Magnesium silicate hydroxides(MSHs)with granular,schistose,and tubular morphologies were separately incorporated to enhance the tribological properties of phosphate/MoS2 composite coatings.The nano-schistose MSH demon...Magnesium silicate hydroxides(MSHs)with granular,schistose,and tubular morphologies were separately incorporated to enhance the tribological properties of phosphate/MoS2 composite coatings.The nano-schistose MSH demonstrated superior tribological performance due to its effective interactions with the worn surface and frictional synergies with solid lubricants.Incorporation of nano-schistose MSH decreased the friction coefficient of composite coatings by about 34.7%and increased the anti-wear performance of composite coatings by about thirteen times.Nano-schistose MSH facilitated the formation of a friction-induced multi-layer heterogenous slipping structure with layered solid lubricants at the friction interface.Moreover,tribo-chemical reactions between nano-schistose MSH and worn surface promoted the in-situ formation of a cermet supporting film,and this also induced the gradual in-situ formation of a lubrication film on the top of worn surface.Consequently,the contact state between tribo-pairs was timely regulated and the invalidation of the nanocomposite slipping structure was effectively restrained during the friction process.As a result,the service life of the phosphate composite coatings was significantly extended and further abrasion on the worn surface was notably reduced.展开更多
基金Financial assistances of the National Key R&D Program of China(No.2022YFB3809000)the National Natural Science Foundation of China(No.52105228)the Defense Industrial Technology Development Program(No.JCKY2021130B038)were greatly appreciated.
文摘Magnesium silicate hydroxides(MSHs)with granular,schistose,and tubular morphologies were separately incorporated to enhance the tribological properties of phosphate/MoS2 composite coatings.The nano-schistose MSH demonstrated superior tribological performance due to its effective interactions with the worn surface and frictional synergies with solid lubricants.Incorporation of nano-schistose MSH decreased the friction coefficient of composite coatings by about 34.7%and increased the anti-wear performance of composite coatings by about thirteen times.Nano-schistose MSH facilitated the formation of a friction-induced multi-layer heterogenous slipping structure with layered solid lubricants at the friction interface.Moreover,tribo-chemical reactions between nano-schistose MSH and worn surface promoted the in-situ formation of a cermet supporting film,and this also induced the gradual in-situ formation of a lubrication film on the top of worn surface.Consequently,the contact state between tribo-pairs was timely regulated and the invalidation of the nanocomposite slipping structure was effectively restrained during the friction process.As a result,the service life of the phosphate composite coatings was significantly extended and further abrasion on the worn surface was notably reduced.
