The recovery of compression set (RS) of wood after dry heating or steam treatment mainly depends on the temperature and time of treatment. For quantitative elucidation, a graph of intermediate RS was built with temper...The recovery of compression set (RS) of wood after dry heating or steam treatment mainly depends on the temperature and time of treatment. For quantitative elucidation, a graph of intermediate RS was built with temperature (T) and time (t) as coordinates. In this graph (abbreviated as T-t planum), a series of curves of RS were created. This leads to a conclusion that same RS can be obtained by numerous different pathways. Further research on pathway equivalency based on T-t planum indicates that a low RS of 10% can be achieved definitely by different combinations of time and temperature. However, the fixation mechanism varies at different temperatures. On the equivalent pathways of higher recovery, the influence of temperature must be taken into consideration. The actual routes must be somewhat modified to achieve an expected result. This makes it possible for us to work out a best fixation pathway among all the possibilities, to eliminate the impact of heat on the mechanical properties of wood.展开更多
The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood...The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood powders were fixed either by heating at different temperatures all resulting in a 10% recovery, or by incubating at 180 °C for different periods with subsequent recovery levels. Both X-ray diffraction and infrared absorption of those samples have been measured. Relative crystalline increases at early stage of heating fixation, and then decreased gradually. Hemicellulose and lignin decomposition were induced by the fixation process, especially at 180 °C, and lignin was degraded actively. Furthermore, absorbed water was lost after heating, but cellulose did not change markedly. Although different fixation pathways can result in the same recovery level, the major chemical reactions un- derlying them vary, which is consistent with the difference of fixation mechanisms.展开更多
基金the National Natural Science Foundation of China (Grant No. 30070606) and by Association of International Education of Japan
文摘The recovery of compression set (RS) of wood after dry heating or steam treatment mainly depends on the temperature and time of treatment. For quantitative elucidation, a graph of intermediate RS was built with temperature (T) and time (t) as coordinates. In this graph (abbreviated as T-t planum), a series of curves of RS were created. This leads to a conclusion that same RS can be obtained by numerous different pathways. Further research on pathway equivalency based on T-t planum indicates that a low RS of 10% can be achieved definitely by different combinations of time and temperature. However, the fixation mechanism varies at different temperatures. On the equivalent pathways of higher recovery, the influence of temperature must be taken into consideration. The actual routes must be somewhat modified to achieve an expected result. This makes it possible for us to work out a best fixation pathway among all the possibilities, to eliminate the impact of heat on the mechanical properties of wood.
基金the National Natural Science Foundation of China (Grant No.30070606) and Association of International Education of Japan
文摘The changes in relative crystalline, chemical composition and internal structure of compressed Chinese fir wood after different heating fixations were found strictly related to fixation conditions. The compressed wood powders were fixed either by heating at different temperatures all resulting in a 10% recovery, or by incubating at 180 °C for different periods with subsequent recovery levels. Both X-ray diffraction and infrared absorption of those samples have been measured. Relative crystalline increases at early stage of heating fixation, and then decreased gradually. Hemicellulose and lignin decomposition were induced by the fixation process, especially at 180 °C, and lignin was degraded actively. Furthermore, absorbed water was lost after heating, but cellulose did not change markedly. Although different fixation pathways can result in the same recovery level, the major chemical reactions un- derlying them vary, which is consistent with the difference of fixation mechanisms.
