This study synthesized UiO-66(Zr)in situ on wood via a one-step solvothermal method.UiO-66/wood was successfully prepared and its catalytic performance for the ofloxacin(OFX)photodegradation under simulate sunlight wa...This study synthesized UiO-66(Zr)in situ on wood via a one-step solvothermal method.UiO-66/wood was successfully prepared and its catalytic performance for the ofloxacin(OFX)photodegradation under simulate sunlight was also explored.UiO-66/wood exhibited a better catalytic performance,and its degradation rate constant was about 1.2 and 1.5 times than that of UiO-66 and wood,respectively.The effects of solution initial concentration,pH of the system and dosage of the photocatalyst were explored.Additionally,the active species trapping experiments and UV-vis diffused reflectance spectra measurements were conducted to investigated the photocatalytic mechanism of the UiO-66/wood composite,superoxide radical(O_(2)^(·-))and hydroxyl radical(^(·)OH)were the main reactive species.In addition,the possible degradation pathways of OFX were analyzed by LC-MS.Meanwhile,the UiO-66/wood showed outstanding stability and reusability after 4 cycles experiments.The removal performance of UiO-66/wood towards real samples showed it has potential in actual application.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21777131 and 21677117)Science and Technology Department Foundation of Sichuan Province(Nos.2018GZ0400 and 2018SZDZX0026)the Fundamental Research Funds for the Central Universities(No.A0920502052001–6)。
文摘This study synthesized UiO-66(Zr)in situ on wood via a one-step solvothermal method.UiO-66/wood was successfully prepared and its catalytic performance for the ofloxacin(OFX)photodegradation under simulate sunlight was also explored.UiO-66/wood exhibited a better catalytic performance,and its degradation rate constant was about 1.2 and 1.5 times than that of UiO-66 and wood,respectively.The effects of solution initial concentration,pH of the system and dosage of the photocatalyst were explored.Additionally,the active species trapping experiments and UV-vis diffused reflectance spectra measurements were conducted to investigated the photocatalytic mechanism of the UiO-66/wood composite,superoxide radical(O_(2)^(·-))and hydroxyl radical(^(·)OH)were the main reactive species.In addition,the possible degradation pathways of OFX were analyzed by LC-MS.Meanwhile,the UiO-66/wood showed outstanding stability and reusability after 4 cycles experiments.The removal performance of UiO-66/wood towards real samples showed it has potential in actual application.
