔点、感官评分为评价指标,最后通过Box-Behnken响应面分析法,选取感官评分建立回归方程得到最优添加量。结果表明,添加结冷胶提高了猪皮冻熔点、硬度和弹性,添加氯化钙促进结冷胶提高了猪皮冻熔点,添加菊粉改善了猪皮冻的适口性。三种物质的添加在总体上提高了猪皮冻的感官得分(未优化:7.58,优化后:8.85)。结论:最佳添加条件为:结冷胶0.45 g/100 g、氯化钙0.06 g/100 g、菊粉3.77 g/100 g,且猪皮冻理论感官得分为8.91。在此条件下,优化后的猪皮冻实际感官得分为8.85,与试验预测值接近。硬度为340.08g,弹性为0.92,熔点为43.4℃,并且微观网络结构更为致密。因此,通过添加结冷胶、菊粉、氯化钙可以改善猪皮冻品质,使感官接受度更高,为猪皮冻进一步加工以及相关产品的开发提供了理论依据。

Extracting useful high-frequency information from wide-field electromagnetic data using time-domain signal reconstruction

The wide-field electromagnetic method is widely used in hydrocarbon exploration,mineral deposit detection,and geological disaster prediction.However,apparent resistivity and normalized field amplitude exceeding 2048 Hz often exhibit upward warping in data,making geophysical inversion and interpretation challenging.The cumulative error of the crystal oscillator in signal transmission and acquisition contributes to an upturned apparent resistivity curve.To address this,a high-frequency information extraction method is proposed based on time-domain signal reconstruction,which helps to record a complete current data sequence;moreover,it helps estimate the crystal oscillator error for the transmitted signal.Considering the recorded error,a received signal was corrected using a set of reconstruction algorithms.After processing,the high-frequency component of the wide-field electromagnetic data was not upturned,while accurate high-frequency information was extracted from the signal.Therefore,the proposed method helped effectively extract high-frequency components of all wide-field electromagnetic data.

音圈马达生产过程的质量控制研究

针对某公司音圈马达(VCM)装配线的制造过程良品率异常问题,应用质量管理工具对产品的质量影响因素进行分析,从焊接不良、变形及破损、点胶不良等方面提出质量控制的改善措施,并对改善后的实施效果进行了评价。研究结果表明,改善措施的实施基本消除了过程的异常波动,提高了产品合格率。