Optimization of Photo-Fenton Catalyst Preparation Based Bamboo Carbon Fiber by Response Surface Methodology

In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based catalyst was excellent and its optimal preparation process was also explored by response surface methodology.First,bamboo-carbon fiber was selected as the photo-Fenton catalyst carrier.Subsequently,the surface of the car-bon fiber was modified,with which dopamine,nano-Fe_(3)O_(4) and nano-TiO_(2) were successively loaded by hydro-thermal method.After the single factor tests,four factors including dopamine concentration,ferric chloride mass,P25 titanium dioxide mass and liquid-solid ratio were selected as the characteristic values.The degradation efficiency of photo-Fenton catalyst to methylene blue(MB)solution was treated as the response value.After the analysis of the response surface optimization,it was shown that the significance sequence of the selected 4 factors in terms of the MB degradation efficiency was arranged as follows:dopamine concentration>liquid-solid ratio>P25 titanium dioxide quality>ferric chloride quality.The optimal process parameters of fiber-carbon catalyst were affirmed as follows:the 1.7 mg/mL concentration of dopamine,the 1.2 g mass of ferric chloride,the 0.2 g mass of P25 titanium dioxide and the liquid-solid ratio of 170 mL/g.The experiment-measured average MB degra-dation efficiency performed by the optimized catalyst was 99.3%,which was nearly similar to the model-predicted value of 98.9%.It showed that the prediction model and response surface model were accurate and reliable.The results from response surface optimization could provide a good reference to design bamboo-based Fenton-like catalyst with excellent catalytic performance.

A new hypothesis for cavitation nucleation in gas saturated solutions:Clustering of gas molecules lowers significantly the surface tension

Cavitation in water generally takes place at much lower negative pressure than predicted from theories.In this work,we try to stress the discrepancy from the influence of the dissolved gas on cavitation nucleation.By combining molecular dynamics simulation and thermodynamic analysis,we evaluated the lowering of surface tension as a function of density of gas molecules in gas clusters formed in aqueous solution.We found that the obtained surface tension of small gas clusters is much more substantially reduced than expected.The surface tension lowering and the non-ideality of gas molecules in the clusters are then taken into account in determining the nucleation of cavitation,and as a consequence,the required negative pressure for cavitation becomes comparable to experimental values.Thus,we give an alternative explanation for the discrepancy of cavitation pressure between experiment and theory,i.e.,it is the substantially reduced surface tension for small gas nuclei,which have not been taken into account in theory,along with the ideal gas approxiamtion that induce its deviation from the experimental values.

An Investigation on the Visible Characteristics of Four Caesalpiniaceae Wood Species in Gabon

Color,whiteness and glossiness of four caesalpiniaceae wood species were characterized by quantitative measurements and image analysis,i.e.,which were respectively Berlinia bracteosa Benth.,Monopetalanthus heitzii Pellegr.,Distemonanthus benthamianus and Erythrophleum ivorense A.Chev.The color of four wood species was evaluated to be consistent by the CIELab and CIE1931 color system.The boards of B.bracteosa,M.heitzii and E.ivorense was divided into dark color.The wood color of B.bracteosa had the highest red to green hue,while the wood appearance of D.benthamianus had the brightest and yellowest color within the four wood species.The whiteness of D.benthamianus was significantly higher than the other three wood species,namely tangential section 21.9%and radial section 22.2%.Hence,the color of the four species varied significantly,which was closely related to internal constituents of wood materials.M.heitzii wood had the highest surface glossiness on both tangential and radial section surfaces.The surface glossiness was highly related to the wood microstructure,especially with the pore and groove structure.This study of the visible characteristics provided the indicated knowledge for the application of the four wood species in wood industry.

Experimental determination of restitution coefficient of garlic bulb based on high-speed photography

Restitution coefficient(RC)of garlic bulb is an important mechanical property that is required to establish the kinematics model of bulb collision and research the damage mechanism of bulb collision.In this study,kinetic equations of bulb collision were established based on Hertz's contact theory.The kinematics characteristics,elastoplastic deformation and contact damage during bulb collision were analyzed by using high-speed photography.The effects of bulb mass,moisture content,collision material,material thickness and release height on the RC were investigated by mixed orthogonal experiments and single-factor experiments.The results showed that the movement of bulb in the compression stage was translation,and the movement in the rebound stage was translation and rotation.During collision,the larger the rotational angular velocity of the bulb was,the smaller the measured RC would be.The contact damage of bulb included internal damage of the tissue,epidermis stretch and tear.The significance of effects of factors on RC decreased with the following sequence:collision material,release height,material thickness,bulb mass,and moisture content.Collision material,release height,material thickness,and bulb mass were significant factors.The RC between the bulb and Q235,nylon,and rubber decreased sequentially.The RC decreased with the increase of release height and bulb mass.The RC increased with the increase of material thickness of Q235,while it decreased with the increase of material thickness of rubber or Nylon.The determination coefficients of the regression equations between the significant factors and the RC were all greater than 0.96.The results will be helpful for damage mechanism analysis and design of garlic production equipment.