A novel interface design is proposed for carbon-based,all-inorganic CsPbIBr2 perovskite solar cells(PSCs)by introducing interfacial voids between TiO2 electron transport layer and CsPbIBr2 absorber.Compared with the g...A novel interface design is proposed for carbon-based,all-inorganic CsPbIBr2 perovskite solar cells(PSCs)by introducing interfacial voids between TiO2 electron transport layer and CsPbIBr2 absorber.Compared with the general interfacial engineering strategies,this design exempts any extra modification layer in final PSC.More importantly,the interfacial voids produced by thermal decomposition of 2-phenylethylammonium iodide trigger three beneficial e ects.First,they promote the light scattering in CsPbIBr2 film and thereby boost absorption ability of the resulting CsPbIBr2 PSCs.Second,they suppress recombination of charge carriers and thus reduce dark saturation current density(J0)of the PSCs.Third,interfacial voids enlarge built-in potential(Vbi)of the PSCs,awarding increased driving force for dissociating photo-generated charge carriers.Consequently,the PSC yields the optimized e ciency of 10.20%coupled with an open-circuit voltage(Voc)of 1.338 V.The Voc achieved herein represents the best value among CsPbIBr2 PSCs reported earlier.Meanwhile,the non-encapsulated PSCs exhibit an excellent stability against light,thermal,and humidity stresses,since it remains^97%or^94%of its initial e ciency after being heated at 85℃for 12 h or stored in ambient atmosphere with relative humidity of 30–40%for 60 days,respectively.展开更多
All-inorganic CsPbBr_(3)perovskite solar cells(PSCs)have attracted more attentions due to the excellent environmental stability,however,the wide bandgap and relatively poor crystallinity of CsPbBr_(3)have been the mai...All-inorganic CsPbBr_(3)perovskite solar cells(PSCs)have attracted more attentions due to the excellent environmental stability,however,the wide bandgap and relatively poor crystallinity of CsPbBr_(3)have been the main obstacle to improve their power conversion efficiency(PCE).Herein,we proposed an efficient and simple strategy of precursor additive in the two-step aqueous-solution method,the resulted CsPbBr_(3)film has achieved more uniform grain size,almost pure perovskite phase,smoother surface,less defects,enhanced light absorption and longer carrier lifetime.This is due to the rapid evaporation of additive(IPA and CH_(3)OH)in the CsBr/H_(2)O precursor leads to a relatively higher local CsBr concentration on the surface of PbBr_(2),which can provide more nucleation sites and accelerate the crystallization of perovskite.Further,when utilizing the optimal additive of 5%(in volume)IPA,the HTM-free carbonbased CsPbBr_(3)PSCs obtained a PCE improvement from 9.09%to 10.29%,and an ultrahigh fill factor(FF)of 85.21%.What is more,by adding 0.1 mol/L PbCl_(2)into the PbBr_(2)solution in the first step,the open circuit voltage of device has increased from 1.36 V to 1.48 V,the champion PCE reached 10.37%(steady output PCE of 10.17%),and the non-encapsulated device could maintain 85%of its initial efficiency after 50 d in the air.This work provides a cost-effective approach to grow CsPbBr_(3)film and boosts the efficiency benchmark of the CsPbBr_(3)PSCs to more than 10%,it is desirable that the highly efficient and stable CsPbBr_(3)PSCs can be developed in future.展开更多
Ensuring the safe and efficient operation of self-driving vehicles relies heavily on accurately predicting their future trajectories.Existing approaches commonly employ an encoder-decoder neural network structure to e...Ensuring the safe and efficient operation of self-driving vehicles relies heavily on accurately predicting their future trajectories.Existing approaches commonly employ an encoder-decoder neural network structure to enhance information extraction during the encoding phase.However,these methods often neglect the inclusion of road rule constraints during trajectory formulation in the decoding phase.This paper proposes a novel method that combines neural networks and rule-based constraints in the decoder stage to improve trajectory prediction accuracy while ensuring compliance with vehicle kinematics and road rules.The approach separates vehicle trajectories into lateral and longitudinal routes and utilizes conditional variational autoencoder(CVAE)to capture trajectory uncertainty.The evaluation results demonstrate a reduction of 32.4%and 27.6%in the average displacement error(ADE)for predicting the top five and top ten trajectories,respectively,compared to the baseline method.展开更多
基金financial support from the National Natural Science Foundation of China(Nos.61804113,61874083)Initiative Postdocs Supporting Program(BX20190261)+1 种基金the National Natural Science Foundation of Shaanxi Province(2018ZDCXL-GY-08-02-02 and 2017JM6049)the Fundamental Research Funds for the Central Universities(JB181107 and JBX171103).
文摘A novel interface design is proposed for carbon-based,all-inorganic CsPbIBr2 perovskite solar cells(PSCs)by introducing interfacial voids between TiO2 electron transport layer and CsPbIBr2 absorber.Compared with the general interfacial engineering strategies,this design exempts any extra modification layer in final PSC.More importantly,the interfacial voids produced by thermal decomposition of 2-phenylethylammonium iodide trigger three beneficial e ects.First,they promote the light scattering in CsPbIBr2 film and thereby boost absorption ability of the resulting CsPbIBr2 PSCs.Second,they suppress recombination of charge carriers and thus reduce dark saturation current density(J0)of the PSCs.Third,interfacial voids enlarge built-in potential(Vbi)of the PSCs,awarding increased driving force for dissociating photo-generated charge carriers.Consequently,the PSC yields the optimized e ciency of 10.20%coupled with an open-circuit voltage(Voc)of 1.338 V.The Voc achieved herein represents the best value among CsPbIBr2 PSCs reported earlier.Meanwhile,the non-encapsulated PSCs exhibit an excellent stability against light,thermal,and humidity stresses,since it remains^97%or^94%of its initial e ciency after being heated at 85℃for 12 h or stored in ambient atmosphere with relative humidity of 30–40%for 60 days,respectively.
基金the National Natural Science Foundation of China under Grants 62004151,62274126 and 62204189the Special Financial Grant from the China Postdoctoral Science Foundation under Grant 2020T130490+1 种基金Young Talent Fund of Association for Science and Technology in Shaanxi under Grant 20220115Fundamental Research Funds for the National 111 Center.
文摘All-inorganic CsPbBr_(3)perovskite solar cells(PSCs)have attracted more attentions due to the excellent environmental stability,however,the wide bandgap and relatively poor crystallinity of CsPbBr_(3)have been the main obstacle to improve their power conversion efficiency(PCE).Herein,we proposed an efficient and simple strategy of precursor additive in the two-step aqueous-solution method,the resulted CsPbBr_(3)film has achieved more uniform grain size,almost pure perovskite phase,smoother surface,less defects,enhanced light absorption and longer carrier lifetime.This is due to the rapid evaporation of additive(IPA and CH_(3)OH)in the CsBr/H_(2)O precursor leads to a relatively higher local CsBr concentration on the surface of PbBr_(2),which can provide more nucleation sites and accelerate the crystallization of perovskite.Further,when utilizing the optimal additive of 5%(in volume)IPA,the HTM-free carbonbased CsPbBr_(3)PSCs obtained a PCE improvement from 9.09%to 10.29%,and an ultrahigh fill factor(FF)of 85.21%.What is more,by adding 0.1 mol/L PbCl_(2)into the PbBr_(2)solution in the first step,the open circuit voltage of device has increased from 1.36 V to 1.48 V,the champion PCE reached 10.37%(steady output PCE of 10.17%),and the non-encapsulated device could maintain 85%of its initial efficiency after 50 d in the air.This work provides a cost-effective approach to grow CsPbBr_(3)film and boosts the efficiency benchmark of the CsPbBr_(3)PSCs to more than 10%,it is desirable that the highly efficient and stable CsPbBr_(3)PSCs can be developed in future.
基金supported in part by the National Natural Science Foundation of China under Grant 52372393,62003238in part by the DongfengTechnology Center(Research and Application of Next-Generation Low-Carbonntelligent Architecture Technology).
文摘Ensuring the safe and efficient operation of self-driving vehicles relies heavily on accurately predicting their future trajectories.Existing approaches commonly employ an encoder-decoder neural network structure to enhance information extraction during the encoding phase.However,these methods often neglect the inclusion of road rule constraints during trajectory formulation in the decoding phase.This paper proposes a novel method that combines neural networks and rule-based constraints in the decoder stage to improve trajectory prediction accuracy while ensuring compliance with vehicle kinematics and road rules.The approach separates vehicle trajectories into lateral and longitudinal routes and utilizes conditional variational autoencoder(CVAE)to capture trajectory uncertainty.The evaluation results demonstrate a reduction of 32.4%and 27.6%in the average displacement error(ADE)for predicting the top five and top ten trajectories,respectively,compared to the baseline method.
基金financially supported by the National Natural Science Foundation of China (61804113, 61874083 and 61704128)the Innovative Postdocs Supporting Program (BX20190261)+1 种基金the China Postdoctoral Science Foundation (2019M663628)the Natural Science Foundation of Shaanxi Province (2018ZDCXL-GY-0802-02 and 2017JM6049)