Ternary complexes of terbium with ortho (and pam) aminobenzoic acid and 1,10-phenanthroline were introduced into silica gel by the sol-gel method. The luminescence behavior of the solid-state samples was studied durin...Ternary complexes of terbium with ortho (and pam) aminobenzoic acid and 1,10-phenanthroline were introduced into silica gel by the sol-gel method. The luminescence behavior of the solid-state samples was studied during the sol-gel aging process by means of emission. excitation spectra, lifetimes and quantum efficiencies.展开更多
Five new monoterpenoid glycosides named ligurobustosides E (1), F (2), I (3), J (4) and K (5) were isolated from the leaves of Ligustrum robustum. Their structures were established by spectroscopic and chemical methods.
From the aerial parts of Clerodendrum indicum, bye new compounds, cleroindicins B-F (1-5) were isolated and their structures identified by spectral method.
Abstract: From the herbs of Coleus sculellarioides, a new diterpenoid was isolated and identified as 2-(2'ξ-methoxypropy)-3-hydroxy-5,7,8-trimethylphenanthrene-1,4--dione,named as scutequinone(1).
Thirteen kinds of binary and ternary complexes of rare earth (Gd, Eu,Tb) with ortho (para) aminobenzoic acid and 1.10--phenanthroline were synthesized and characterized. The phosphorescence spectra and lifetimes of ga...Thirteen kinds of binary and ternary complexes of rare earth (Gd, Eu,Tb) with ortho (para) aminobenzoic acid and 1.10--phenanthroline were synthesized and characterized. The phosphorescence spectra and lifetimes of gadolinium complexes were measured and the lowest triplet state energies of ligands and the energy transfer efficiencies between ligands were determined. The luminescence properties and intramolecular energy transfer of these complexes were studied in details.展开更多
Two new taxane diterpenoids from Taxus yunnanensis were elucidated by spectroscopic techniques, one of which was identified as a unique taxane with 2,20-oxo group.
The luminescence properties of silica gels and silica gels doped with two rare earth complexes, Eu(TTA)(3) and Tb(o-CBA)(3) (TTA=thenoyltriffuocetate, o-CBA=o-chlorobenzoic acid) are reported and discussed. Pure silic...The luminescence properties of silica gels and silica gels doped with two rare earth complexes, Eu(TTA)(3) and Tb(o-CBA)(3) (TTA=thenoyltriffuocetate, o-CBA=o-chlorobenzoic acid) are reported and discussed. Pure silica gels show a blue luminescence, and the maximum excitation and emission wavelengths depend strongly on the solvents used. Both of the studied rare earth complexes exhibit the characteristic emissions of the rare earth ions in silica gels, i.e., Eu3+5D0-->F-7(J)(J=0,1,2,3,4), Tb3+5D4-->F-7(J)(J=3,4,5,6) transitions. Compared with the pure RE-complexes powder, the silica gels doped with RE-complexes show fewer emission lines of the rare earth ions. Furthermore the rare earth ion (Tb3+) presents a longer lifetime (1346 mu s) in silica gel doped with Tb(o-CBA)3 than in pure Tb((o-CBA)(3) powder (744 mu s). The reasons responsible for these results are discussed in the context.展开更多
THE Langmuir-Blodgett film has a good prospect of application in molecular electronics,inte-grated options,information storage,chemistry and biosensor since it is ultrathin,homoge-neous and can be arbitrarily assemble...THE Langmuir-Blodgett film has a good prospect of application in molecular electronics,inte-grated options,information storage,chemistry and biosensor since it is ultrathin,homoge-neous and can be arbitrarily assembled on molecular level.People are becoming interested ininducting functional rare earth complexes to LB films.As a kind of polymer having indef-inite chain structure,rare earth carboxylate complexes have both good luminescence展开更多
A series of binary and ternary rare earth (Gd, Eu, Tb) complexes with ortho hydroxyl benzoic acid, pam aminobenzoic acid, nicotinic acid and 1,10-phenanthroline were synthesized. Phosphorescence spectra and lifetimes ...A series of binary and ternary rare earth (Gd, Eu, Tb) complexes with ortho hydroxyl benzoic acid, pam aminobenzoic acid, nicotinic acid and 1,10-phenanthroline were synthesized. Phosphorescence spectra and lifetimes of Gd complexes were measured and the lowest triplet state energies of gadolinium binary complexes end the intramolecular energy transfer efficiencies were determined. The luminescence properties and energy transfer process of Eu3+ and Tb3+ complexes were discussed.展开更多
文摘Ternary complexes of terbium with ortho (and pam) aminobenzoic acid and 1,10-phenanthroline were introduced into silica gel by the sol-gel method. The luminescence behavior of the solid-state samples was studied during the sol-gel aging process by means of emission. excitation spectra, lifetimes and quantum efficiencies.
文摘Five new monoterpenoid glycosides named ligurobustosides E (1), F (2), I (3), J (4) and K (5) were isolated from the leaves of Ligustrum robustum. Their structures were established by spectroscopic and chemical methods.
文摘From the aerial parts of Clerodendrum indicum, bye new compounds, cleroindicins B-F (1-5) were isolated and their structures identified by spectral method.
文摘Abstract: From the herbs of Coleus sculellarioides, a new diterpenoid was isolated and identified as 2-(2'ξ-methoxypropy)-3-hydroxy-5,7,8-trimethylphenanthrene-1,4--dione,named as scutequinone(1).
文摘Thirteen kinds of binary and ternary complexes of rare earth (Gd, Eu,Tb) with ortho (para) aminobenzoic acid and 1.10--phenanthroline were synthesized and characterized. The phosphorescence spectra and lifetimes of gadolinium complexes were measured and the lowest triplet state energies of ligands and the energy transfer efficiencies between ligands were determined. The luminescence properties and intramolecular energy transfer of these complexes were studied in details.
文摘Two new taxane diterpenoids from Taxus yunnanensis were elucidated by spectroscopic techniques, one of which was identified as a unique taxane with 2,20-oxo group.
基金Project supported by the National Natural Science Foundation of China and Foundation of the National Personnel Ministry of China.
文摘The luminescence properties of silica gels and silica gels doped with two rare earth complexes, Eu(TTA)(3) and Tb(o-CBA)(3) (TTA=thenoyltriffuocetate, o-CBA=o-chlorobenzoic acid) are reported and discussed. Pure silica gels show a blue luminescence, and the maximum excitation and emission wavelengths depend strongly on the solvents used. Both of the studied rare earth complexes exhibit the characteristic emissions of the rare earth ions in silica gels, i.e., Eu3+5D0-->F-7(J)(J=0,1,2,3,4), Tb3+5D4-->F-7(J)(J=3,4,5,6) transitions. Compared with the pure RE-complexes powder, the silica gels doped with RE-complexes show fewer emission lines of the rare earth ions. Furthermore the rare earth ion (Tb3+) presents a longer lifetime (1346 mu s) in silica gel doped with Tb(o-CBA)3 than in pure Tb((o-CBA)(3) powder (744 mu s). The reasons responsible for these results are discussed in the context.
文摘THE Langmuir-Blodgett film has a good prospect of application in molecular electronics,inte-grated options,information storage,chemistry and biosensor since it is ultrathin,homoge-neous and can be arbitrarily assembled on molecular level.People are becoming interested ininducting functional rare earth complexes to LB films.As a kind of polymer having indef-inite chain structure,rare earth carboxylate complexes have both good luminescence
基金Project supported by the National Natural Science Foundation of China and the President Foundation of Chinese Academy of Sciences.
文摘A series of binary and ternary rare earth (Gd, Eu, Tb) complexes with ortho hydroxyl benzoic acid, pam aminobenzoic acid, nicotinic acid and 1,10-phenanthroline were synthesized. Phosphorescence spectra and lifetimes of Gd complexes were measured and the lowest triplet state energies of gadolinium binary complexes end the intramolecular energy transfer efficiencies were determined. The luminescence properties and energy transfer process of Eu3+ and Tb3+ complexes were discussed.
