Substrate temperature dependence of chemical state and magnetoresistance characteristics of Co–TiO2 nanocomposite films

Co−TiO2 nanocomposite films were prepared via magnetron sputtering at various substrate temperatures.The films comprise Co particles dispersed in an amorphous TiO2 matrix and exhibit coexisting ferromagnetic and superparamagnetic properties.When the substrate temperature increases from room temperature to 400℃,Co particles gradually grow,and the degree of Co oxidation significantly decreases.Consequently,the saturation magnetization increases from 0.13 to 0.43 T at the same Co content by increasing the substrate temperature from room temperature to 400℃.At a high substrate temperature,conductive pathways form among some of the clustered Co particles.Thus,resistivity rapidly declines from 1600 to 76μΩ·m.The magnetoresistive characteristic of Co−TiO2 films is achieved even at resistivity of as low as 76μΩ·m.These results reveal that the obtained nanocomposite films have low Co oxidation,high magnetization and magnetoresistance at room temperature.

Synthetic Effects of Frequency and Duty Ratio on Growth Characteristics, Energy Consumption and Corrosion Properties of Microarc Oxidized Coating Formed on Ti6Al4V

The synthetic effects of frequency and duty ratio on growth characteristics and corrosion properties of coating on Ti6Al4V fabricated by microarc oxidation are investigated comprehensively. Under the condition of uniform cumulating time of positive impulse width, the essence of altering frequency and duty ratio to determine the formation of coating is to vary the duration and interval time of positive pulse. The growth of coating is mainly controlled by duration time of positive pulse and hardly correlated to the interval time of positive pulse, while both duration and interval time of positive pulse have few influences on the morphology and phase structures of coating. The dynamic current is related to positive impulse width and the ratio of positive pulse on-time to pulse off-time. Regardless of uniform duration or interval time of positive pulse, the energy dissipation presents a descending tendency. The relationship between energy consumption and anticorrosion performance is contradictory, and obtaining excellent corrosion ratio and frequency can be designed purposefully to realize the resistance is bound to sacrifice lots of energy. The duty optimal process.