[Objectives] The aim was to reveal the accumulation characteristics and differences of biomass productivity of Taiwania flousiana plantation and successive rotation plantation of Cunninghamia lanceolata .[Methods] The...[Objectives] The aim was to reveal the accumulation characteristics and differences of biomass productivity of Taiwania flousiana plantation and successive rotation plantation of Cunninghamia lanceolata .[Methods] The biomass and productivity of the 23-year-old T. flousiana plantation and successive rotation plantation of C. lanceolata were studied at Nandan Shankou Forestry Farm of Guangxi., China.[Results] There were differences in the biomass distribution of different organs of T. flousiana plantation and successive rotation plantation of C.lanceolata. The biomass for the T. flousiana plantation was distributed in the order of stem 〉 branch 〉 leaves 〉 bark, and the successive rotation plantations of C. lanceolata was stem〉 root 〉 branch 〉 bark 〉 leaves. The biomass of tree layer of 23-years-old T. flousiana plantation and successive rotation plantations were 195.21 and 136.82 t/hm^2, respectively, including 113.32 and 87.91 t/hm^2 of economic biomass (stem). The annual net productivity of tree layer of the 2 plantations were 8.49 and 5.95 t/(hm^2·a), respectively, including 5.14 and 3.82 t/(hm^2·a) of stem. Therefore, T. flousiana plantation has higher biomass accumulation ability than that of successive rotation plantations of C.lanceolata, and can be used as an excellent substitute tree species for the regeneration of C.lanceolata cutover plantation.[Conclusions]展开更多
Transparent glass has been identified as a vital medium for three-dimensional(3D)optical information storage and multi-level encryption.However,it has remained a challenge for directly writing 3D patterning inside a t...Transparent glass has been identified as a vital medium for three-dimensional(3D)optical information storage and multi-level encryption.However,it has remained a challenge for directly writing 3D patterning inside a transparent glass using semiconductor blue laser instead of high-cost femtosecond laser.Here,we demonstrate that rare earth ions doped transparent glass can be used as 3D optical information storage and data encryption medium based on their reversible transmittance and photoluminescence manipulation.The color of tungsten phosphate glass doped with rare earth ions change reversibly from light yellow to blue upon alternating 473 nm laser illumination and temperature stimulation,resulting in the reversible luminescence modulation.The information data could be repeatedly written and erased in arbitrary 3D space of transparent glass,not only showing the ability of the excellent reproducibility and storage capacity,but also opening opportunities in information security.The present work expands the application fields of luminescent glass,and it is conducive to develop a novel 3D data storage and information encryption media.展开更多
Exploring a new tuning way to facilely realize single-band red emission in trivalent rare-earth ions(RE3+) doped upconversion(UC) materials is still desirable.In this work,the intense single-band red emission is achie...Exploring a new tuning way to facilely realize single-band red emission in trivalent rare-earth ions(RE3+) doped upconversion(UC) materials is still desirable.In this work,the intense single-band red emission is achieved by co-doping only Ho3+in the BiOCl:Er3+ under 1550 nm excitation.In the BiOCl layered host,co-doping Ho3+can further enhance the red emission and simultaneously suppress the green emission of Er3+,and thus obviously improve the red-to-green(R/G) ratio.It is found that Ho3+does not se rve as ene rgy trapping through the 5 I6 state as in traditional UC materials but acts as ET bridge(4 S3/2,2 H11/2(Er3+)→5 F4,5 S2(Ho3+)→4 F9/2(Er3+)).The tuning mechanism of Ho3+is discussed in detail and further confirms through a comparative experiment.Our research gives an unusual perspective to tune the UC behavior of Er3+through co-doping Ho3+,which might be inspiring for achievement of single-band red UC emission.展开更多
Dear Editor,Tungsten-based photochromic materials are well known,suchastungsten-phosphateglasses,tungsten-telluriteglasses,andtungsten-borateglasses'.Photoluminescence glasses exhibit a wide range of application i...Dear Editor,Tungsten-based photochromic materials are well known,suchastungsten-phosphateglasses,tungsten-telluriteglasses,andtungsten-borateglasses'.Photoluminescence glasses exhibit a wide range of application in the fields of display,lighting,laser and optical thermometry,et al.Combination of photochromic and luminescence can extend the application of luminescence materials2-7.Our focus is not on the development of new photochromic materials,but on the control of luminescence through photochromic reaction,especially achieved the real complex threedimensional patterns using laser directly writing technology in photo-modulated transparent glass.In our work2,the three-dimensional optical data storage and information encryption application of photochromic glass with luminescence was obtained.展开更多
Photonic crystal heterostructures composed of YbPO4:Er^(3+) inverse opal and polystyrene opal were prepared via a template-assisted process, which exhibited two photonic band gaps. The microstructure,phase and opt...Photonic crystal heterostructures composed of YbPO4:Er^(3+) inverse opal and polystyrene opal were prepared via a template-assisted process, which exhibited two photonic band gaps. The microstructure,phase and optical properties of photonic crystal heterostructures were investigated by x-ray diffraction,scanning electron microscopy, fluorescence spectroscopy, absorption spectroscopy, fluorescence lifetime,etc. The upconversion emission suppression caused by single photonic band gap from the following YbPO4:Er^(3+) inverse opal or the upper opal was observed. The upconversion luminescence was strongly suppressed due to the two photonic band gap overlapping effect caused by the following YbPO4:Er^(3+) inverse opal or the upper opal. The modified mechanisms of upconversion luminescence were discussed by the upconversion luminescence lifetime of YbPO4:Er^(3+) photonic crystal heterostructures. The results demonstrated the modified upconversion luminescence is attributed to the photon trapping caused by Bragg reflection of photonic crystal heterostructures.展开更多
BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3+/Sm^3+ co-doped BiOCl phosphors as single-phase phosphors were reported. Upo...BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3+/Sm^3+ co-doped BiOCl phosphors as single-phase phosphors were reported. Upon near ultraviolet excitation(NUV, 380 nm corresponding the ^4 I15/2→ ^4 G11/2 transition of Er^3+ ions), the phosphors exhibit the efficient characteristic emissions of Er^3+ and Sm^3+ ions simultaneously. The energy transfer(ET) from Er^3+ to Sm^3+ ions in the layered crystals has been validated by the variation of emission intensities and decay lifetimes respectively, which is ascribed to be a dipoledipole interaction. By virtue of the ET behavior and increasing Sm^3+ ion concentration, the enhancing emission intensity of Sm^3+ and the tunability of emission color from yellowish-green(0.318, 0.420) to white(0.343, 0.347) are realized. The results of our work indicate that the Er^3+/Sm^3+ co-doped BiOCI phosphor has a promising application serving as single component white emitting phosphors for NUV excited WLEDs.展开更多
基金Supported by Guangxi Key R&D Plan Project(Guike AB17292008)Major Science and Technology Project of Guangxi Forestry(Guilin Science Word[2010]No.7)Guangxi Science Research and Technology Development Plan Program(Guikeneng 159825-38)
文摘[Objectives] The aim was to reveal the accumulation characteristics and differences of biomass productivity of Taiwania flousiana plantation and successive rotation plantation of Cunninghamia lanceolata .[Methods] The biomass and productivity of the 23-year-old T. flousiana plantation and successive rotation plantation of C. lanceolata were studied at Nandan Shankou Forestry Farm of Guangxi., China.[Results] There were differences in the biomass distribution of different organs of T. flousiana plantation and successive rotation plantation of C.lanceolata. The biomass for the T. flousiana plantation was distributed in the order of stem 〉 branch 〉 leaves 〉 bark, and the successive rotation plantations of C. lanceolata was stem〉 root 〉 branch 〉 bark 〉 leaves. The biomass of tree layer of 23-years-old T. flousiana plantation and successive rotation plantations were 195.21 and 136.82 t/hm^2, respectively, including 113.32 and 87.91 t/hm^2 of economic biomass (stem). The annual net productivity of tree layer of the 2 plantations were 8.49 and 5.95 t/(hm^2·a), respectively, including 5.14 and 3.82 t/(hm^2·a) of stem. Therefore, T. flousiana plantation has higher biomass accumulation ability than that of successive rotation plantations of C.lanceolata, and can be used as an excellent substitute tree species for the regeneration of C.lanceolata cutover plantation.[Conclusions]
基金supported by the National Natural Science Foundation of China (51762029, 11674137)the Applied Basic Research Key Program of Yunnan Province (2018FA026)
基金the National Natural Science Foundation of China(51762029,62075063,51772101)the Applied Basic Research Key Program of Yunnan Province(2018FA026)the Key R&D Program of Guangzhou(202007020003).
文摘Transparent glass has been identified as a vital medium for three-dimensional(3D)optical information storage and multi-level encryption.However,it has remained a challenge for directly writing 3D patterning inside a transparent glass using semiconductor blue laser instead of high-cost femtosecond laser.Here,we demonstrate that rare earth ions doped transparent glass can be used as 3D optical information storage and data encryption medium based on their reversible transmittance and photoluminescence manipulation.The color of tungsten phosphate glass doped with rare earth ions change reversibly from light yellow to blue upon alternating 473 nm laser illumination and temperature stimulation,resulting in the reversible luminescence modulation.The information data could be repeatedly written and erased in arbitrary 3D space of transparent glass,not only showing the ability of the excellent reproducibility and storage capacity,but also opening opportunities in information security.The present work expands the application fields of luminescent glass,and it is conducive to develop a novel 3D data storage and information encryption media.
基金the National Natural Science Foundation of China(11874186)the Applied Basic Research Program of Yunnan Province(2017FB079)+1 种基金the Reserve Talents Project of Yunnan Province(2015HB013)the Scientific Research Foundation of the Education Department of Yunnan Province(2018JS452)。
文摘Exploring a new tuning way to facilely realize single-band red emission in trivalent rare-earth ions(RE3+) doped upconversion(UC) materials is still desirable.In this work,the intense single-band red emission is achieved by co-doping only Ho3+in the BiOCl:Er3+ under 1550 nm excitation.In the BiOCl layered host,co-doping Ho3+can further enhance the red emission and simultaneously suppress the green emission of Er3+,and thus obviously improve the red-to-green(R/G) ratio.It is found that Ho3+does not se rve as ene rgy trapping through the 5 I6 state as in traditional UC materials but acts as ET bridge(4 S3/2,2 H11/2(Er3+)→5 F4,5 S2(Ho3+)→4 F9/2(Er3+)).The tuning mechanism of Ho3+is discussed in detail and further confirms through a comparative experiment.Our research gives an unusual perspective to tune the UC behavior of Er3+through co-doping Ho3+,which might be inspiring for achievement of single-band red UC emission.
文摘Dear Editor,Tungsten-based photochromic materials are well known,suchastungsten-phosphateglasses,tungsten-telluriteglasses,andtungsten-borateglasses'.Photoluminescence glasses exhibit a wide range of application in the fields of display,lighting,laser and optical thermometry,et al.Combination of photochromic and luminescence can extend the application of luminescence materials2-7.Our focus is not on the development of new photochromic materials,but on the control of luminescence through photochromic reaction,especially achieved the real complex threedimensional patterns using laser directly writing technology in photo-modulated transparent glass.In our work2,the three-dimensional optical data storage and information encryption application of photochromic glass with luminescence was obtained.
基金Project supported by the National Natural Science Foundation of China(11674137)the Applied Basic Research Program of Yunnan Province(2014FB127)+1 种基金Reserve Talents Project of Yunnan Province(2012HB068)Talent Youth Science Foundation of College of Materials Science and Technology,Kunming University of Science and Technology(20140205)
文摘Photonic crystal heterostructures composed of YbPO4:Er^(3+) inverse opal and polystyrene opal were prepared via a template-assisted process, which exhibited two photonic band gaps. The microstructure,phase and optical properties of photonic crystal heterostructures were investigated by x-ray diffraction,scanning electron microscopy, fluorescence spectroscopy, absorption spectroscopy, fluorescence lifetime,etc. The upconversion emission suppression caused by single photonic band gap from the following YbPO4:Er^(3+) inverse opal or the upper opal was observed. The upconversion luminescence was strongly suppressed due to the two photonic band gap overlapping effect caused by the following YbPO4:Er^(3+) inverse opal or the upper opal. The modified mechanisms of upconversion luminescence were discussed by the upconversion luminescence lifetime of YbPO4:Er^(3+) photonic crystal heterostructures. The results demonstrated the modified upconversion luminescence is attributed to the photon trapping caused by Bragg reflection of photonic crystal heterostructures.
基金Project supported by the National Natural Science Foundation of China(No.61465006)the Reserve talents project of Yunnan Province(2015HB013)
文摘BiOCl crystal shows potential as efficient optical host due to its special layered structure. Here,the luminescence properties of the Er^3+/Sm^3+ co-doped BiOCl phosphors as single-phase phosphors were reported. Upon near ultraviolet excitation(NUV, 380 nm corresponding the ^4 I15/2→ ^4 G11/2 transition of Er^3+ ions), the phosphors exhibit the efficient characteristic emissions of Er^3+ and Sm^3+ ions simultaneously. The energy transfer(ET) from Er^3+ to Sm^3+ ions in the layered crystals has been validated by the variation of emission intensities and decay lifetimes respectively, which is ascribed to be a dipoledipole interaction. By virtue of the ET behavior and increasing Sm^3+ ion concentration, the enhancing emission intensity of Sm^3+ and the tunability of emission color from yellowish-green(0.318, 0.420) to white(0.343, 0.347) are realized. The results of our work indicate that the Er^3+/Sm^3+ co-doped BiOCI phosphor has a promising application serving as single component white emitting phosphors for NUV excited WLEDs.