A novel Bi2S3 microsphere was fabricated through one-pot urea-assisted solvothermal method.The synthesized Bi2S3 microsphere was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),Fourier transf...A novel Bi2S3 microsphere was fabricated through one-pot urea-assisted solvothermal method.The synthesized Bi2S3 microsphere was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),Fourier transformed infrared spectroscopy(FT-IR)and thermal gravimetric analysis and differential thermal analysis(DTA-TG).Subsequently,the photocatalytic performances of Bi2S3 microsphere were evaluated by photocatalytic degradation of methyl orange(MO)simulation solution under visible-light irradiation.The results show that,Bi2S3 microsphere could be used as a potential cost-efficient catalysis for eliminating of methyl orange from aqueous solutions,whose degradation rate could reach 91.07%within 180 min.Besides,a tentative photocatalytic reaction mechanism was discussed according to the energy band position.Therefore,this work indicated a simplistic approach for the fabrication of visible-light responsive Bi2S3 microsphere photocatalyst,which can be used as a valuable candidate in solar energy conversion and environment pollution treatment.展开更多
We build a conceptual coupled model of the climate and tidal evolution of the Earth-Moon system to find the influence of the former on the latter. An energy balance model is applied to calculate steady-state temperatu...We build a conceptual coupled model of the climate and tidal evolution of the Earth-Moon system to find the influence of the former on the latter. An energy balance model is applied to calculate steady-state temperature field from the mean annual insolation as a function of varying astronomical parameters. A harmonic oscillator model is applied to integrate the lunar orbit and Earth’s rotation with the tidal torque dependent on the dominant natural frequency of ocean. An ocean geometry acts as a bridge between temperature and oceanic frequency. On assumptions of a fixed hemispherical continent and an equatorial circular lunar orbit, considering only the 41 kyr periodicity of Earth’s obliquity ε and the M2 tide, simulations are performed near tidal resonance for 106 yr. It is verified that the climate can influence the tidal evolution via ocean. Compared with the tidal evolution with constant ε, that with varying ε is slowed down;the EarthMoon distance oscillates in phase with ε before the resonance maximum but exactly out of phase after that;the displacement of the oscillation is in positive correlation with the difference between oceanic frequency and tidal frequency.展开更多
Within the framework of nonrelativistic-QCD factorization,we calculate both the next-to-leading-order relativistic and QCD corrections to prompt J/ψpair production,with feed-down fromψ(2S)mesons,via photon-photon co...Within the framework of nonrelativistic-QCD factorization,we calculate both the next-to-leading-order relativistic and QCD corrections to prompt J/ψpair production,with feed-down fromψ(2S)mesons,via photon-photon collisions at future e^(+)e^(−)colliders,including the Future Circular Lepton Collider(FCC-ee),the Circular Electron Positron Collider(CEPC),and the Compact Linear Collider(CLIC).We present total cross sections and distributions in single J/ψtransverse momentum and rapidity,as well as in J/ψpair invariant mass.The relativistic and QCD corrections both turn out to be large and negative.However,the production rates are large enough for useful experimental studies.展开更多
Pollutant transport in overland flow over surfaces with spatially varying microtopography,roughness,and infiltration was investigated using the diffusion wave equation and transport rate-based equation.The finite volu...Pollutant transport in overland flow over surfaces with spatially varying microtopography,roughness,and infiltration was investigated using the diffusion wave equation and transport rate-based equation.The finite volume method in space and an implicit backward difference scheme in time were employed in the numerical solution of the 2D governing equations.The developed model was first tested against an analytical solution and an experimental study involving overland flow and the associated pollutant transport,subsequently a series of numerical tests were carried out.Non-point source pollution was investigated under spatially varying microtopography,roughness,and infiltration.The simulation results showed that microtopography and roughness were the dominant factors causing significant spatial variations in solute concentration.When the spatially varying microtopography was replaced by a smooth surface,the result was an overestimation of the solute rate at the outlet of the upland.On the other hand,when the spatially varying roughness was replaced by the average roughness and spatially varying infiltration rate by the average infiltration rate,the pollutant discharge at the outlet of the upland was not significantly affected.The numerical results further showed that one cannot ignore the spatial variations of slope and roughness when investigating the local pollutant concentration distribution.展开更多
基金Projects(21476269,21776319) supported by the National Natural Science Foundation of ChinaProject(2016TP1007) supported by Hunan Provincial Science and Technology Plan Project of China+2 种基金Project(2017J01569) supported by the Natural Science Foundation of Fujian Province,ChinaProject(201710533255) supported by National College Students’ Free Exploration Project of ChinaProject(2017zzts777) supported by Fundamental Research Funds for the Central Universities of Central South University,China
文摘A novel Bi2S3 microsphere was fabricated through one-pot urea-assisted solvothermal method.The synthesized Bi2S3 microsphere was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),Fourier transformed infrared spectroscopy(FT-IR)and thermal gravimetric analysis and differential thermal analysis(DTA-TG).Subsequently,the photocatalytic performances of Bi2S3 microsphere were evaluated by photocatalytic degradation of methyl orange(MO)simulation solution under visible-light irradiation.The results show that,Bi2S3 microsphere could be used as a potential cost-efficient catalysis for eliminating of methyl orange from aqueous solutions,whose degradation rate could reach 91.07%within 180 min.Besides,a tentative photocatalytic reaction mechanism was discussed according to the energy band position.Therefore,this work indicated a simplistic approach for the fabrication of visible-light responsive Bi2S3 microsphere photocatalyst,which can be used as a valuable candidate in solar energy conversion and environment pollution treatment.
基金funded by the National Key Research and Development Program of China (2017YFC0305905)the Natural Science Foundation of Zhejiang Province (LR16E090001)NSFC-Zhejiang Joint Fund for the Integration of Industrialization and Informatization (U1709204)
文摘We build a conceptual coupled model of the climate and tidal evolution of the Earth-Moon system to find the influence of the former on the latter. An energy balance model is applied to calculate steady-state temperature field from the mean annual insolation as a function of varying astronomical parameters. A harmonic oscillator model is applied to integrate the lunar orbit and Earth’s rotation with the tidal torque dependent on the dominant natural frequency of ocean. An ocean geometry acts as a bridge between temperature and oceanic frequency. On assumptions of a fixed hemispherical continent and an equatorial circular lunar orbit, considering only the 41 kyr periodicity of Earth’s obliquity ε and the M2 tide, simulations are performed near tidal resonance for 106 yr. It is verified that the climate can influence the tidal evolution via ocean. Compared with the tidal evolution with constant ε, that with varying ε is slowed down;the EarthMoon distance oscillates in phase with ε before the resonance maximum but exactly out of phase after that;the displacement of the oscillation is in positive correlation with the difference between oceanic frequency and tidal frequency.
基金Supported in part by the German Research Foundation DFG through Research Unit FOR 2926"Next Generation Perturbative QCD for Hadron Structure:Preparing for the Electron-Ion Collider"(409651613)National Natural Science Foundation of China(12061131006)National Natural Science Foundation of China(U1832160,12075177)。
文摘Within the framework of nonrelativistic-QCD factorization,we calculate both the next-to-leading-order relativistic and QCD corrections to prompt J/ψpair production,with feed-down fromψ(2S)mesons,via photon-photon collisions at future e^(+)e^(−)colliders,including the Future Circular Lepton Collider(FCC-ee),the Circular Electron Positron Collider(CEPC),and the Compact Linear Collider(CLIC).We present total cross sections and distributions in single J/ψtransverse momentum and rapidity,as well as in J/ψpair invariant mass.The relativistic and QCD corrections both turn out to be large and negative.However,the production rates are large enough for useful experimental studies.
基金Project supported by the National Natural Science Foundation of China (No. 51009120)the Research Fund for the Doctoral Program of Higher Education of China (No. 20090101120065)the State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau of China (No. 10501-243)
文摘Pollutant transport in overland flow over surfaces with spatially varying microtopography,roughness,and infiltration was investigated using the diffusion wave equation and transport rate-based equation.The finite volume method in space and an implicit backward difference scheme in time were employed in the numerical solution of the 2D governing equations.The developed model was first tested against an analytical solution and an experimental study involving overland flow and the associated pollutant transport,subsequently a series of numerical tests were carried out.Non-point source pollution was investigated under spatially varying microtopography,roughness,and infiltration.The simulation results showed that microtopography and roughness were the dominant factors causing significant spatial variations in solute concentration.When the spatially varying microtopography was replaced by a smooth surface,the result was an overestimation of the solute rate at the outlet of the upland.On the other hand,when the spatially varying roughness was replaced by the average roughness and spatially varying infiltration rate by the average infiltration rate,the pollutant discharge at the outlet of the upland was not significantly affected.The numerical results further showed that one cannot ignore the spatial variations of slope and roughness when investigating the local pollutant concentration distribution.
基金supported by the Australian Research Council Linkage Projectsthe National Natural Science Foundation of China(Nos.51279180+4 种基金5107912751579221and 51179171)the National Basic Research Program(973 Program)of China(No.2013CB035901)the Public Welfare Technology Application Research Project of Zhejiang Province(No.2013C33043),China