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电子级HEA制备中痕量钠钾离子吸附及过程模拟
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作者 陈寿天宝 张凯 +3 位作者 许振良 程亮 徐孙杰 魏永明 《过程工程学报》 CAS CSCD 北大核心 2024年第7期843-851,共9页
丙烯酸羟乙酯(HEA)是一种应用广泛的化工原料,目前电子级HEA分离纯化的研究文献报道较少。本工作采用离子交换树脂吸附方式,在去除Na^(+)和 K^(+)的同时避免了HEA自身高温环境下发生聚合降低产品纯度的问题。通过树脂静态吸附实验,拟合... 丙烯酸羟乙酯(HEA)是一种应用广泛的化工原料,目前电子级HEA分离纯化的研究文献报道较少。本工作采用离子交换树脂吸附方式,在去除Na^(+)和 K^(+)的同时避免了HEA自身高温环境下发生聚合降低产品纯度的问题。通过树脂静态吸附实验,拟合得到HEA中Na^(+)和 K^(+)的动力学模型及特性;通过比较Langmuir等温吸附模型与Freundlich吸附模型的拟合度,选择拟合度更好的Langmuir模型,并由此得到的Langmuir等温吸附线获得Na^(+)与K^(+)树脂最大吸附量。通过动态吸附实验获得Na^(+)及K^(+)在该树脂上的穿透曲线,并通过AspenAdsorption模拟动态吸附过程,得到床层工作状态与吸附时间的关系,实验值与模型值符合良好。因此,模拟结果为电子级HEA的应用提供了相关参数及数据支持。 展开更多
关键词 电子级HEA 离子交换树脂 吸附 金属离子 Aspen Adsorption模拟
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Advanced treatment of dyeing wastewater towards reuse by the combined Fenton oxidation and membrane bioreactor process 被引量:27
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作者 Fei Feng zhenliang xu +2 位作者 Xiaohuan Li Wenting You Yang Zhen 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2010年第11期1657-1665,共9页
The performance of combined Fenton oxidation and membrane bioreactor (MBR) process for the advanced treatment of an effluent from an integrated dyeing wastewater treatment plant was evaluated. The experimental resul... The performance of combined Fenton oxidation and membrane bioreactor (MBR) process for the advanced treatment of an effluent from an integrated dyeing wastewater treatment plant was evaluated. The experimental results revealed that under the optimum Fenton oxidation conditions (initial pH 5, H 2 O 2 dosage 17 mmol/L, and Fe^ 2+ 1.7 mmol/L) the average total organic carbon (TOC) and color removal ratios were 39.3% and 69.5% after 35 min of reaction, respectively. Results from Zahn-Wallens Test also represented that Fenton process was effective to enhance the biodegradability of the test wastewater. As for the further purification of MBR process, TOC removal capacity was examined at different hydraulic retention times (HRT) of 10, 18 and 25 hr. Under the optimum HRT of 18 hr, the average TOC concentration and color of the final MBR effluent were 16.8 mg/L and 2 dilution time, respectively. The sludge yield coefficient was 0.13 g MLSS/g TOC and TOC degradation rate was 0.078 kg TOC/(m ^3 ·day). The final effluent of MBR can meet the reuse criteria of urban recycling water – water quality standard for miscellaneous water consumption GBT18920-2002. 展开更多
关键词 dyeing wastewater Fenton oxidation membrane bioreactor Zahn-Wallens Test
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Formation of microporous polymeric membranes via thermally induced phase separation: A review 被引量:11
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作者 Min Liu Shenghui Liu +2 位作者 zhenliang xu Yongming Wei Hu Yang 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2016年第1期57-75,共19页
A review of recent research related to micro- porous polymeric membranes formed via thermally induced phase separation (TIPS) and the morphologies of these membranes is presented. A summary of polymers and suitable ... A review of recent research related to micro- porous polymeric membranes formed via thermally induced phase separation (TIPS) and the morphologies of these membranes is presented. A summary of polymers and suitable diluents that can be used to prepare these microporous membranes via TIPS are summarized. The effects of different kinds of polymer materials, diluent types, cooling conditions, extractants and additive agents on the morphology and performance of TIPS membranes are also discussed. Finally new developments in TIPS technology are summarized. 展开更多
关键词 POLYMER microporous membrane thermally induced phase separation
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