The integrated perovskite/organic solar cell(IPOSC) is widely concerned as an effective approach to broaden the spectrum of perovskite solar cell(PerSC) by utilizing near-infrared light of lower bandgap organic semico...The integrated perovskite/organic solar cell(IPOSC) is widely concerned as an effective approach to broaden the spectrum of perovskite solar cell(PerSC) by utilizing near-infrared light of lower bandgap organic semiconductor. Compared to tandem solar cells, the IPOSCs eliminate the preparation of the intermediate layer and simplify the manufacturing process, but retain the advantages of wide light harvesting. Meanwhile, the IPOSCs can maintain the open-circuit voltage as high as PerSCs. This review summarizes the recent developments of perovskite materials and low-bandgap organic conjugated materials applied in solar cells. Then, the working mechanism of IPOSCs and the recent developments of IPOSCs based on low-bandgap donor and acceptor materials are highlighted. Besides, the study of charge dynamic in IPOSC is summarized. Finally, the potential of IPOSCs and approach to improve device performance are also envisaged.展开更多
基金financially supported by the National Key Research and Development Program of China (No.2016YFA0202401)the National Natural Science Foundation of China (Nos.51873007,51961165102 and 21835006)+2 种基金the Fundamental Research Funds for the Central Universities in China (No.2019MS025)the State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources (No.LAPS20003)the Outstanding Talent Research Fund of Zhengzhou University (No.32340035)。
文摘The integrated perovskite/organic solar cell(IPOSC) is widely concerned as an effective approach to broaden the spectrum of perovskite solar cell(PerSC) by utilizing near-infrared light of lower bandgap organic semiconductor. Compared to tandem solar cells, the IPOSCs eliminate the preparation of the intermediate layer and simplify the manufacturing process, but retain the advantages of wide light harvesting. Meanwhile, the IPOSCs can maintain the open-circuit voltage as high as PerSCs. This review summarizes the recent developments of perovskite materials and low-bandgap organic conjugated materials applied in solar cells. Then, the working mechanism of IPOSCs and the recent developments of IPOSCs based on low-bandgap donor and acceptor materials are highlighted. Besides, the study of charge dynamic in IPOSC is summarized. Finally, the potential of IPOSCs and approach to improve device performance are also envisaged.
