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协同光电及热效应实现铜光阴极上等离激元催化高效硝酸根还原反应
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作者 陈振霖 薛静 +5 位作者 武磊 党昆 籍宏伟 陈春城 章宇超 赵进才 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第7期219-230,共12页
近年来,电催化硝酸根还原反应(NO_(3)RR)已经成为水处理和合成氨领域的研究热点.相比于传统的电催化剂,等离激元辅助的电催化反应通过将太阳能和电化学偏压同时施加到金属纳米结构上,在实现高效太阳能到化学能转化领域展现出了巨大潜力... 近年来,电催化硝酸根还原反应(NO_(3)RR)已经成为水处理和合成氨领域的研究热点.相比于传统的电催化剂,等离激元辅助的电催化反应通过将太阳能和电化学偏压同时施加到金属纳米结构上,在实现高效太阳能到化学能转化领域展现出了巨大潜力.然而,目前有关等离激元辅助NO_(3)RR的文献报道较少,已有的研究主要集中于利用金(Au)纳米结构的等离激元效应辅助增强NO_(3)RR.但Au对NO_(3)RR的本征电催化活性很差,这导致在等离激元辅助NO_(3)RR领域,氨的产率和法拉第效率难以令人满意.此外,对于等离激元辅助NO_(3)RR的机理研究不深入,例如如何区分等离激元产生的光电效应和光热效应对NO_(3)RR的影响,以及等离激元激发的金属纳米结构是如何影响NO_(3)RR过程等问题都尚未解决.因此,有必要采取有效的策略来深入探究等离激元辅助NO_(3)RR的内在机制,从而进一步提高其催化性能.铜(Cu)作为一种高效的硝酸根还原电催化剂,同时是一种典型的具有等离激元效应的金属材料.然而,目前关于利用Cu的等离激元效应辅助增强NO_(3)RR的报道很少.本文报道了利用Cu纳米线(CuNWs)的等离激元效应辅助增强NO_(3)RR性能.在等离激元激发条件下,CuNWs展现出较好的NO_(3)RR催化性能.在协同的光电和热效应的作用下,与暗态常温条件相比,催化性能提升了近2倍.经过400次循环伏安测试,CuNWs光阴极的电流密度仅下降到初始值的88%,而在黑暗条件下,CuNWs光阴极催化NO_(3)RR的电流密度则下降了43%.这表明光照同时显著提升了CuNWs催化NO_(3)RR的稳定性.产物分析结果表明,在-0.2到-0.4 V(相对于可逆氢电极)的宽电势范围内,CuNWs光阴极实现了接近100%的氨法拉第效率,并取得了较高的氨产率,超过了之前大多数报道的等离激元辅助Au催化剂的NO_(3)RR性能.通过活化能实验、微分电流实验以及升温实验,区分了等离激元激发产生的光电效应以及光热效应对NO_(3)RR的影响.通过原位拉曼光谱、在线差分电化学质谱以及原位电化学红外光谱技术,确定了CuNWs光阴极NO_(3)RR过程中的活性相及反应中间体.密度泛函理论计算结果表明,氨的脱附是NO_(3)RR的决速步.光生电子可以通过电子跃迁激发脱附机制促进氨的脱附从而抑制了氨在Cu表面的累积,弱化了氨对CuNWs光阴极的毒化作用.同时,光热效应也显著提升了NO_(3)RR的反应速率.因此,等离激元激发产生的光电和光热效应协同促进了NO_(3)RR性能,提高了CuNWs光阴极的活性与稳定性.将该策略拓展到其它Cu纳米材料上,同样展现出较好的等离激元促进效果.综上,本文提出了利用Cu的等离激元效应辅助增强电催化NO_(3)RR性能的策略,并验证了该策略在其它Cu纳米材料上的适用性.深入的机理研究揭示了同时耦合太阳能、电能以及热能对进一步提升NO_(3)RR性能的巨大潜力. 展开更多
关键词 铜光阴极 等离激元辅助电催化剂 光电效应 光热效应 硝酸根还原反应
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Meta-Analysis of the Clinical Effect of Acupuncture on Postherpetic Neuralgia
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作者 Lu Wang zhenlin chen +2 位作者 Shuo Zhang Wenjing Ma Tiantian Gao 《Proceedings of Anticancer Research》 2022年第1期20-32,共13页
Objective:To systematically evaluate the safety and efficacy of acupuncture on patients with postherpetic neuralgia.Methods:Based on the heyword retrieval method,China National Knowledge Infrastructure(CNKI,1978-2020)... Objective:To systematically evaluate the safety and efficacy of acupuncture on patients with postherpetic neuralgia.Methods:Based on the heyword retrieval method,China National Knowledge Infrastructure(CNKI,1978-2020),China Biomedical Literature database(CBM,1979-2020),VIP database(WEIPU,1989-2020),Wanfang database(1989-2020),Cochrane Library,PubMed,and Embase were searched;randomized controlled trials of the use of acupuncture in the treatment of postherpetic neuralgia were screened out;the quality of the included literatures was evaluated based on the evaluation criteria in the Cochrane Handbook,and meta-analysis was performed using RevMan 5.3.Results:Twenty-six literatures that met the criteria,involving 2,174 patients,were included;the meta-analysis showed that compared with western medicine,the use of acupuncture can improve the overall effective rate(RR=1.24,95%CI[1.17,1.32],P<0.00001)and reduce the VAS score(MD=-1.43,95%CI[-1.97,-0.89],P<0.00001).Conclusion:The use of acupuncture can further improve the clinical effect of patients with postherpetic neuralgia. 展开更多
关键词 ACUPUNCTURE Postherpetic neuralgia META-ANALYSIS Clinical effect VAS score
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Discussion on the Application of Warm Yang to Promote Qi Transformation in Acne Mastitis from“Yang Promotes Qi Transformation and Yin Promotes Forming”
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作者 Yupei chen zhenlin chen Pu Zhang 《Journal of Clinical and Nursing Research》 2021年第6期155-158,共4页
“Yang promotes Qi transformation and Yin promotes forming”maintains the normal progress of human life activities,which is an important embodiment of human vitality.The dysfunction of“Yang promotes Qi transformation... “Yang promotes Qi transformation and Yin promotes forming”maintains the normal progress of human life activities,which is an important embodiment of human vitality.The dysfunction of“Yang promotes Qi transformation and Yin promotes forming”leads to the coagulation of pathological products such as phlegm and blood stasis in the breast meridian,resulting in the occurrence of acne mastitis.In clinical treatment,we should take“warm Yang to promote Qi transformation”as the treatment principle,and add or subtract according to the specific situation. 展开更多
关键词 Yang promotes Qi transformation and Yin promotes formation Warm Yang to promote Qi transformation Acne mastitis
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爆炸载荷下裂纹扩展的数值研究 被引量:4
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作者 蒲传金 杨鑫 +4 位作者 赵晗 陈臻林 肖定军 周昌林 薛冰 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2022年第1期123-136,共14页
脆性材料中动态裂纹扩展在理解断裂机制方面起着重要作用.通过Autodyn3D软件对有机玻璃(PMMA)在爆炸载荷下裂纹扩展进行了数值模拟.尽管Johnson-Holmquist(JH-2)模型被广泛认为是--种可接受的方案,但它不能改善对材料破坏后响应的描述,... 脆性材料中动态裂纹扩展在理解断裂机制方面起着重要作用.通过Autodyn3D软件对有机玻璃(PMMA)在爆炸载荷下裂纹扩展进行了数值模拟.尽管Johnson-Holmquist(JH-2)模型被广泛认为是--种可接受的方案,但它不能改善对材料破坏后响应的描述,也不能减少对网格的依赖性,因此本文基于两个破坏准则,引入了拉伸断裂软化失效模型、首先,根据现有数据和计算,确定了JH-2模型、失效准则和裂纹软化失效模型的材料参数.通过对圆形和矩形薄板进行建模,以探讨单孔和双孔爆炸下的断裂机制.模拟结果很好地再现了破碎区和断裂区的整个动态演化过程,裂纹的起裂、扩展和止裂以及二次扩展,成功地证明了JH-2构成模型、失效准则和拉伸软化失效模型的组合及相应材料参数的可靠性.对于双孔爆炸,当孔距L=20和30cm时,裂纹贯穿良好;在L=40 cm时,虽然主裂缝已经延伸至对侧的断裂区,但裂缝未能相互贯穿.更重要的是,发现裂缝的贯穿主要取决于L,其对贯穿方式和贯穿位置有重要影响、尽管较大的L使裂缝贯穿更加困难,但该困难不在于裂缝长度不足,而在于失去了对双孔间裂纹定向扩展的控制. 展开更多
关键词 断裂区 破坏准则 双孔 失效模型 失效准则 爆炸载荷 裂纹扩展 裂缝长度
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RELATIONSHIP BETWEEN HORIZONTAL EXTINCTION COEFFICIENT AND PM_(10) CONCENTRATION IN XI'AN,CHINA,DURING 1980-2002 被引量:3
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作者 Huizheng Che Xiaoye Zhang +2 位作者 Yang Li Zijiang Zhou zhenlin chen 《China Particuology》 SCIE EI CAS CSCD 2006年第6期327-329,共3页
Based on daily visibility data obtained from 1980-2002 and air pollution index data from 2001-2004 in Xi'an, long-term variations and relationships for daily horizontal extinction coefficient and mass concentration o... Based on daily visibility data obtained from 1980-2002 and air pollution index data from 2001-2004 in Xi'an, long-term variations and relationships for daily horizontal extinction coefficient and mass concentration of PM10 have been evaluated. A decreasing trend was found in horizontal extinction coefficient during the past 23 years, with higher values observed in 1980s relative to 1990s, and the highest and lowest values in winter and summer, respectively. Significant correlation and similar seasonal variations existed between horizontal extinction coefficient and PM10 concentration, suggesting the high influence of PM10 to the visibility drop at a site in the Guanzhong Plain of central China during the past two decades. 展开更多
关键词 VISIBILITY AEROSOL horizontal extinction coefficient air pollution index Xi'an
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A valveless piezoelectric pump with novel flow path design of function of rectification to improve energy efficiency
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作者 Jianhui ZHANG Xiaosheng chen +5 位作者 zhenlin chen Jietao DAI Fan ZHANG Mingdong MA Yuxuan HUO Zhenzhen GUI 《Frontiers of Mechanical Engineering》 SCIE CSCD 2022年第3期177-193,共17页
Existing valveless piezoelectric pumps are mostly based on the flow resistance mechanism to generate unidirectional fluid pumping,resulting in inefficient energy conversion because the majority of mechanical energy is... Existing valveless piezoelectric pumps are mostly based on the flow resistance mechanism to generate unidirectional fluid pumping,resulting in inefficient energy conversion because the majority of mechanical energy is consumed in terms of parasitic loss.In this paper,a novel tube structure composed of a Y-shaped tube and aȹ-shaped tube was proposed considering theory of jet inertia and vortex dissipation for the first time to improve energy efficiency.After verifying its feasibility through the flow field simulation,the proposed tubes were integrated into a piezo-driven chamber,and a novel valveless piezoelectric pump with the function of rectification(NVPPFR)was reported.Unlike previous pumps,the reported pump directed the reflux fluid to another flow channel different from the pumping fluid,thus improving pumping efficiency.Then,mathematical modeling was established,including the kinetic analysis of vibrator,flow loss analysis of fluid,and pumping efficiency.Eventually,experiments were designed,and results showed that NVPPFR had the function of rectification and net pumping effect.The maximum flow rate reached 6.89 mL/min,and the pumping efficiency was up to 27%.The development of NVPPFR compensated for the inefficiency of traditional valveless piezoelectric pumps,broadening the application prospect in biomedicine and biology fields. 展开更多
关键词 composite tube valveless piezoelectric pump RECTIFICATION energy efficiency
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