The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coheren...The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coherent anti-stokes Raman scattering（CARS） to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes（VMs） in the ground state of nitrobenzene, which are located at 682 cm^-1（v1）, 854 cm^-1（v2）, 1006 cm^-1（v3）, and 1023 cm^-1（v4）,is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.展开更多
We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers （Tr-OFVn, n=1-4） employing steady-state absorption and emission spectroscopy, transient absorp...We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers （Tr-OFVn, n=1-4） employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligolners gradually enhance in company with the extension of π- conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing organic materials for two-photon applications.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21573094,11274142,11474131,11574112,and 51502109)the National Found for Fostering Talents of Basic Science,China(Grant No.J1103202)+1 种基金the Science Challenging Program(Grant No.JCKY2016212A501)China Scholarship Council(CSC) during a visit of Ning Sui(Grant No.201706175038) to MPIA is also acknowledged
文摘The energy dissipation mechanism of energetic materials（EMs） is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption（TA） spectroscopy and time-resolved coherent anti-stokes Raman scattering（CARS） to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes（VMs） in the ground state of nitrobenzene, which are located at 682 cm^-1（v1）, 854 cm^-1（v2）, 1006 cm^-1（v3）, and 1023 cm^-1（v4）,is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.
文摘We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers （Tr-OFVn, n=1-4） employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligolners gradually enhance in company with the extension of π- conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing organic materials for two-photon applications.
