Pushing the Electrochemical Performance Limits of Polypyrrole Toward Stable Microelectronic Devices

Conducting polymers have achieved remarkable attentions owing to their exclusive characteristics,for instance,electrical conductivity,high ionic conductivity,visual transparency,and mechanical tractability.Surface and nanostructure engineering of conjugated conducting polymers offers an exceptional pathway to facilitate their implementation in a variety of scientific claims,comprising energy storage and production devices,flexible and wearable optoelectronic devices.A two-step tactic to assemble high-performance polypyrrole(PPy)-based microsupercapacitor(MSC)is utilized by transforming the current collectors to suppress structural pulverization and increase the adhesion of PPy,and then electrochemical co-deposition of PPy-CNT nanostructures on rGO@Au current collectors is performed.The resulting fine patterned MSC conveyed a high areal capacitance of 65.9 mF cm^(−2)(at a current density of 0.1 mA cm^(−2)),an exceptional cycling performance of retaining 79%capacitance after 10,000 charge/discharge cycles at 5 mA cm^(−2).Benefiting from the intermediate graphene,current collector free PPy-CNT@rGO flexible MSC is produced by a facile transfer method on a flexible substrate,which delivered an areal capacitance of 70.25 mF cm^(−2) at 0.1 mA cm^(−2) and retained 46%of the initial capacitance at a current density of 1.0 mA cm^(−2).The flexible MSC is utilized as a skin compatible capacitive micro-strain sensor with excellent electromechanochemical characteristics.

Near-surface structure from ambient-noise tomography and horizontal-to-vertical spectral ratio beneath the Nankou-Sunhe fault

Active faults pose a great threat to urban security.As the largest NW-trend active fault in Beijing area,the Nankou-Sunhe fault plays an important role in earthquake disaster and city construction.In this study,we collect continuous ambient noise data recorded by 43 temporary short-period seismograph between September 21th to October 12th 2019 to investigate the near-surface structure beneath the Nankou-Sunhe fault by using ambient noise tomography(ANT)and horizontal-to-vertical spectral ratio(HVSR)method.From ambient noise processing,fundamental-mode Rayleigh wave signals are clearly observed in the frequency band of 0.4-2.5 Hz.Then direct surface-wave inversion algorithm is applied to calculate the 3D shear-wave velocity model.Our results show that there is a sharp velocity contrast across the Nankou-Sunhe fault,with low velocities down to about 2 km on the hanging wall and high velocity on the footwall of the fault.According to the geological investigation,the low velocities are related to thicker sediments and Jurassic volcanic rock below which are the cap rock of the hydrothermal system.From the HVSR analysis,the HVSR curves of the sites near the fault shows double-peak,one less than 1 Hz and the other centered 7 Hz.After converting frequency to depth by the empirical equation,the results show that the thickness of sediments is thinned from southwest to northeast,which generally agrees well to field survey.Our results provide high-resolution near-surface structure for future study on disaster risk reduction and urban planning.

Tribological performance and scuffing behaviors of several automobile piston rings mating with chrome-plated cylinder liner

The friction and wear properties,as well as the scuffing resistance,of different piston-ring coatings mating with a chrome-plated cylinder liner were investigated.Interrupted wear tests under the lubricant starvation condition were conducted to examine the wear behavior of Cr-diamond coating(GDC)and diamond-like coating(DLC).The results indicated that the DLC coating had outstanding tribological properties(small coefficient of friction and wear loss)at 150°C,while the GDC coating exhibited better performance at an elevated temperature(240°C).The DLC coating had a better scuffing resistance;no material adhesion occurred for 70 min under the unlubricated condition.The interrupted wear behaviors revealed that the scuffing process of the GDC coating involved the consumption of lubricant oil with relatively stable wear,a reduction in the friction force,and the occurrence of scuffing,in sequence.In contrast,although the friction force also increased after a short period of weak friction,no scuffing was observed.This is attributed to the formation of a mixed oxide and graphitic C tribolayer.

Luminescence and recombine centre in ZnO/Si films

The D0h luminescence of ZnO films deposited on p-type Si substrates is produced by metal-organic chemical vapor deposition(MOCVD).After annealing in the air at 700°C for an hour,the photoluminescence(PL)spectra,the I-V characteristics and the deep level transient spectroscopy(DLTS)of the samples are measured.All the samples have a rectification characteristic.DLTS signals show two deep levels of E1 and E2.The Gaussian fit curves of the PL spectra at room temperature show three luminescence lines b,c and d,of which b is attributed to the exciton emission.The donor level E1 measured by DLTS and the location state donor ionization energy Ed of the closely neighboring emission lines c and d are correlated.E1 is judged as neutral donor bound to hole emission(D0h).Moreover,the intensity of the PL spectra decreases while the relative density of E2 increases,showing that E2 has the property of a nonradiative center.