A pilot-scale study of selective desulfurization via urea addition in iron ore sintering

The iron ore sintering process is the main source of SO_2 emissions in the iron and steel industry. In our previous research, we proposed a novel technology for reducing SO_2 emissions in the flue gas in the iron ore sintering process by adding urea at a given distance from the sintering grate bar. In this paper, a pilot-scale experiment was carried out in a commercial sintering plant. The results showed that, compared to the SO_2 concentration in flue gas without urea addition, the SO_2 concentration decreased substantially from 694.2 to 108.0 mg/m^3 when 0.10wt% urea was added. NH_3 decomposed by urea reacted with SO_2 to produce（NH_4）_2SO_4, decreasing the SO_2 concentration in the flue gas.

Effects of gangue compositions on reduction process of carbonbearing iron ore pellets

The influence of gangue compositions (mainly composed of SiO2,CaO,MgO and Al2O3)on the reduction kinetics of carbon-bearing iron ore pellets was estimated at 1373-1473 K in N2 atmosphere.The results showed that gangue content and each component distribution affected the pellets reduction process.The reduction rate was found to follow a linear correlation with quaternary basicity R4 [mass ratio of (CaO +MgO)to (SIO2 +Al2O3)]of the carbon-beating iron ore pellets;also,the content of SiO2 solid solution in iron oxide had a significant impact on the reduction rate.At the same reduction temperature,a higher R4 resulted in a lower SiO2 free content,weakening its inhibitory effect on the Boudouard reaction.The reduction temperature of Fe2SiO4 could be reduced by increasing the contents of CaO and MgO,improving the iron oxide reduction as well as the precipitation and growth of the iron grains.The g'angue content and .component distribution showed no effect on the rate-controlling step of the reduction;however,the apparent activation energy of reaction decreased with increasing quaternary basicity.When R4 increased from 0.15 to 0.67,the apparent activation energy decreased from 228.51 to 193.66 kJ/mol.

Definition of Raceway Boundary Using Fractal Theory

The particle velocity contours were obtained by tracking the tracer particles in the raceway region of the COREX melter gasifier model and the contours were irregular. According to the fractal theory, the fractal dimen sions of different particle velocity contours were determined. Through the analysis of the fractal dimensions, a new method for precise determination of the raceway boundary was proposed. The results show that, when the velocity is less than 0.18 m/s, the particles are located in the stagnant zone and the fractal dimensions of particle velocity con- tours are almost constant as 1.41; when the velocity increases from 0.18 to 0.83 m/s, the particles are located in the rapid movement zone and the fractal dimensions decrease gradually from 1.41 to 1.05 ＇when the velocity is grea- ter than 0.83 m/s, the particles are located in the cavity zone and the fractal dimensions are again almost constant as approaching to 1.00. Therefore, the velocity contour of 0.18 m/s, which is critical to distinguish the rapid move- ment zone and stagnant zone, can be used to define the raceway boundary. Based on this method, the effect of blo wing rate on raceway size was calculated and the results show that the penetration depth and height of the raceway increase with the increase of blowing rate.