We developed a fluorescent double network hydrogel with ionic responsiveness and high mechanical properties for visual detection.The nanocomposite hydrogel of laponite and polyacrylamide serves as the first network,wh...We developed a fluorescent double network hydrogel with ionic responsiveness and high mechanical properties for visual detection.The nanocomposite hydrogel of laponite and polyacrylamide serves as the first network,while the ionic cross-linked hydrogel of terbium ions and sodium alginate serves as the second network.The double-network structure,the introduction of nanoparticles and the reversible ionic crosslinked interactions confer high mechanical properties to the hydrogel.Terbium ions are not only used as the ionic cross-linked points,but also used as green emitters to endow hydrogels with fluorescent properties.On the basis of the “antenna effect” of terbium ions and the ion exchange interaction,the fluorescence of the hydrogels can make selective responses to various ions(such as organic acid radical ions,transition metal ions) in aqueous solutions,which enables a convenient strategy for visual detection toward ions.Consequently,the fluorescent double network hydrogel fabricated in this study is promising for use in the field of visual sensor detection.展开更多
Physical layer key generation(PKG)technology leverages the reciprocal channel randomness to generate the shared secret keys.The low secret key capacity of the existing PKG schemes is due to the reduction in degree-of-...Physical layer key generation(PKG)technology leverages the reciprocal channel randomness to generate the shared secret keys.The low secret key capacity of the existing PKG schemes is due to the reduction in degree-of-freedom from multipath fading channels to multipath combined channels.To improve the wireless key generation rate,we propose a multipath channel diversity-based PKG scheme.Assisted by dynamic metasurface antennas(DMA),a two-stage multipath channel parameter estimation algorithm is proposed to efficiently realize super-resolution multipath parameter estimation.The proposed algorithm first estimates the angle of arrival(AOA)based on the reconfigurable radiation pattern of DMA,and then utilizes the results to design the training beamforming and receive beamforming to improve the estimation accuracy of the path gain.After multipath separation and parameter estimation,multi-dimensional independent path gains are utilized for generating secret keys.Finally,we analyze the security and complexity of the proposed scheme and give an upper bound on the secret key capacity in the high signal-to-noise ratio(SNR)region.The simulation results demonstrate that the proposed scheme can greatly improve the secret key capacity compared with the existing schemes.展开更多
基金Funded by the National Natural Science Foundation of China(No.51873167)the National Innovation and Entrepreneurship Training Program for College Students(No.226801001)。
文摘We developed a fluorescent double network hydrogel with ionic responsiveness and high mechanical properties for visual detection.The nanocomposite hydrogel of laponite and polyacrylamide serves as the first network,while the ionic cross-linked hydrogel of terbium ions and sodium alginate serves as the second network.The double-network structure,the introduction of nanoparticles and the reversible ionic crosslinked interactions confer high mechanical properties to the hydrogel.Terbium ions are not only used as the ionic cross-linked points,but also used as green emitters to endow hydrogels with fluorescent properties.On the basis of the “antenna effect” of terbium ions and the ion exchange interaction,the fluorescence of the hydrogels can make selective responses to various ions(such as organic acid radical ions,transition metal ions) in aqueous solutions,which enables a convenient strategy for visual detection toward ions.Consequently,the fluorescent double network hydrogel fabricated in this study is promising for use in the field of visual sensor detection.
基金supported in part by the National Natural Science Foundation of China(No.U22A2001)the National Key Research and Development Program of China(No.2022YFB2902202,No.2022YFB2902205)。
文摘Physical layer key generation(PKG)technology leverages the reciprocal channel randomness to generate the shared secret keys.The low secret key capacity of the existing PKG schemes is due to the reduction in degree-of-freedom from multipath fading channels to multipath combined channels.To improve the wireless key generation rate,we propose a multipath channel diversity-based PKG scheme.Assisted by dynamic metasurface antennas(DMA),a two-stage multipath channel parameter estimation algorithm is proposed to efficiently realize super-resolution multipath parameter estimation.The proposed algorithm first estimates the angle of arrival(AOA)based on the reconfigurable radiation pattern of DMA,and then utilizes the results to design the training beamforming and receive beamforming to improve the estimation accuracy of the path gain.After multipath separation and parameter estimation,multi-dimensional independent path gains are utilized for generating secret keys.Finally,we analyze the security and complexity of the proposed scheme and give an upper bound on the secret key capacity in the high signal-to-noise ratio(SNR)region.The simulation results demonstrate that the proposed scheme can greatly improve the secret key capacity compared with the existing schemes.
