Empirical decay relationship between ionic conductivity and porosity of garnet type inorganic solid-state electrolytes

Ionic conductivity is one of the crucial parameters for inorganic solid-state electrolytes.To explore the relationship between porosity and ionic conductivity,a series of Li_(6.4)Ga_(0.2)La_(3)Zr_(2)O_(12) garnet type solid-state electrolytes with different porosities were prepared via solid-state reaction.Based on the quantified data,an empirical decay relationship was summarized and discussed by means of mathematical model and dimensional analysis method.It suggests that open porosity causes ionic conductivity to decrease exponentially.The pre-exponential factor obeys the Arrhenius Law quite well with the activation energy of 0.23 eV,and the decay constant is averaged to be 2.62%.While the closed porosity causes ionic conductivity to decrease linearly.The slope and intercept of this linear pattern also obey the Arrhenius Law and the activation energies are 0.24 and 0.27 eV,respectively.Moreover,the total porosity is linearly dependent on the open porosity,and different sintering conditions will lead to different linear patterns with different slopes and intercepts.

Receiver Power Allocation and Transmitter Power Control Analysis for Multiple-Receiver Wireless Power Transfer Systems

As different power has its own receivers,this paper analyzes and designs a multiple-receiver wireless power transfer(WPT)system systematically.The equivalent circuit model of the system is established to analyze the key parameters including transmitter power,receiver power,transmission efficiency,and each receiver power allocation.A control circuit is proposed to achieve the maximum transmission efficiency and transmitter power control and arbitrary receiver power allocation ratios for different receivers.Through the proposed control circuit,receivers with different loads can allocate appropriate power according to its power demand,the transmitter power and system efficiency do not vary with the change of the number of receivers.Finally,this control circuit is validated using a 130-kHz WPT system with three receivers whose power received is 3:10:12,and the overall system efficiency can reach as high as 55.5%.