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含双重动态键的可重加工及室温自修复聚氨酯弹性体 被引量:14
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作者 田丽蓉 杨莉 +1 位作者 王占华 夏和生 《高分子学报》 SCIE CAS CSCD 北大核心 2019年第5期527-534,共8页
通过同时向聚合物的主链和交联点引入2种动态共价键—Diels-Alder (D-A)键和二硫(S―S)键,制备了具有自修复、可重加工性能的聚氨酯(PU-SSDA)弹性体.一方面分布在主链和交联点的动态键使聚合物分子链通过可逆的断裂重组实现自修复,另一... 通过同时向聚合物的主链和交联点引入2种动态共价键—Diels-Alder (D-A)键和二硫(S―S)键,制备了具有自修复、可重加工性能的聚氨酯(PU-SSDA)弹性体.一方面分布在主链和交联点的动态键使聚合物分子链通过可逆的断裂重组实现自修复,另一方面,交联的PU中同时存在线性的分子链,从而提高了断面间分子的运动性能,使被破坏的断面间迅速浸润,提高修复效率. PU-SSDA在室温下修复60 min的修复效率可达93%.此外,这些聚氨酯材料可以利用无溶剂一步法制备,作为环境友好材料具有广泛的应用潜力. 展开更多
关键词 Diels-Alder键 S–S键 室温自修复 重加工 聚氨酯
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Mechanical properties of a microalloyed bainitic steel after hot forging and tempering 被引量:7
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作者 Zhi-bao Xu Wei-jun Hui +3 位作者 zhan-hua wang Yong-jian Zhang Xiao-li Zhao Xiu-ming Zhao 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2017年第11期1085-1094,共10页
Mechanical properties of a newly developed microalloyed bainitic steel were investigated after the hot forging, air cooling and tempering process. The microstructure of the as forged bainitic steel mainly consists of ... Mechanical properties of a newly developed microalloyed bainitic steel were investigated after the hot forging, air cooling and tempering process. The microstructure of the as forged bainitic steel mainly consists of granular bainite and -20 vol. % martensite. The fraction of retained austenite remains unchanged until tempering at 200 ℃, above which it decreases significantly. The increase of tempering temperature leads to decreases of both ultimate tensile strength and total elongation but decreases of both yield strength and reduction of area. The maximum and mini- mum values of impact toughness were observed after tempering at around 200 and 400 ℃, respectively. These effects are mainly attributed to the decomposition of martensite/austenite con stituents and the tempering effects in martensite. The tempering of the forged bainitic steel at around 200 ℃ results in an excellent combination of strength and toughness, which is comparable to that of the conventional quenched and-tempered 40Cr steel. Therefore, low-tempering treatment coupled with post-forging residual stress relieving is a feasible method to further improve the mechanical prooerties of the bainitic foging steel. 展开更多
关键词 Bainitic forging steel Mechanical property Tempering Microstructure Granular bainite
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Hydrogen embrittlement of a microalloyed bainitic forging steel 被引量:1
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作者 Wei-jun Hui zhan-hua wang +2 位作者 Zhi-bao Xu Yong-jian Zhang Xiao-li Zhao 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2019年第9期1011-1021,共11页
The hydrogen embrittlement (HE) of a novel microalloyed bainitic forging steel with a strength level of 1100 MPa was evaluated using electrochemical charging and slow strain rate tensile test method with notched round... The hydrogen embrittlement (HE) of a novel microalloyed bainitic forging steel with a strength level of 1100 MPa was evaluated using electrochemical charging and slow strain rate tensile test method with notched round bar specimens. The results show that the susceptibility to HE of the as-forged bainitic forging steel is notably higher than that of the quenched and tempered (Q&T) steel at same strength level, which is ascribed primarily to the presence of a relatively high amount of large blocky martensite/austenite (M/A) constituents of the former. It was found that low-temperature tempering treatment at 200 C could significantly alleviate the susceptibility to HE by a relative decrease of * 35% of the as-forged bainitic forging steel at no expense of strength and ductility, though its resistance to HE is still a little lower than that of the Q&T steel. Thus, it is suggested that efforts concerning refining of the large blocky M/A through optimizing chemical composition and processing route could help to further alleviate the susceptibility to HE of the tested bainitic forging steel. 展开更多
关键词 HYDROGEN EMBRITTLEMENT Bainitic FORGING steel Microstructure GRANULAR BAINITE M/A CONSTITUENT
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Anisotropy in tensile properties and fracture behaviour of 316L stainless steel parts manufactured by fused deposition modelling and sintering
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作者 Lin-Ju Wen Xiao-Gang Hu +3 位作者 Zhong Li zhan-hua wang Ji-Kai Wu Qiang Zhu 《Advances in Manufacturing》 SCIE EI CAS CSCD 2022年第3期345-355,共11页
Fused deposition modelling and sintering(FDMS)is a potential metal additive manufacturing technology due to its low cost and high efficiency.The mixture of metal powder and binder goes through heating,extrusion,debind... Fused deposition modelling and sintering(FDMS)is a potential metal additive manufacturing technology due to its low cost and high efficiency.The mixture of metal powder and binder goes through heating,extrusion,debinding and sintering processes to produce the compact finished part.However,it is generally believed that parts produced by FDMS possess poor and anisotropic tensile properties,which always attributes to the weak interlayer combination.The current work aimed to enhance tensile properties and better understand the anisotropic fracture behavior of the 316L stainless steel prepared by FDMS.By process optimization,the yield strength and ultimate tensile strength obtained in this work are increased by 26.1%and 15.2%,based on the highest performance reported in previous studies.According to the ultimate tensile strength,the performance difference between the horizontal and vertical directions has been reduced to 27%.Furthermore,the experimental results indicated that the clustered irregular shape holes evolved from primitive voids prefer to distribute in the build direction,resulting in anisotropic tensile performance.It is suggested that the mechanical properties could be improved by applying a smaller extrusion diameter and rolling-assisted printing.In addition,the current FDMS parts show qualified performance for producing the customized and small batch components. 展开更多
关键词 Fused deposition modelling 316L stainless steel ANISOTROPY Mechanical properties Fracture behaviour
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