Optimized CeO_(2) Nanowires with Rich Surface Oxygen Vacancies Enable Fast Li-Ion Conduction in Composite Polymer Electrolytes

Low-cost and flexible solid polymer electrolytes are promising in all-solid-state Li-metal batteries with high energy density and safety.However,both the low room-temperature ionic conductivities and the small Li^(+)transference number of these electrolytes significantly increase the internal resistance and overpotential of the battery.Here,we introduce Gd-doped CeO_(2) nanowires with large surface area and rich surface oxygen vacancies to the polymer electrolyte to increase the interaction between Gd-doped CeO_(2) nanowires and polymer electrolytes,which promotes the Li-salt dissociation and increases the concentration of mobile Li ions in the composite polymer electrolytes.The optimized composite polymer electrolyte has a high Li-ion conductivity of 5×10^(-4)4 S cm^(-1) at 30℃ and a large Li+transference number of 0.47.Moreover,the composite polymer electrolytes have excellent compatibility with the metallic lithium anode and high-voltage LiNi_(0.8)Mn _(0.1)Co_(0.1)O_(2)(NMC)cathode,providing the stable cycling of all-solid-state batteries at high current densities.

An overview of the policies and models of integrated development for solar and wind power generation in China

Under the goal of “Carbon Emission Peak and Carbon Neutralization”, the integrated development between various industries and renewable energy(photovoltaic, wind power) is of great significance in China. This paper summarizes the relevant policies, integration schemes and typical cases of the integrated development between renewable energy and other industries. First, the development status of wind and solar generation in China is introduced. Second, we summarize the relevant policies issued by the National Development and Reform Commission, National Energy Administration and other departments to promote the integrated development in photovoltaic and wind power generation in China. Third, eight kinds of photovoltaic three-dimensional development models are described, including “photovoltaic + agriculture, industry, environmental protection, transportation, architecture, communication, hydrogen and ecology”. Fourth, eight kinds of wind power threedimensional development models are summarized, including “Offshore wind power + marine ranch, marine energy, marine tourism, marine oil and gas, hydrogen, communication, Energy Island” and “Onshore wind power+ courtyard”. In the future, the promotion and application of the above integrated development projects will be accelerated. This overview aims to provide reference for the design in photovoltaic and wind energy systems and help potential investors to make decisions.

Comparative study of surface energy and land-surface parameters in different climate zones in Northwest China

Based on observational data of arid,semi-arid and semi-humid areas in Northwest China,the characteristics of surface-wa ter heat transfer and land-surface parameters were compared and analyzed.The results show that the annual mean net radi ation was largest in the semi-humid area,followed by the semi-arid area,and then the arid area:77.72 W/m^2,67.73 W/m^2,and 55.47 W/m^2,respectively.The annual mean sensible heat flux was largest in the arid area,followed by the semi-arid and semi-humid areas,while latent heat flux showed the reverse.The annual mean sensible heat flux in arid,semi-arid,and semi-humid areas was 85.7 W/m^2,37.59 W/m^2,and 27.55 W/m^2,respectively.The annual mean latent heat flux was 0 W/m^2,26.08 W/m^2,and 51.19 W/m2,respectively.The annual mean soil-heat flux at the 5-cm soil layer in arid,semi-arid,and semi-humid areas was 1.00 W/m^2,0.82 W/m^2,and 1.25 W/m^2,respectively.The annual mean surface albedo was larg est in the arid area,followed by the semi-humid area;and the smallest was in the semi-arid area:0.24,0.21,and 0.18,re spectively.The annual mean Bowen ratio in the semi-arid area was about 2.06,and that in semi-humid area was about 0.03.The annual mean soil thermal conductivity in the arid,semi-arid,and semi-humid areas was 0.26 W/(m k),1.15 W/(m k),and 1.20 W/(m k),respectively.

The application and comparison of several flux profile relations in CoLM

This paper discusses the important role that flux profile relations play in momentum flux, sensible heat flux, and latent heat flux simulations in CoLM （Common Land Model） and compares the application of three flux profile relation schemes in CoLM by means of the Loess Plateau Land-Atmosphere Interaction Pilot Experiment （LOPEX） of 2005. It reveals that the results simulated by the model barely changed in the original flux profile schemes of the models a^er eliminating the very stable condition and the very unstable condition, and there were only tiny changes in numerical values. This indicates that the corrected terms added to fm（ξm）,fh（ξh） were very tiny and can be ignored under very stable and very unstable circumstances. According to a comparison of the three flux profile relations, the simulation results were basically coherent by using any CoLM： the correlation coefficient of the simulation value and the observed value was 0.89, and this bears on the coherence with the numerical procedures for the flux pro- file relations under unstable circumstances. The simulation results were improved considerably by utilizing the Lobocki flux pro- file schemes, which numerical procedures under unstable circumstances differed significantly fi＇om other three flux profile schemes; in this case the correlation coefficient of the value of simulation and the observed value became 0.95. In the next itera- tion of this study, it will be of great importance for the development of the land surface process model to continue experimenting with the application of some novel flux profile schemes in the land surface process models in typical regions.

蓝光钙钛矿发光二极管:机遇与挑战

金属卤化钙钛矿由于具有优异的光电性能(如:高电子/空穴迁移率,高荧光量子产率,高色纯度,以及光色可调性等),成为应用于发光二极管(LED)的理想材料。近年来,钙钛矿LED的发展十分迅速,红光和绿光钙钛矿LED的外量子效率(EQE)均已超过20%。然而,蓝光(尤其是深蓝光)钙钛矿LED的EQE以及稳定性依然相对落后,这严重制约了钙钛矿LED在高性能、广色域显示领域和高显色指数白光照明领域的应用。因此,总结现阶段蓝光钙钛矿LED的发展,并剖析其机遇与挑战,对未来蓝光甚至整个钙钛矿LED领域的发展至关重要。本文将蓝光钙钛矿LED根据光色细分为天蓝光、纯蓝光、深蓝光三大部分进行总结,回顾了三种LED器件的发展历程,并详细阐述了现阶段实现他们的主要手段以及相关的基础原理,最后分析了它们各自的问题并提出了相应的解决思路。

Study on the atmospheric heat engine efficiency and heat source characteristics of the Qinghai-Tibet Plateau in summer

There are many types of atmospheric heat engines in land-air systems.The accurate definition,calculation and interpretation of the efficiency of atmospheric heat engines are key to understanding energy transfer and transformation of landair systems.The atmosphere over the Qinghai-Tibet Plateau(QTP)in summer can be regarded as a positive heat engine.The study of the heat engine efficiency is helpful to better understand land-air interaction and thermal-dynamic processes on the QTP.It also provides a new perspective to explain the impact of the QTP on the climate of China,East Asia and even the world.In this paper,we used MOD08 and ERA5 reanalysis data to calculate the atmospheric heat engine efficiency,surface heat source and atmospheric heat source on the QTP in summer(May to September)from 2000 to 2020.The average atmospheric heat engine efficiency on the QTP in summer from 2000 to 2020 varies between 1.2%and 1.5%,which is less than 1.6%;the heat engine efficiency in summer is higher than that in June,July and August;the Qaidam Basin is the region with the highest atmospheric heat engine efficiency,followed by the western QTP.The mean surface heat source on the QTP in summer from 2000 to 2020 is 96.0 W m^(−2),the atmospheric heat source is 90.7 W m^(−2),and the release of precipitation condensation latent heat is the most important component of the atmospheric heat source on the QTP in summer.There is a strong and significant positive correlation between the atmospheric heat engine efficiency and the surface heat source on the QTP in summer.The precipitation condensation latent heat is the most important component of the atmospheric heat source in summer and can reflect the precipitation process.There is a strong and significant negative correlation between the atmospheric heat engine efficiency and the atmospheric heat source on the QTP in summer.

Testing and Improving the Performance of the Common Land Model:A Case Study for the Gobi Landscape

Land surface processes take place on the interface between the earth and atmosphere, exerting significant influ- ences on the weather and climate. Correct modeling of these processes is important to numerical weather forecast and climate prediction. In order to obtain a more thorough understanding of the land surface processes over the Gobi landscape, we evaluated the performance of the Common Land Model （CoLM） at Dunhuang station in Gansu Province of China to determine whether the model formulation, driven by observational data, is capable of simulat- ing surface fluxes over the underlying desert surface. In comparison with the enhanced observation data collected at Dunhuang station over the period 22-28 August 2008, the results showed that the surface albedo simulated by CoLM was larger than that in the observation, and the simulated surface temperature was lower than the observed. After the measured values were used to correct the surface albedo, the solar radiation absorbed by the ground surface was more consistent with the measurements. A new empirical relationship of the surface thermal exchange coefficient r~ was used to modify the thermal aerodynamic impedance. The simulated soil surface temperature became significantly closer to the observed value, and the simulated surface sensible heat as well as net radiative fluxes were also im- proved,