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四氢萘为良溶剂液/液界面法制备多级C60晶体(英文) 被引量:2
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作者 张琳雯 周升菊 +2 位作者 陈孟军 尹克样 李洪光 《新型炭材料》 SCIE EI CAS CSCD 北大核心 2019年第3期238-246,共9页
采用液/液界面法制备了不同形貌的多级C60结构。以四氢萘作良溶剂,异丙醇、乙醇、甲醇作不良溶剂,通过优化实验条件,成功制备了形貌特殊、界面清晰的C60晶体结构。此晶体表面粗糙度能通过乙醇洗涤得到进一步提高。通过对晶体内部形貌的... 采用液/液界面法制备了不同形貌的多级C60结构。以四氢萘作良溶剂,异丙醇、乙醇、甲醇作不良溶剂,通过优化实验条件,成功制备了形貌特殊、界面清晰的C60晶体结构。此晶体表面粗糙度能通过乙醇洗涤得到进一步提高。通过对晶体内部形貌的观察,证实了晶体的多级自组装结构。红外、拉曼光谱和热重分析表明晶体仅由C60组成,不含溶剂分子。在纳米尺度上,通过X-射线衍射证实了分子水平上C60分子按照面心立方结构方式排列。此法制备的多级结构C60晶体比高温转变、溶剂热处理等方法更为简易,为多级材料制备提供了一条新路径。 展开更多
关键词 富勒烯C60晶体 多级结构 液-液界面法 面心立方晶格
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Simulation on dissolute and dust dispersion in comprehensive mechanized heading face with forced-exhaust ventilation 被引量:21
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作者 NIE Wen CHENG Wei-min +3 位作者 HAN Li zhou sheng-ju YU Yan-bin ZHAO Shan-shan 《Journal of Coal Science & Engineering(China)》 2011年第3期298-304,共7页
According to the characteristics of comprehensive mechanized heading face, established the mathematical model of single-phase air flow with κ-ε two equations model, and have established κ-ε-θ-κp mathematic model... According to the characteristics of comprehensive mechanized heading face, established the mathematical model of single-phase air flow with κ-ε two equations model, and have established κ-ε-θ-κp mathematic model to solve two-phase flow of gas and particles in dust space with eulerian-eulerian method and eulerian-lagrangian method. Numerical solution of gas-particle two-phase flow was put forward based on collocated grid SIMPLE algorithm. Moreover, numerical simulation of dust concentration in fully mechanized caving face was carded out by using Fluent software. Finally, when in forced-exhaust ventilation circumstance, drawer type fan drum have less dust absorption, and most of dust spread to the other site; the dust concentration is inversely proportional to the distance from tunneling head, and the dust concentration has already diffused to decrease below 102 mg/m3 at the position ofx=12 m. Dust are more focused on relative side(in the range about y from 0 to 2 meter) of roadway space of press-ventilated fan drum, especially between tunneling place and drawer type fan drum; the roadway with road header have a higher dust concentration. These conclusions provide reliable theory basis for the dust prevention in comprehensive mechanized heading face. 展开更多
关键词 dissolute dust dispersion forced-exhaust ventilation circumstance κ-ε-θ-κp mathematical model comprehensive digging
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