There are three formation stages of Silurian hydrocarbon pools in the Tarim Basin. The widely distributed asphaltic sandstones in the Tazhong （central Tarim） and Tabei （northern Tarim） areas are the results of des...There are three formation stages of Silurian hydrocarbon pools in the Tarim Basin. The widely distributed asphaltic sandstones in the Tazhong （central Tarim） and Tabei （northern Tarim） areas are the results of destruction of hydrocarbon pools formed in the first-stage, and the asphaltic sandstones around the Awati Sag were formed in the second-stage. The hydrocarbon migration characteristics reflected by the residual dry asphalts could represent the migration characteristics of hydrocarbons in the Silurian paleo-pools, while the present movable oil in the Silurian reservoirs is related to the iater-stage （the third-stage） hydrocarbon accumulation.展开更多
The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal a...The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal area of this Basin, in which the Jurassic and Triassic Chang-3 are the main oil-bearing strata. Currently, no consensus has been reached regarding oil source and oil migration in the area, and an assessment of oil accumulation patterns is thus challenging. In this paper, the oil source, migration direction, charging site and migration pathways are investigated through analysis of pyrrolic nitrogen compounds and hydrocarbon biomarkers. Oil source correlations show that the oils trapped in the Jurassic and Chang-3 reservoirs were derived from the Triassic Chang-7 source rocks. The Jurassic and Chang-3 crude oils both underwent distinct vertical migration from deep to shallow strata, indicating that the oils generated by Chang-7 source rocks may have migrated upward to the shallower Chang-3 and Jurassic strata under abnormally high pressures, to accumulate along the sand bodies of the ancient rivers and the unconformity surface. The charging direction of the Jurassic and Chang-3 crude oils is primarily derived from Mubo, Chenhao, and Shangliyuan, which are located northeast of the southern Tianhuan Depression, with oils moving toward the west, southwest, and south. The results show that an integration of biomarker and nitrogen-bearing compound analyses can provide useful information about oil source, migration, and accumulation.展开更多
So far there has been no common opinion on oil source of the Chepaizi swell in the Junggar Basin. Therefore, it is difficult to determine the pathway system and trend of hydrocarbon migration, and this resulted in dif...So far there has been no common opinion on oil source of the Chepaizi swell in the Junggar Basin. Therefore, it is difficult to determine the pathway system and trend of hydrocarbon migration, and this resulted in difficulties in study of oil-gas accumulation patterns. In this paper, study of nitrogen compounds distribution in oils from Chepaizi was carried out in order to classify source rocks of oils stored in different reservoirs in the study area. Then, migration characteristics of oils from the same source were investigated by using nitrogen compounds parameters. The results of nitrogen compounds in a group of oil/oil sand samples from the same source indicate that the oils trapped in the Chepaizi swell experienced an obvious vertical migration. With increasing migration distance, amounts and indices of carbazoles have a regular changing pattern （in a fine linear relationship）. By using nitrogen compounds techniques, the analyzed oil/oil sand samples of Chepaizi can be classified into two groups. One is the samples stored in reservoir beds of the Cretaceous and Tertiary, and these oils came from mainly Jurassic source rock with a small amount of Cretaceous rock; the other is those stored in the Jurassic, Permian and Carboniferous beds, and they originated from the Permian source. In addition, a sample of oil from an upper Jurassic reservoir （Well Ka 6）, which was generated from Jurassic coal source rock, has a totally different nitrogen compound distribution from those of the above-mentioned two groups of samples, which were generated from mudstone sources. Because of influence from fractionation of oil migration, amounts and ratios of nitrogen compounds with different structures and polarities change regularly with increasing migrating distance, and as a result the samples with the same source follow a good linear relationship in content and ratio, while the oil samples of different sources have obviously different nitrogen compound distribution owing to different organic matter types of their source rocks. These conclusions of oil source study are identical with those obtained by other geochemical bio-markers. Therefore, nitrogen compounds are of great significance in oil type classification and oil/source correlation.展开更多
Based on analysis of main controlling factors of Chang 9, the source rock, driving force of migration, migration and accumulation modes, reservoir forming stages and model and enrichment law of Chang 9 reservoir were ...Based on analysis of main controlling factors of Chang 9, the source rock, driving force of migration, migration and accumulation modes, reservoir forming stages and model and enrichment law of Chang 9 reservoir were examined. The study showed that the oil of Chang 9 reservoir in the Jiyuan and Longdong(Eastern Gansu) areas came primarily from the source rock of Chang 7 Member, but the oil of Chang 9 reservoir in the Zhidan area came primarily from the source rock of Chang 9 Member. There developed lithologic-structural oil reservoirs in Gufengzhuang-Mahuangshan area in northwest Jiyuan, structural-lithologic oil reservoirs in east Jiyuan, and lithologic reservoirs in Huachi–Qingcheng area and Zhidan area. The overpressure of Chang 7 Member was the driving force of oil migration. The burial history showed that Chang 9 Member experienced two stages of reservoir forming, the reservoir formed in the Late Jurassic was smaller in charging scope and scale, and the Early Cretaceous was the period when the source rock generated oil and gas massively and the Chang 9 reservoir came into being. Along with the tectonic movements, Chang 7 bottom structure turned from high in the west and lower in the East in the sedimentary stage to high in the east and lower in the west in the hydrocarbon accumulation stage and at last to gentle western-leaning monoclinal structure at present. In Early Cretaceous, the Chang 7 bottom structure was the lowest in the west of Huanxian-Huachi-Wuqi-Dingbian areas, so the oil migrated laterally towards the higher positions around after entering the reservoir. In the main reservoir forming period, Chang 7 bottom had an ancient anticline in Mahuangshan-Hongjingzi area of west Jiyuan, controlling the oil reservoir distribution in west Jiyuan.展开更多
The results presented in this paper indicated that the carbazole-type compounds have high thermal stabil- ity and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrati...The results presented in this paper indicated that the carbazole-type compounds have high thermal stabil- ity and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and (or) bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin (at the end of the Silurian period) and at the second stage in the Awati area (in Permian), the hydrocar- bons experienced a long-distance migration.展开更多
文摘There are three formation stages of Silurian hydrocarbon pools in the Tarim Basin. The widely distributed asphaltic sandstones in the Tazhong （central Tarim） and Tabei （northern Tarim） areas are the results of destruction of hydrocarbon pools formed in the first-stage, and the asphaltic sandstones around the Awati Sag were formed in the second-stage. The hydrocarbon migration characteristics reflected by the residual dry asphalts could represent the migration characteristics of hydrocarbons in the Silurian paleo-pools, while the present movable oil in the Silurian reservoirs is related to the iater-stage （the third-stage） hydrocarbon accumulation.
基金supported by the National Basic Research Program of China (973 Program) (No. 2012CB822003)Specialized Research Fund for the Doctoral Program of Higher Education (No. 20120211110022)the National Science and Technology Major Projects (2011zx05001-004)
文摘The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal area of this Basin, in which the Jurassic and Triassic Chang-3 are the main oil-bearing strata. Currently, no consensus has been reached regarding oil source and oil migration in the area, and an assessment of oil accumulation patterns is thus challenging. In this paper, the oil source, migration direction, charging site and migration pathways are investigated through analysis of pyrrolic nitrogen compounds and hydrocarbon biomarkers. Oil source correlations show that the oils trapped in the Jurassic and Chang-3 reservoirs were derived from the Triassic Chang-7 source rocks. The Jurassic and Chang-3 crude oils both underwent distinct vertical migration from deep to shallow strata, indicating that the oils generated by Chang-7 source rocks may have migrated upward to the shallower Chang-3 and Jurassic strata under abnormally high pressures, to accumulate along the sand bodies of the ancient rivers and the unconformity surface. The charging direction of the Jurassic and Chang-3 crude oils is primarily derived from Mubo, Chenhao, and Shangliyuan, which are located northeast of the southern Tianhuan Depression, with oils moving toward the west, southwest, and south. The results show that an integration of biomarker and nitrogen-bearing compound analyses can provide useful information about oil source, migration, and accumulation.
基金supported by the State 973 Funds(No. 2006CB202308)
文摘So far there has been no common opinion on oil source of the Chepaizi swell in the Junggar Basin. Therefore, it is difficult to determine the pathway system and trend of hydrocarbon migration, and this resulted in difficulties in study of oil-gas accumulation patterns. In this paper, study of nitrogen compounds distribution in oils from Chepaizi was carried out in order to classify source rocks of oils stored in different reservoirs in the study area. Then, migration characteristics of oils from the same source were investigated by using nitrogen compounds parameters. The results of nitrogen compounds in a group of oil/oil sand samples from the same source indicate that the oils trapped in the Chepaizi swell experienced an obvious vertical migration. With increasing migration distance, amounts and indices of carbazoles have a regular changing pattern （in a fine linear relationship）. By using nitrogen compounds techniques, the analyzed oil/oil sand samples of Chepaizi can be classified into two groups. One is the samples stored in reservoir beds of the Cretaceous and Tertiary, and these oils came from mainly Jurassic source rock with a small amount of Cretaceous rock; the other is those stored in the Jurassic, Permian and Carboniferous beds, and they originated from the Permian source. In addition, a sample of oil from an upper Jurassic reservoir （Well Ka 6）, which was generated from Jurassic coal source rock, has a totally different nitrogen compound distribution from those of the above-mentioned two groups of samples, which were generated from mudstone sources. Because of influence from fractionation of oil migration, amounts and ratios of nitrogen compounds with different structures and polarities change regularly with increasing migrating distance, and as a result the samples with the same source follow a good linear relationship in content and ratio, while the oil samples of different sources have obviously different nitrogen compound distribution owing to different organic matter types of their source rocks. These conclusions of oil source study are identical with those obtained by other geochemical bio-markers. Therefore, nitrogen compounds are of great significance in oil type classification and oil/source correlation.
基金Supported by China National Science and Technology Major Project(2016ZX05050,2017ZX05001002-008)the PetroChina Science and Technology Major Project(2016E-0501)
文摘Based on analysis of main controlling factors of Chang 9, the source rock, driving force of migration, migration and accumulation modes, reservoir forming stages and model and enrichment law of Chang 9 reservoir were examined. The study showed that the oil of Chang 9 reservoir in the Jiyuan and Longdong(Eastern Gansu) areas came primarily from the source rock of Chang 7 Member, but the oil of Chang 9 reservoir in the Zhidan area came primarily from the source rock of Chang 9 Member. There developed lithologic-structural oil reservoirs in Gufengzhuang-Mahuangshan area in northwest Jiyuan, structural-lithologic oil reservoirs in east Jiyuan, and lithologic reservoirs in Huachi–Qingcheng area and Zhidan area. The overpressure of Chang 7 Member was the driving force of oil migration. The burial history showed that Chang 9 Member experienced two stages of reservoir forming, the reservoir formed in the Late Jurassic was smaller in charging scope and scale, and the Early Cretaceous was the period when the source rock generated oil and gas massively and the Chang 9 reservoir came into being. Along with the tectonic movements, Chang 7 bottom structure turned from high in the west and lower in the East in the sedimentary stage to high in the east and lower in the west in the hydrocarbon accumulation stage and at last to gentle western-leaning monoclinal structure at present. In Early Cretaceous, the Chang 7 bottom structure was the lowest in the west of Huanxian-Huachi-Wuqi-Dingbian areas, so the oil migrated laterally towards the higher positions around after entering the reservoir. In the main reservoir forming period, Chang 7 bottom had an ancient anticline in Mahuangshan-Hongjingzi area of west Jiyuan, controlling the oil reservoir distribution in west Jiyuan.
文摘The results presented in this paper indicated that the carbazole-type compounds have high thermal stabil- ity and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and (or) bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin (at the end of the Silurian period) and at the second stage in the Awati area (in Permian), the hydrocar- bons experienced a long-distance migration.
