Manipulating emergent quantum phenomena is a key issue for understanding the underlying physics and contributing to possible applications.Here we study the evolution of insulating ground states of Ta_(2)Pu_(3)Te_(5) a...Manipulating emergent quantum phenomena is a key issue for understanding the underlying physics and contributing to possible applications.Here we study the evolution of insulating ground states of Ta_(2)Pu_(3)Te_(5) and Ta_(2)Ni_(3)Te_(5) under in-situ surface potassium deposition via angle-resolved photoemission spectroscopy.Our results confirm the excitonic insulator character of Ta_(2)d_(3)Te_(5).Upon surface doping,the size of its global gap decreases obviously.After a deposition time of more than 7 min,the potassium atoms induce a metal-insulator phase transition and make the system recover to a normal state.In contrast,our results show that the isostructural compound Ta_(2)Ni_(3)Te_(5) is a conventional insulator.The size of its global gap decreases upon surface doping,but persists positive throughout the doping process.Our results not only confirm the excitonic origin of the band gap in Ta_(2)Pd_(3)Te_(5),but also offer an effective method for designing functional quantum devices in the future.展开更多
Two-dimensional(2D)ferromagnetic materials have been exhibiting promising potential in applications,such as spintronics devices.To grow epitaxial magnetic films on silicon substrate,in the single-layer limit,is practi...Two-dimensional(2D)ferromagnetic materials have been exhibiting promising potential in applications,such as spintronics devices.To grow epitaxial magnetic films on silicon substrate,in the single-layer limit,is practically important but challenging.In this study,we realized the epitaxial growth of Mn Sn monolayer on Si(111)substrate,with an atomically thin Sn/Si(111)-231/2×231/2-buffer layer,and controlled the Mn Sn thickness with atomic-layer precision.We discovered the ferromagnetism in Mn Sn monolayer with the Curie temperature(Tc)of^54 K.As the Mn Sn film is grown to 4 monolayers,Tc increases accordingly to^235 K.The lattice of the epitaxial Mn Sn monolayer as well as the Sn/Si(111)-231/2×231/2 is perfectly compatible with silicon,and thus an sharp interface is formed between Mn Sn,Sn and Si.This system provides a new platform for exploring the 2D ferromagnetism,integrating magnetic monolayers into silicon-based technology,and engineering the spintronics heterostructures.展开更多
Electron-phonon interactions and electron-electron correlations represent two crucial facets of condensed matter physics.For instance,in a half-filled spin-1/2 anti-ferromagnetic chain,the lattice dimerization induced...Electron-phonon interactions and electron-electron correlations represent two crucial facets of condensed matter physics.For instance,in a half-filled spin-1/2 anti-ferromagnetic chain,the lattice dimerization induced by electron-nucleus interaction can be intensified by onsite Coulomb repulsion,resulting in a spin-Peierls state.Through first-principles calculations and crystal structure prediction methods,we have identified that under mild pressures,potassium and ammonia can form stable compounds:R3m K(NH_(3))_(2),Pm3 m K(NH_(3))_(2),and Cm K_(2)(NH_(3))_(3).Our predictions suggest that the R3 m K(NH_(3))_(2)exhibits electride characteristics,marked by the formation of interstitial anionic electrons(IAEs)in the interlayer space.These IAEs are arranged in quasi-two-dimensional triangular arrays.With increasing pressure,the electronic van-Hove singularity shifts toward the Fermi level,resulting in an augmented density of states and the onset of both Peierls and magnetic instabilities.Analyzing these instabilities,we determine that the ground state of the R3 m K(NH_(3))_(2)is the dimerized P2_(1)/m phase with zigzag-type anti-ferromagnetic IAEs.This state can be described by the triangular-lattice antiferromagnetic Heisenberg model with modulated magnetic interactions.Furthermore,we unveil the coexistence and positive interplay between magnetic and Peierls instability,constituting a scenario of spin-Peierls instability unprecedented in realistic 2D materials,particularly involving IAEs.This work provides valuable insights into the coupling of IAEs with the adjacent lattice and their spin correlations in quantum materials.展开更多
In this study, we used the crystal structure search method and first-principles calculations to systematically explore the highpressure phase diagrams of the TaAs family(NbP, NbAs, TaP, and TaAs). Our calculation resu...In this study, we used the crystal structure search method and first-principles calculations to systematically explore the highpressure phase diagrams of the TaAs family(NbP, NbAs, TaP, and TaAs). Our calculation results show that NbAs and TaAs have similar phase diagrams, the same structural phase transition sequence I4_1 md→P6 m2→P2_1/c→Pm3 m, and slightly different transition pressures. The phase transition sequence of NbP and TaP differs somewhat from that of NbAs and TaAs, in which new structures emerge, such as the Cmcm structure in NbP and the Pmmn structure in TaP. Interestingly, we found that in the electronic structure of the high-pressure phase P6 m2-NbAs, there are coexistingWeyl points and triple degenerate points, similar to those found in high-pressure P6 m2-TaAs.展开更多
Dirac nodal-line semimetals with the linear bands crossing along a line or loop, represent a new topological state of matter. Here, by carrying out magnetotransport measurements and performing first-principle calculat...Dirac nodal-line semimetals with the linear bands crossing along a line or loop, represent a new topological state of matter. Here, by carrying out magnetotransport measurements and performing first-principle calculations, we demonstrate that such a state has been realized in high-quality single crystals of SrAs_3.We obtain the nontrivial ∏ Berry phase by analysing the Shubnikov-de Haas quantum oscillations. We also observe a robust negative longitudinal magnetoresistance induced by the chiral anomaly.Accompanying first-principles calculations identifies that a single hole pocket enclosing the loop nodes is responsible for these observations.展开更多
Low-dimensional materials have attracted significant attention over the past decade.To discover new low-dimensional materials,high-throughput screening methods for structures with target dimensionality have been appli...Low-dimensional materials have attracted significant attention over the past decade.To discover new low-dimensional materials,high-throughput screening methods for structures with target dimensionality have been applied in different materials databases.For this purpose,the reliability of dimensionality identification is therefore highly important.In this work,we find that the existence of self-penetrating nets may lead to incorrect results by previous methods.Instead of this,we use the quotient graph to analyse the topologies of structures and compute their dimensionalities.展开更多
Quadratic band crossing points(QBCPs)and quantum anomalous Hall effect(QAHE)have attracted the attention of both theoretical and experimental researchers in recent years.Based on first-principle calculations,we find t...Quadratic band crossing points(QBCPs)and quantum anomalous Hall effect(QAHE)have attracted the attention of both theoretical and experimental researchers in recent years.Based on first-principle calculations,we find that the FeB_(2) monolayer is a nonmagnetic semimetal with QBCPs at K.Through symmetry analysis and k·p invariant theory,we find that the QBCP is not protected by rotation symmetry and consists of two Dirac points with the same chirality(Berry phase of 2π).Once introducing Coulomb interactions,we find that there is a spontaneous-time-reversal-breaking instability of the spinful QBCPs,which gives rise to a C=2 QAH insulator with orbital moment ordering.展开更多
基金Project supported by the Ministry of Science and Technology of China (Grant No. 2022YFA1403800)the National Natural Science Foundation of China (Grant Nos. U2032204,12188101, and U22A6005)+2 种基金the Chinese Academy of Sciences (Grant No. XDB33000000)the Synergetic Extreme Condition User Facility (SECUF)the Center for Materials Genome。
文摘Manipulating emergent quantum phenomena is a key issue for understanding the underlying physics and contributing to possible applications.Here we study the evolution of insulating ground states of Ta_(2)Pu_(3)Te_(5) and Ta_(2)Ni_(3)Te_(5) under in-situ surface potassium deposition via angle-resolved photoemission spectroscopy.Our results confirm the excitonic insulator character of Ta_(2)d_(3)Te_(5).Upon surface doping,the size of its global gap decreases obviously.After a deposition time of more than 7 min,the potassium atoms induce a metal-insulator phase transition and make the system recover to a normal state.In contrast,our results show that the isostructural compound Ta_(2)Ni_(3)Te_(5) is a conventional insulator.The size of its global gap decreases upon surface doping,but persists positive throughout the doping process.Our results not only confirm the excitonic origin of the band gap in Ta_(2)Pd_(3)Te_(5),but also offer an effective method for designing functional quantum devices in the future.
基金supported by the National Natural Science Foundation of China(Grant Nos.11774149,11790311,11574133,and 11834006)the National Key R&D Program of China(Grant Nos.2016YFA0300404,2015CB921202,and 2014CB921103)。
文摘Two-dimensional(2D)ferromagnetic materials have been exhibiting promising potential in applications,such as spintronics devices.To grow epitaxial magnetic films on silicon substrate,in the single-layer limit,is practically important but challenging.In this study,we realized the epitaxial growth of Mn Sn monolayer on Si(111)substrate,with an atomically thin Sn/Si(111)-231/2×231/2-buffer layer,and controlled the Mn Sn thickness with atomic-layer precision.We discovered the ferromagnetism in Mn Sn monolayer with the Curie temperature(Tc)of^54 K.As the Mn Sn film is grown to 4 monolayers,Tc increases accordingly to^235 K.The lattice of the epitaxial Mn Sn monolayer as well as the Sn/Si(111)-231/2×231/2 is perfectly compatible with silicon,and thus an sharp interface is formed between Mn Sn,Sn and Si.This system provides a new platform for exploring the 2D ferromagnetism,integrating magnetic monolayers into silicon-based technology,and engineering the spintronics heterostructures.
基金financial support from the National Key R&D Program of China(2022YFA1403201)the National Natural Science Foundation of China(12125404,11974162,and 11834006)the Fundamental Research Funds for the Central Universities。
文摘Electron-phonon interactions and electron-electron correlations represent two crucial facets of condensed matter physics.For instance,in a half-filled spin-1/2 anti-ferromagnetic chain,the lattice dimerization induced by electron-nucleus interaction can be intensified by onsite Coulomb repulsion,resulting in a spin-Peierls state.Through first-principles calculations and crystal structure prediction methods,we have identified that under mild pressures,potassium and ammonia can form stable compounds:R3m K(NH_(3))_(2),Pm3 m K(NH_(3))_(2),and Cm K_(2)(NH_(3))_(3).Our predictions suggest that the R3 m K(NH_(3))_(2)exhibits electride characteristics,marked by the formation of interstitial anionic electrons(IAEs)in the interlayer space.These IAEs are arranged in quasi-two-dimensional triangular arrays.With increasing pressure,the electronic van-Hove singularity shifts toward the Fermi level,resulting in an augmented density of states and the onset of both Peierls and magnetic instabilities.Analyzing these instabilities,we determine that the ground state of the R3 m K(NH_(3))_(2)is the dimerized P2_(1)/m phase with zigzag-type anti-ferromagnetic IAEs.This state can be described by the triangular-lattice antiferromagnetic Heisenberg model with modulated magnetic interactions.Furthermore,we unveil the coexistence and positive interplay between magnetic and Peierls instability,constituting a scenario of spin-Peierls instability unprecedented in realistic 2D materials,particularly involving IAEs.This work provides valuable insights into the coupling of IAEs with the adjacent lattice and their spin correlations in quantum materials.
基金supported by the National Key R&D Program of China(Grant No.2016YFA0300404)the National Key Projects for Basic Research in China(Grant No.2015CB921202)+4 种基金the National Natural Science Foundation of China(Grant Nos.11574133,and 51372112)the Natural Science Foundation Jiangsu Province(Grant No.BK20150012)the Science Challenge Project(Grant No.TZ2016001)the Fundamental Research Funds for the Central UniversitiesSpecial Program for Applied Research on Super Computation of the National Natural Science FoundationGuangdong Joint Fund
文摘In this study, we used the crystal structure search method and first-principles calculations to systematically explore the highpressure phase diagrams of the TaAs family(NbP, NbAs, TaP, and TaAs). Our calculation results show that NbAs and TaAs have similar phase diagrams, the same structural phase transition sequence I4_1 md→P6 m2→P2_1/c→Pm3 m, and slightly different transition pressures. The phase transition sequence of NbP and TaP differs somewhat from that of NbAs and TaAs, in which new structures emerge, such as the Cmcm structure in NbP and the Pmmn structure in TaP. Interestingly, we found that in the electronic structure of the high-pressure phase P6 m2-NbAs, there are coexistingWeyl points and triple degenerate points, similar to those found in high-pressure P6 m2-TaAs.
基金supported by the National Natural Science Foundation of China(11674157,51372112 and 11574133)the National Key Research and Development Plan(2016YFA0300404)the National Basic Research Program of China(2015CB921202)
文摘Dirac nodal-line semimetals with the linear bands crossing along a line or loop, represent a new topological state of matter. Here, by carrying out magnetotransport measurements and performing first-principle calculations, we demonstrate that such a state has been realized in high-quality single crystals of SrAs_3.We obtain the nontrivial ∏ Berry phase by analysing the Shubnikov-de Haas quantum oscillations. We also observe a robust negative longitudinal magnetoresistance induced by the chiral anomaly.Accompanying first-principles calculations identifies that a single hole pocket enclosing the loop nodes is responsible for these observations.
基金J.S.gratefully acknowledges financial support from the National Key R&D Program of China(Grant No.2016YFA0300404)the National Natural Science Foundation of China(Grant Nos.11974162 and 11834006)the Fundamental Research Funds for the Central Universities.
文摘Low-dimensional materials have attracted significant attention over the past decade.To discover new low-dimensional materials,high-throughput screening methods for structures with target dimensionality have been applied in different materials databases.For this purpose,the reliability of dimensionality identification is therefore highly important.In this work,we find that the existence of self-penetrating nets may lead to incorrect results by previous methods.Instead of this,we use the quotient graph to analyse the topologies of structures and compute their dimensionalities.
基金supported by the National Natural Science Foundation of China(11974395 and 12188101)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB33000000)+6 种基金the Center for Materials Genomesupport from the Ministry of Science and Technology of China under Grant Nos.2016YFA0300600 and 2018YFA0305700the Chinese Academy of Sciences under Grant No.XDB28000000the Science Challenge Project(TZ2016004)the K.C.Wong Education Foundation(GJTD-2018-01)Beijing Municipal Science&Technology Commission(Z181100004218001)Beijing Natural Science Foundation(Z180008)。
基金supported by the National Natural Science Foundation of China(Grant Nos.11974395,12188101,and U2032204)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB33000000)+1 种基金the China Postdoctoral Science Foundation funded project(Grant No.2021M703461)the Center for Materials Genome。
文摘Quadratic band crossing points(QBCPs)and quantum anomalous Hall effect(QAHE)have attracted the attention of both theoretical and experimental researchers in recent years.Based on first-principle calculations,we find that the FeB_(2) monolayer is a nonmagnetic semimetal with QBCPs at K.Through symmetry analysis and k·p invariant theory,we find that the QBCP is not protected by rotation symmetry and consists of two Dirac points with the same chirality(Berry phase of 2π).Once introducing Coulomb interactions,we find that there is a spontaneous-time-reversal-breaking instability of the spinful QBCPs,which gives rise to a C=2 QAH insulator with orbital moment ordering.