At present,with the increasing application needs of phosphor-converted white light-emitting diode(wLED),the synthetic efficiency and thermal stability of phosphor become urgent problems.Herein,this research reports a ...At present,with the increasing application needs of phosphor-converted white light-emitting diode(wLED),the synthetic efficiency and thermal stability of phosphor become urgent problems.Herein,this research reports a microwave-assisted fast synthesis approach to obtain a Sm^(3+)-activated borotellurate Na_(2)Y_(2)TeO_(4)(BO_(3))_(2)(NYTB)red phosphor with high crystallinity,excellent thermostability,and low chromaticity shift.For the NYTB-based phosphor,in contrast to the conventional solid-state synthesis,the microwave-assisted synthesis method involves lower synthesis temperature and shorter processing time.Additionally,the concentration quenching mechanism was determined.The w-LED device packaged with the studied phosphor exhibits a near-standard white light with proper CCT and high Ra parameters.展开更多
基金Project supported by the National Natural Science Foundation of China(22165031,21761034)NationalUndergraduate Innovation and Entrepreneurship Foundation(202210673034)Scientific Research Foundation of Education Departmentof Yunnan province(2022Y001)。
文摘At present,with the increasing application needs of phosphor-converted white light-emitting diode(wLED),the synthetic efficiency and thermal stability of phosphor become urgent problems.Herein,this research reports a microwave-assisted fast synthesis approach to obtain a Sm^(3+)-activated borotellurate Na_(2)Y_(2)TeO_(4)(BO_(3))_(2)(NYTB)red phosphor with high crystallinity,excellent thermostability,and low chromaticity shift.For the NYTB-based phosphor,in contrast to the conventional solid-state synthesis,the microwave-assisted synthesis method involves lower synthesis temperature and shorter processing time.Additionally,the concentration quenching mechanism was determined.The w-LED device packaged with the studied phosphor exhibits a near-standard white light with proper CCT and high Ra parameters.