城市地质学基础理论探讨

城市地质有近百年的研究历史,学科研究取得了很大的进展,但是总体上看,学科性质存在较多的争论,城市地质学基础理论难于满足现代城市管理的需求,无法为城市高质量发展提供系统完整的地学解决方案。本文系统梳理了国内外城市地质的发展历程和研究进展,进一步明确了城市地质学的学科性质,运用系统理论提出城市地质系统的概念,并基于这一概念,清晰地界定了城市地质学的研究对象,阐述了现代城市地质学的研究内容和技术框架,为今后形成完善的城市地质学理论体系提供研究基础。

面向室内定位的WIFI探针数据预处理研究

为验证依据多探针同时感知到的同一WIFI终端的RSSI值辨识WIFI终端是否在指定区域内的可行性,本文围绕多探针数据集的构造将将WIFI终端数据预处理流程划分为探针探测数据集解析、探针探测数据时间帧编号、面向室内人员定位的探针数据构造等三个阶段,并设计了相关预处理任务的流程并进行了实现。实验结果表明,以预处理后的数据为输入,基于BP神经网络的判别器可以以很高的准确率判别WIFI终端是否在指定的区域内,依据多探针同时感知到的同一WIFI终端的RSSI值辨识WIFI终端是否在指定区域内是可行的。

Photocatalytic Treatment of Microcystin-LR-Containing Wastewater Using Pt/WO ₃Nanoparticles under Simulated Solar Light

This study investigates the photocatalytic degradation of microcystin-LR (MC-LR) under simulated solar light using Pt modified nano-sized tungsten trioxides (Pt/WO3). Photocatalytic activity was higher during the degradation of MC-LR with Pt/WO 3 than with pure WO 3 or Ti O2 . The catalyst loading greatly affect the degradation performance. The rate of degradation is influenced by the initial pH of the reaction solution. This study also investigates the photocatalytic inactivation of cyanobacteria. The results show that the algal growth was successfully controlled by the Pt/W O 3 . This study suggests Pt/W O 3 photocatalytic oxidation with solar light is a promising treatment for water containing MC-LR.

A study on marine industry and environment of China: regarding Japan's experience

China is facing the challenge of many marine environment problems with rapid economic growth. Japan had experienced similar marine environmental pressure during its industrialization and had been facing the problem through successful environment policy step by step. The paper reviews the lessons and experiences of Japan’s marine environment protection and analyzes the marine environment pollution in China and its causes, taking Shandong province as a case, such as GDP-oriented economic growth, heavy coal assumption, etc. The paper also analyzes the marine industry with focuses on coastal tourism and its relationship with marine environment. Suggestions on polices are provided based on the analysis on China’ marine environment and Japan’s experience.

Enhanced Biohydrogen Production by Accelerating the Hydrolysis of Macromolecular Components of Waste Activated Sludge Using TiO₂Photocatalysis as a Pretreatment

The effects of TiO2 photocatalysis on the hydrolysis of protein of waste activated sludge (WAS) and its biodegradability were investigated in this study. After 12-h UV irradiation, the removal ratio of protein by TiO2 photocatalysis reached 98.1%. The optimal condition for photocatalytic degradation of protein is TiO2 dosage of 5.0 mg·L–1 under 2.4 w·m–2 UV light irradiation. TiO2 photocatalysis in comparison with other pretreatments obviously accelerated the hydrolysis of WAS and improved the conversion of total COD (tCOD) to soluble COD (sCOD). The sCOD/tCOD ratio of WAS pretreated by TiO2 photocatalysis, UV photolysis and TiO2 adsorption and that of the control were 92.8%, 32.5%, 18.0% and 16.6%, respectively. TiO2 photocatalytic pretreatment accelerated the biohydrogen production from 10-fold diluted WAS. The bioreactors containing UV photolysis and TiO2 adsorption pretreated WASs and the control reactor require 0.5-d, 0.9-d and 0.7-d start-up period for biohydrogen production, respectively. While the bioreactor containing TiO2 photocatalysis pretreated WAS obtained a hydrogen yield of 0.5 mL-H2/g-VS merely after 0.5-d mesophilic fermentation. The cumulative biohydrogen production from TiO2 photocatalysis pretreated WAS during 4-d mesophilic fermentation reached 11.7 mL-H2/g-VS, which was 1.2 times higher than that from the control. TiO2 photocatalytic pretreatment enhanced the biohydrogen production from WAS via accelerating the hydrolysis of its macromolecular components to smaller molecule weight hydrolysates.

Efficient Electrochemical Removal of Ammonia with Various Cathodes and Ti/RuO₂-Pt Anode

Electrochemical oxidation of ammonia was studied with an objective to enhance the selectivity of ammonia to nitrogen gas and to remove the by-products in an undivided electrochemical cell, in which various cathodes and Ti/RuO 2-Pt anode were assembled. In the present study, anodic oxidation of ammonia and cathodic reduction of by-products were achieved, especially with Cu/Zn as cathode. In the presence of 1.0 g/L NaCl the ammonia-N decreased from 100.0 to 0 after 120 min electrolysis at current density of 30 mA/cm2, and no nitrite was detected in the treated solution. The lowest amount of nitrate was formed with Cu/Zn as cathode during electrolysis due to its high reduction ability. Initial pH range from 7 and 9 and uncontrolled temperature were favorable for electrochemical ammonia oxidation and the ammonia oxidation rates with Cu/Zn cathode was higher than that with Ti and Fe cathode. The reduction rate increased with increasing current density in the range of 5 - 50 mA/cm2. As ammonia could be completely removed by the simultaneous oxidation and reduction in this study, it is suitable for deep treatment of ammonia polluted water.

Electrochemical Degradation of Chlorsulfuron Herbicide from Water Solution Using Ti/IrO₂-Pt Anode

Chlorsulfuron (ChS) which is a nonbiodegradable herbicide was effectively removed using an electrochemical method at the Ti/IrO2-Pt anode. The influences of current density, initial ChS concentration, initial solution pH and different NaCl dosages on electrochemical degradation of ChS were investigated. HOCl formed during electrolysis and quickly generated .OH radicals would likely play an important role in the electrochemical degradation of ChS with the presence of NaCl. At current density of 20 mA?cm–2, ChS concentration decreased from 1 mg.L–1 to 0 mg.L–1 after 10 min electrolysis with 0.2 g?L–1 NaCl dosage. It was found that the ChS removal rate increased with increasing current density and the ChS degradation was similar at different initial pH values, which means that Ti/IrO2-Pt anode can be used in a wide pH range. The electrochemical performance of Ti/IrO2-Pt anode for degradation of ChS will not decrease after serviced for a long time. These results reveal that an electrochemical approach would be a novel treatment method for effective and rapid degradation of ChS herbicide from aqueous solution.

Unveiling the mechanisms of Fe(Ⅲ)-loaded chitosan composite(CTS-Fe)in enhancing anaerobic digestion of waste activated sludge

Anaerobic digestion(AD)of waste activated sludge(WAS)is usually limited by the low generation efficiency of methane.Fe(Ⅲ)-loaded chitosan composite(CTS-Fe)have been reported to effectively enhanced the digestion of WAS,but its role in promoting anaerobic sludge digestion remains unclear.In present study,the effects of CTS-Fe on the hydrolysis and methanogenesis stages of WAS anaerobic digestion were investigated.The addition of CTSFe increased methane production potential by 8%-23%under the tested conditions with the addition of 5-20 g/L CTS-Fe.Besides,the results demonstrate that the addition of CTS-Fe could effectively promote the hydrolysis of WAS,evidenced by lower protein or polysaccharides concentration,higher soluble organic carbon in rector adding CTS-Fe,as well as the increased activity of extracellular hydrolase with higher CTS-Fe concentration.Meanwhile,the enrichment of Clostridia abundance(iron-reducing bacteria(IRBs))was observed in CTS-Fe adding reactor(8.9%-13.8%),which was higher than that in the control reactor(7.9%).The observation further suggesting the acceleration of hydrolysis through dissimilatory iron reduction(DIR)process,thus providing abundant substrates for methanogenesis.However,the presence of CTS-Fe was inhibited the acetoclastic and hydrogenotrophic methanogenesis process,which could be ascribed to the Fe(Ⅲ)act as electron acceptor coupled to methane for anaerobic oxidation.Furthermore,coenzyme F420 activity in the CTS-Fe added reactor was 34.9% lower than in the blank,also abundance of microorganisms involved in hydrogenotrophic methanogenesis was decreased.Results from this study could provide theoretical support for the practical applications of CTS-Fe.

室内Wi-Fi异步效应下CSI定位误差界估计方法

与传统的基于接收信号强度(received signal strength, RSS)的室内Wi-Fi定位方法相比,信道状态信息(channel state information, CSI)包含了信号传输过程中更细粒度和更多样化的物理层信息(如信道中各个子载波的振幅和相位信息),故基于CSI的室内Wi-Fi定位方法通常具有更高的定位精度.在利用CSI进行定位时,发送端采用正交频分复用(orthogonal frequency division multiplexing,OFDM)技术在多个正交子载波上并行发送数据并在接收端进行解调,但由于异步效应(如载波频率偏差(carrier frequency offset, CFO)、采样时钟频率偏差(sampling frequency offset, SFO)和符号定时偏差(symbol timing offset, STO))的存在,接收端子载波的正交性难以得到保证,于是,基于CSI的室内Wi-Fi定位方法的性能会因为符号间干扰(inter symbol interference, ISI)和载波间干扰(inter carrier interference, ICI)的影响而下降.对此,本文从频域的角度推导了不同异步效应下的CSI定位误差界以评估基于CSI的室内Wi-Fi定位性能.

Observation of chemical components of PM2.5 and secondary inorganic aerosol formation during haze and sandy haze days in Zhengzhou, China

Mineral dust particles play an important role in the formation of secondary inorganic aerosols, which largely contribute to haze pollution in China.During this study, a haze episode(haze days) and a typical haze process mixed with sandstorm(sandy haze days)were observed in Zhengzhou with a series of high-time-resolution monitoring instruments from November 22 to December 8, 2018.Concentrations of PM10 and crustal elements clearly increased in the sandy haze days.Concentrations of gaseous pollutants, metallic elements emitted from anthropogenic sources, nitrate, and ammonium during sandy haze days were slightly lower than those during the haze days but still obviously higher than those during the non-haze days.The sulfate concentrations, the sulfate fractions in PM2.5,and the sulfur oxidation ratios significantly increased in the sandy haze days.Heterogeneous reactions dominated the conversion of SO2 during the haze and sandy haze days.Enhanced SO2 conversion during the sandy haze days may be attributed to the high concentrations of transition metal ions from the sandstorm when the values of relative humidity(RH) were in 30%–70%, and high O3 at certain time points.Gas-phase NO2 oxidation reactions were the main pathways for nitrate formation.In the sandy haze days,higher nitrogen oxidation ratio(NOR) at daytime may be associated with higher RH and lower temperature than those in the haze days, which facilitate the gas-to-particle partitioning of nitrate;higher NOR values at night may be attributed to the higher O3 concentrations, which promoted the formation of N2O5.

Removal of veterinary antibiotics from anaerobically digested swine wastewater using an intermittently aerated sequencing batch reactor

A lab-scale intermittently aerated sequencing batch reactor（IASBR）was applied to treat anaerobically digested swine wastewater（ADSW）to explore the removal characteristics of veterinary antibiotics.The removal rates of 11 veterinary antibiotics in the reactor were investigated under different chemical organic demand（COD）volumetric loadings,solid retention times（SRT）and ratios of COD to total nitrogen（TN）or COD/TN.Both sludge sorption and biodegradation were found to be the major contributors to the removal of veterinary antibiotics.Mass balance analysis revealed that greater than 60%of antibiotics in the influent were biodegraded in the IASBR,whereas averagely 24%were adsorbed by sludge under the condition that sludge sorption gradually reached its equilibrium.Results showed that the removal of antibiotics was greatly influenced by chemical oxygen demand（COD）volumetric loadings,which could achieve up to 85.1%±1.4%at 0.17±0.041 kg COD/m-3/day,while dropped to 75.9%±1.3%and 49.3%±12.1%when COD volumetric loading increased to 0.65±0.032 and1.07±0.073 kg COD/m-3/day,respectively.Tetracyclines,the dominant antibiotics in ADSW,were removed by 87.9%in total at the lowest COD loading,of which 30.4%were contributed by sludge sorption and 57.5%by biodegradation,respectively.In contrast,sulfonamides were removed about 96.2%,almost by biodegradation.Long SRT seemed to have little obvious impact on antibiotics removal,while a shorter SRT of 30–40 day could reduce the accumulated amount of antibiotics and the balanced antibiotics sorption capacity of sludge.Influent COD/TN ratio was found not a key impact factor for veterinary antibiotics removal in this work.

Microstructural Evolution of Rapidly Solidified ZK60 Powders during Extrusion

The microstructural evolution of rapidly solidified（RS） ZK60 powders extruded at 250 C was investigated.It was shown that formation of new ultrafine grains took place through continuous dynamic recrystallization（CDRX）,accompanied by the perfect bonding of powders via severe plastic deformation.At a low strain level,a well-defined structure made up of equiaxed and elongated subgrains was developed.Simultaneously,the operation of basal and non-basal dislocation slip led to the formation of low-angle dislocation cells（LADC） within the elongated subgrains.With increasing strain,the number and average misorientation of LADC increased,resulting in fragmentation of original elongation subgrains into a finally homogeneous fine-grained structure.Almost full-recrystallized structure with an average grain size of 0.4 μm was finally evolved after large cumulative strain.The results suggested that structural change was connected with thermal strain,where dislocation activities dominated this process.

PM2.5-related health impacts of utilizing ammonia-hydrogen energy in Kanto Region, Japan

Ammonia has emerged as a promising hydrogen carrier with applications as an energy source in recent years. However, in addition to being toxic, gaseous ammonia is a precursor of secondary inorganic aerosols. The concentration of ambient fine particulate matter （PM2.5） is intrinsically connected to public health. In this study, PM2.5-related health impacts of utilizing ammonia-hydrogen energy in Kanto Region, Japan, were investigated. It was assumed that 20% of the electricity consumption in Kanto Region, the most populated area in Japan, was supplied by mnmonia-hydrogen energy. The PM2.5 resulted from incomplete ammonia decomposition was simulated by a chemical transport model： ADMER-PRO （modified version）. Based on the incremental PM2.5 concentration, health impacts on the elderly （individuals over 65 years old） were quantitatively evaluated. The ammonia emission in this scenario increased PM2 s by 11.7% （0.16 μg·m-3.y-1） in winter and 3.5% （0.08 μg · m-3.y-1） in summer, resulting in 351 premature deaths per year. This study suggests that cost- effective emissions control or treatment and appropriate land planning should be considered to reduce the associated health impacts of this type of energy generation. In addition, further in-depth research, including cost-benefit analysis and security standards, is needed.