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基于共轭共聚物网络的动态褶皱的多重调控
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作者 钱杰 章露枝 +4 位作者 王泽鸿 吴诗杰 姜学松 林绍梁 姚远 《Science China Materials》 SCIE EI CAS CSCD 2024年第1期363-371,共9页
环境刺激响应的动态微/纳米图案可调节表面特性,为智能表面的按需制备提供了有效的解决方案.我们合成了一种光响应共轭聚合物(P(AEG-AAzo-AAN)),基于简单的策略构建了光驱动的双层动态褶皱图案系统.聚合物所含蒽侧基的光二聚和偶氮苯侧... 环境刺激响应的动态微/纳米图案可调节表面特性,为智能表面的按需制备提供了有效的解决方案.我们合成了一种光响应共轭聚合物(P(AEG-AAzo-AAN)),基于简单的策略构建了光驱动的双层动态褶皱图案系统.聚合物所含蒽侧基的光二聚和偶氮苯侧基的光异构化可以分别调节交联密度和应力松弛,从而决定褶皱的产生/擦除,实现多级次褶皱的按需制备.硫酸掺杂后,褶皱图案能够对湿度做出响应,薄膜变为半导体.这种多重响应动态褶皱可能在智能显示器和防伪标签中获得潜在的应用. 展开更多
关键词 防伪标签 共轭聚合物 光驱动 光异构化 多重响应 应力松弛 交联密度 策略构建
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具有力学增强及抗冲击性能的光固化自褶皱涂层
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作者 李瑾 张晓亮 +7 位作者 苏志龙 李甜甜 王泽鸿 董仕龙 徐凡 马晓东 印杰 姜学松 《Science Bulletin》 SCIE EI CAS CSCD 2023年第19期2200-2209,M0004,共11页
表面聚合物涂层作为保护层广泛应用于表面防腐、防渗透和抗冲击等各种领域,如何在已有材料体系和工艺条件下提高涂层机械力学性能,是一个重要但具有挑战性的问题.受自下而上的制造工艺和生物体的层级结构的能量耗散机制的启发,本文开发... 表面聚合物涂层作为保护层广泛应用于表面防腐、防渗透和抗冲击等各种领域,如何在已有材料体系和工艺条件下提高涂层机械力学性能,是一个重要但具有挑战性的问题.受自下而上的制造工艺和生物体的层级结构的能量耗散机制的启发,本文开发了一种具有自褶皱表面形态和梯度交联结构的光固化涂层.理论模拟和实验结果表明,表面自褶皱的独特形貌和体系内梯度交联结构有助于提升涂层的力学性能及抗冲击性.这种光固化自褶皱涂层为设计功能抗冲击聚合物涂层材料开辟了新的途径. 展开更多
关键词 聚合物涂层 机械力学性能 交联结构 光固化 抗冲击性 防渗透 表面形态 制造工艺
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Evolutionary characteristics and driving factors of carbon emission performance at the city level in China 被引量:1
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作者 Shaojian wang zehong wang Chuanglin FANG 《Science China Earth Sciences》 SCIE EI CSCD 2022年第7期1292-1307,共16页
To achieve carbon peak targets,realize carbon neutrality vision,and tackle global climate change,China must improve the carbon emission performance at the city level.Based on the carbon emission performance of 191 pre... To achieve carbon peak targets,realize carbon neutrality vision,and tackle global climate change,China must improve the carbon emission performance at the city level.Based on the carbon emission performance of 191 prefecture-level cities in China from 1997 to 2017,this paper analyses the evolution characteristics of urban carbon emission performance from three aspects:the overall spatial and temporal evolution,the differences according to both region and city size,and the differences among clusters categorized by carbon emission performance at the city level.This paper also reveals the impact of the social and economic transition on China’s carbon emission performance.The results show that:(1)The overall level of carbon emission performance of Chinese cities is low,and there is a downward trend during the study period.The differences in carbon emission performance among cities are convergent,but there is a wide gap between high and low values.(2)The carbon emission performance of cities in eastern coastal areas is higher than that in non-coastal areas cities.Large urban agglomerations and economically developed regions,such as provincial capitals,are the agglomeration areas of high urban carbon emission performance values.(3)The carbon emission performance level of cities with similar sizes will converge.At the same time,such changes will enhance the differences among carbon emission performances at the city level within the same region.(4)Cities that belong to high urban carbon emission performance clusters are mainly distributed in the eastern region.Such cities are classified into large cities,supercities,and megacities.Compared with low urban carbon emission performance clusters,cities in high urban carbon emission performance clusters show a higher proportion in the medium-high level and high level of carbon emission performance.Moreover,cities in high urban carbon emission performance clusters are more likely to improve their urban carbon emission performance.(5)The economic agglomeration effect,industrial structure adjustment and carbon intensity reduction have a significant impact on improving urban carbon emission performance.Population agglomeration has an incremental effect,and the anticipated benefits of environmental regulation have yet to be fully realized.The impacts of different clusters and different regions are variable.Finally,this paper advances policy enlightenment according to its research findings. 展开更多
关键词 Carbon emission performance at the city level Evolution characteristics Regional difference Influencing factors
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