浮动基多机协调吊运系统的工作空间分析

At present,the cranes used at sea have several shortcomings in terms of flexibility,efficiency,and safety.Therefore,a floating multi-robot coordinated lifting system is proposed to fulfill the offshore lifting requirements.First,the structure of the lifting system is established according to the lifting task,the kinematic model of the system is developed by using the D–H coordinate transformation,and the dynamic model is developed based on rigid-body dynamics and hydrodynamics.Then,the static and dynamic workspace of the lifting system are analyzed,and the solving steps of the workspace are given by using the Monte–Carlo method.The effect of the load mass and the maximum allowable tension of the cable on the workspace is examined by simulation.Results show that the lifting system has limited carrying capacity and a data reference for selecting the structural parameters by analyzing the factors affecting the workspace.Findings provide a basis for further research on the optimal design of structural parameters and the determination of safe configurations of the lifting system.

U-Pb zircon ages and petrogeochemistry and tectonic implications of gabbro and granite in southwest Lahad Datu area of Sabah, Malaysia

The southwest Lahad Datu felsic rocks were previously thought to have formed in the late Triassic as part of the microcontinental crystalline basement.Based on U-Pb ages,geochemistry,and the Hfisotopes of zircon from the southeastern Sabah gabbro and granite,in this study,the tectonic properties of the Sabah area during the Triassic were investigated.The weighted average U-Pb zircon ages of the gabbro and granite samples were determined to be(230.9±2.5)Ma and(207.1±3.3)Ma,respectively.The granite had SiO_(2) contents of 66.54%-79.47%,low TiO_(2) contents of 0.08%-0.3%,Al_(2)O_(3) contents of 10.97%-16.22%,Na_(2)O contents of 5.91 %-6.39%,and low K_(2)O contents of 0.15%-0.65%.The chondrite-normalized rare earth element(REE) patterns exhibit light REE enrichment,with right-sloping curves.The primitive mantle-normalized trace element spider diagrams exhibit Th,U,La,Sr,and Zr enrichment and Nb,Ta,P and Ti depletions,i.e.,the geochemical characteristics of typical island arc igneous rocks.The tectonic discriminant diagram indicates that the granite is a volcanic arc granite.The Hf isotopic an alysis of gabbro zircon revealed that the zircons have ε_(Hf)(t)values of 12.08-16.24(mean of 14.32) and two-stage model ages(t_(DM2)) of 223-491 Ma(mean of 347 Ma).This indicates that the diagenetic magma of the gabbro was mainly derived from melting of newly formed crustal materials.The ophiolite in southeast Sabah has existed since the early Late Triassic.The crystalline basement granite in southeastern S abah was emplaced lasted from late Triassic to early Cretaceous.Based on previous studies and global plate reconstruction models,it is speculated that the southeastern Sabah granite may have been formed in an island arc setting,i.e.,where the oceanic crust of the Paleo-Tethys Ocean collided with the oceanic crust of the Panthalassa Ocean.

A Survey of Knowledge Graph Construction Using Machine Learning

Knowledge graph(KG)serves as a specialized semantic network that encapsulates intricate relationships among real-world entities within a structured framework.This framework facilitates a transformation in information retrieval,transitioning it from mere string matching to far more sophisticated entity matching.In this transformative process,the advancement of artificial intelligence and intelligent information services is invigorated.Meanwhile,the role ofmachine learningmethod in the construction of KG is important,and these techniques have already achieved initial success.This article embarks on a comprehensive journey through the last strides in the field of KG via machine learning.With a profound amalgamation of cutting-edge research in machine learning,this article undertakes a systematical exploration of KG construction methods in three distinct phases:entity learning,ontology learning,and knowledge reasoning.Especially,a meticulous dissection of machine learningdriven algorithms is conducted,spotlighting their contributions to critical facets such as entity extraction,relation extraction,entity linking,and link prediction.Moreover,this article also provides an analysis of the unresolved challenges and emerging trajectories that beckon within the expansive application of machine learning-fueled,large-scale KG construction.

The influence of organic sources and environments on source rock deposition during the periods of Cretaceous–Eocene and Oligocene–Miocene,northern Kalimantan

The sedimentary system of Kalimantan has undergone significant development since the Oligocene.Previous research have largely ignored the capacity of the Cretaceous–Eocene sediments to produce hydrocarbons,focusing instead primarily on the Oligocene–Miocene coal as the principal source rocks.Shales and coals from the outcrops in the northern margin of Kalimantan were analyzed with palynological and geochemical methods to characterize the palaeoenvironmental and palaeoecological differences between the Cretaceous–Eocene and the Oligocene–Miocene samples.The high proportion of Cheirolepidoaceae,Schizaeoisporites and Ephedripites in the pollen assemblage from the Cretaceous–Eocene outcrops reflects an arid tropical/subtropical climate.The relatively low abundances of gymnosperm-derived biomarkers including isopimarane,β-phyllocladane,β-kaurane,suggest the gymnosperm features in flora.High C_(27)/C_(29)ααα20R sterane ratios,(C_(19)–C_(29))tricyclic terpanes/C_(30)αβhopane and extremely low oleanane/C_(30)αβhopane,bicadinane T/C_(30)αβhopane,and diterpenoid abundance indicate that there was a dominance of algae relative to higher plants in the organic matter.The gymnosperm-derived biomarkers,including isopimarane,β-phyllocladane,β-kaurane,suggest that palaeovegetation during this period was dominated by gymnosperms.The saline and reducing conditions in the bathyal and abysmal sea,evidenced by rather low Pr/Ph and high Gammarerane index,are beneficial for the preservation of hydrogen-rich organic matter.It is presumed that the Cretaceous–Eocene shales had great hydrocarbon generation potential in the southern South China Sea.During the period of Oligocene to Miocene in the Zengmu Basin and the Baram-Sabah Basin,the climate changed to a dominant humid and warm condition,which is corroborated by abundant pollen of Florschuetzia and Magnastriatites hawardi.Low C_(27)/C_(29)ααα20R sterane ratios,(C_(19)–C_(29))tricyclic terpanes/C_(30)αβhopane,and high oleanane/C_(30)αβhopane,bicadinane T/C_(30)αβhopane suggest that the palaeovegetation was dominated by angiosperms including the mangrove plants.The extremely abundant higher plants provide ample terrigenous organic matter for the formation of coal-measures in delta facies.The low gammacerane index and high Pr/Ph indicate the fresh and sub-oxic water in delta-neriticabysmal faces,which is not beneficial for the accumulation of hydrogen-rich organic matter.Thus,the Oligocene–Miocene marine argillaceous rocks can be potential sources of natural gas.

The gradual subduction-collision evolution model of Proto-South China Sea and its control on oil and gas

This study involved outcrop,drilling,seismic,gravity,and magnetic data to systematically document the geological records of the subduction process of Proto-South China Sea(PSCS)and establish its evolution model.The results indicate that a series of arc-shaped ophiolite belts and calcalkaline magmatic rocks are developed in northern Borneo,both of which have the characteristics of gradually changing younger from west to east,and are direct signs of subduction and collision of PSCS.At the same time,the subduction of PSCS led to the formation of three accretion zones from the south to the north in Borneo,the Kuching belt,Sibu belt,and Miri belt.The sedimentary formation of northern Borneo is characterized by a three-layer structure,with the oceanic basement at the bottom,overlying the deep-sea flysch deposits of the Rajang–Crocker group,and the molasse sedimentary sequence that is dominated by river-delta and shallow marine facies at the top,recording the whole subduction–collision–orogeny process of PSCS.Further,seismic reflection and tomography also confirmed the subduction and collision of PSCS.Based on the geological records of the subduction and collision of PSCS,combined with the comprehensive analysis of segmented expansion and key tectonic events in the South China Sea,we establish the“gradual”subduction-collision evolution model of PSCS.During the late Eocene to middle Miocene,the Zengmu,Nansha,and Liyue–Palawan blocks were separated by West Baram Line and Balabac Fault,which collided with the Borneo block and Kagayan Ridge successively from the west to the east,forming several foreland basin systems,and PSCS subducted and closed from the west to the east.The subduction and extinction of PSCS controlled the oil and gas distribution pattern of southern South China Sea(SSCS)mainly in three aspects.First,the“gradual”closure process of PSCS led to the continuous development of many large deltas in SSCS.Second,the deltas formed during the subduction–collision of PSCS controlled the development of source rocks in the basins of SSCS.Macroscopically,the distribution and scale of deltas controlled the distribution and scale of source rocks,forming two types of source rocks,namely,coal measures and terrestrial marine facies.Microscopically,the difference of terrestrial higher plants carried by the delta controlled the proportion of macerals of source rocks.Third,the difference of source rocks mainly controlled the distribution pattern of oil and gas in SSCS.Meanwhile,the difference in the scale of source rocks mainly controlled the difference in the amount of oil and gas discoveries,resulting in a huge amount of oil and gas discoveries in the basin of SSCS.Meanwhile,the difference of macerals of source rocks mainly controlled the difference of oil and gas generation,forming the oil and gas distribution pattern of“nearshore oil and far-shore gas”.

春大豆雄性核不育基础群体构建与轮回选择育种技术

大豆ms1核不育轮回群体选择育种技术作为种质创新的方法在大豆新种质创新方面有着广泛的应用。大豆ms1核不育基因实现了大豆的开放授粉、基因聚集、积累,丰富了群体的遗传多样性。本文介绍了宁夏春大豆雄性核不育种质基因库基础群体的构建,大豆ms1核不育轮回选择育种技术及取得的效果。大豆种质基因库基础群体及轮回选择技术为宁夏春大豆新品种选育奠定了的基础。

热塑性聚氨酯发泡片材和发泡珠粒成形体的形貌与力学性能的关系

通过不同的发泡工艺和成型工艺制备了密度相近的热塑性聚氨酯发泡片材(TPU-FS)和发泡珠粒成形体(ETPU)材料,研究了2种泡沫材料的形貌与力学性能的关系。通过扫描电镜表征了2种聚氨酯泡沫的结构;利用万能试验机研究了二者的单向压缩性能和循环压缩性能;用旋转流变仪表征了材料在不同压力下的流变性能。研究发现,相近密度下,TPU-FS和ETPU泡沫具有相近的泡孔面积占有率,但是ETPU发泡区域泡孔的平均孔径远大于TPU-FS泡沫;在循环压缩试验中,TPU-FS泡沫具有较高的损耗能和损耗百分比;流变实验中,在不同压力时,ETPU泡沫的储能模量和损耗模量均低于TPU-FS泡沫,且阻尼因子(tanδ)较小,TPU-FS泡沫的tanδ有一定的频率依赖性,而ETPU泡沫的tanδ随频率的变化不明显。同时,对密度相近的TPU-FS泡沫和ETPU泡沫的形貌与损耗百分比的关系进行了初步探讨。

Suppression of tumorigenesis by human mesenchymal stem cells in a hepatoma model

人的间充质的干细胞(hMSCs ) 装家到肿瘤地点并且禁止肿瘤细胞的生长。很少对内在的分子的机制被知道连接 hMSCs 到肿瘤房间的指向的抑制。在这研究，我们从 hMSCs 用一个动物移植模型，一个合作文化系统和调节媒介在二根人的 hepatoma 房间线(H7402 和 HepG2 ) 上调查了 hMSCs 的效果。当 SCID 老鼠与 H7402 细胞和 Z3 hMSCs 的一个相等的数字被注射时，动物移植研究证明肿瘤形成的潜伏的时间被延长并且肿瘤尺寸更小。当 co 有教养时与 Z3 房间， H7402 细胞增殖减少了，增加的 apoptosis，和 Bcl-2 的表示， c-Myc，原子抗原(PCNA ) 和 survivin 低是的增殖的房间调整了。在有调节媒介的处理源于 Z3 hMSC 文化以后， H4702 房间出现了减少的形成殖民地的能力和减少的增长。Immunoblot 分析证明 beta-catenin， Bcl-2， c-Myc， PCNA 和 survivin 表示是在 H7402 和 HepG2 房间调整的 down。总起来说，我们的调查结果证明 hMSCs 禁止 H7402 和 HepG2 人的肝癌症房间线的恶意的显型，它包括增长，形成殖民地的能力和 oncogene 表示试管内和体内。而且，我们的研究提供表明小径的 Wnt 可以在调停 hMSC 的指向和肿瘤房间抑制有一个角色的证据。

江苏省区域突发环境事件风险评估工作存在的问题与建议

区域突发环境事件风险评估是摸清区域内突发环境事件风险底数,制定有针对性的整改措施的重要途径,有助于防控区域整体环境风险水平。江苏省区域突发环境事件风险评估工作在中国起步较早、体系较为健全,在先行先试的过程中遇到了一些困难和问题,如缺乏政策依据和有力抓手,各地对区域风险评估的目的认识不足,工作的基础和保障还不完备,评估质量有待提升等。针对上述问题,提出了完善配套政策、突出评估工作关键重点、强化能力提升等相关建议,以期为下一步重点解决的问题和重要举措的出台提供参考。

Growth and nutrient dynamics of Betula alnoides seedlings under exponential fertilization

Betula alnoides is a fast-growing hardwood species grown in large plantations in Southeast Asia and South China.Nitrogen requirements for producing robus seedlings,growth and nutrient dynamics were investigated using exponential fertilization treatments.Root collar diameter,height,dry mass and nutrient contents of seedlings increased exponentially in all fertilization treatments as time progressed.Moreover,with water soluble fertilizer（Plant Products plus microelements N–P2O5–K2O：20–20–20）,300 mg N seedling-1was adequate.Vector analysis revealed that P was the most responsive nutrient element followed by N and K.Dilutions of N and K were evident in the plants without N addition,which induced initial P sufficiency and then luxury consumption probably due to the antagonistic interaction between N and P.However deficiencies of N,P and K were mostly observed in al exponential regimes during the experiment because seedling growth rate exceeded nutrient uptake rate,inferring that further study on improving the nutrient uptake efficiency is needed.Analysis of relationships among nutrient supply,dry mass,N content and N concentration demonstrated that 100–400 mg N seedling-1induced sufficiency to luxury consumption of nitrogen without significant change in dry mass,and 400 mg N seedling-1is recommended to apply for nutrient loading of seedlings before outplanting.The findings will help improve seedling quality and enhance the production of robust seedlings for plantation forestry of this species.

56例多发性骨髓瘤患者自体外周血造血干细胞动员方案的临床分析

目的:旨在比较化疗联合粒细胞集落刺激因子(chemotherapy plus granulocyte cyte colony stimulating factor,G-CSF)与化疗联合G-CSF和粒巨噬细胞集落刺激因子(granulocyte-macrophage colony-stimulating factor,GM-CSF)方案对多发性骨髓瘤(multiple myeloma,MM)患者外周血造血干细胞(peripheral blood stem cell,PBSC)动员、采集及造血重建的影响。方法:回顾性分析56例2008年5月至2016年7月天津医科大学肿瘤医院血液科化疗联合G-CSF或化疗联合G-CSF和GM-CSF动员采集PBSC行自体外周血造血干细胞移植(autologous peripheral blood stem cell transplantation,APBSCT)的MM患者资料。分析患者年龄、性别、疾病类型、临床分期(DS、ISS、R-ISS分期系统)、既往治疗方案和周期数等因素对动员效果及移植后造血重建、发热和抗生素应用等的影响。结果:单因素分析发现女性、ISS分期Ⅲ期、R-ISS分期Ⅱ/Ⅲ期及化疗+G-CSF动员方案的患者采集效果较差(P<0.05)。年龄≤60岁或年龄>60岁、疾病类型、DS分期(Ⅰ+Ⅱ/Ⅲ)、动员前化疗次数(≤6次或>6次)、有无烷化剂治疗史、动员前疾病缓解状态部分缓解(partial response,PR)或完全缓解(complete response,CR)及确诊到动员间隔时间(≤18个月或>18个月)与采集获得的CD34+细胞数及采集成功率无相关性(P>0.05)。进一步多因素分析结果显示,化疗联合G-CSF和GM-CSF患者较化疗联和GCSF患者采集成功率较高(OR=12.009,95%CI:1.961～73.537),不同动员方案是影响干细胞采集结果的独立预后因素(P=0.007)。所有患者移植后均顺利获得造血重建,无移植相关性死亡。两项动员方案组的造血重建时间及回输后发热、抗生素使用情况差异均无统计学意义(P>0.05)。结论:化疗联合G-CSF和GM-CSF动员方案采集的成功率较高,而不良反应未见增加,该动员方案可作为MM患者外周血干细胞动员的一项较好选择。

Simulating the heartwood formation process of Erythrophleum fordii in South China

We studied the formation of heartwood in Ery- throphleumfordii Oliv., an endangered rosewood species, by cross-section analysis on 52 stumps aged 28-57 years and arbitrarily sampled from natural forests in South China. Width and area of heartwood were positively correlated with age and xylem width （XW）, and were independent of annual radial growth. The proportions of heartwood and sapwood areas were equal at about 40 years. The heartwood formation pro- cess was simulated by linear regression of age and XW.

Effects on antioxidant enzyme activities and osmolytes in Halocnemum strobilaceum under salt stress

The seedlings of Halocnermum strobilaceum were cultivated in 0.5% hoagland nutrient solution containing 0.0%, 0.9%, 2.7% and 5.4% of NaC1 as well as composite salt （Na^＋, Ca^2＋, K^＋, Si^4＋） for 20 days; all the contents are in weight ratio. Succulent level, inorganic ions （Na^＋, K^＋）, organics such as betaine, proline, malondialdehyde, and antioxidant enzyme activities including superoxide dismutase （SOD）, catalase （CAT）, peroxidase （POD）, betaine aldehyde dehydrogenase （BADH） were measured to reveal its salt tolerance mechanism. When the composite salt concentration reaches 5.4%, SOD activity level, and MDA content is five times the control group; when it reaches 2.7%, the succulent level of seedlings, and the content ofK＋ in roots is nearly two times the NaCl treatment; the dry weight is more than three times the control group; with the NaCl treatment, MDA is three times the contrast; when the salt concentration is 2.7%, POD reaches the maximum. Results indicate that Si^4＋, K^＋, and Ca^20 from composite salt in the roots of H. strobilaceum improved the water-holding capacity. The activities of antioxidant enzyme were raised by the accumulation ofproline and betaine, which increased the salt tolerance. The absorption of K^＋ promoted the high ratio of K^＋/Na^＋ and alleviated the damage of cell membranes of H. strobilaceum, which is associated with osmotic contents such as betaine and proline.

Effective short text classification via the fusion of hybrid features for IoT social data

Nowadays short texts can be widely found in various social data in relation to the 5G-enabled Internet of Things (IoT). Short text classification is a challenging task due to its sparsity and the lack of context. Previous studies mainly tackle these problems by enhancing the semantic information or the statistical information individually. However, the improvement achieved by a single type of information is limited, while fusing various information may help to improve the classification accuracy more effectively. To fuse various information for short text classification, this article proposes a feature fusion method that integrates the statistical feature and the comprehensive semantic feature together by using the weighting mechanism and deep learning models. In the proposed method, we apply Bidirectional Encoder Representations from Transformers (BERT) to generate word vectors on the sentence level automatically, and then obtain the statistical feature, the local semantic feature and the overall semantic feature using Term Frequency-Inverse Document Frequency (TF-IDF) weighting approach, Convolutional Neural Network (CNN) and Bidirectional Gate Recurrent Unit (BiGRU). Then, the fusion feature is accordingly obtained for classification. Experiments are conducted on five popular short text classification datasets and a 5G-enabled IoT social dataset and the results show that our proposed method effectively improves the classification performance.

Heartwood variations in mid-aged plantations of Erythrophleum fordii

Erythrophleum fordii Oliv.(Caesalpiniaceae)is a rosewood species naturally distributed in southeast Asia and south China,and the heartwood is commonly used for high-quality crafts and furniture.While there are differences in heartwood development among single trees with distinct social status,the relationship between heartwood development and growth performance remains unclear.This information is essential to improve plantation management for high-yield heartwood production.Forty dominant,intermediate and suppressed trees were sampled from E.fordii plantations aged in 32-35 years in Pingxiang City,Guangxi,China.Stem analysis was carried out to determine horizontal and vertical variations of heartwood and sapwood.Number of annual rings,diameter and area of heartwood and sapwood as well as ratios of heartwood diameter and area at breast height were all significantly influenced by the social status of trees in stands(P<0.05).In these mid-aged plantations,E.fordii stems developed heartwood once the xylem diameter reached 5-10 cm,and then heartwood diameter and area increased with increasing xylem diameter.Heartwood ring numbers,diameter and area as well as their ratios decreased with increasing height,while sapwood ring numbers and diameter were relatively constant within the section where heartwood occurred.Heartwood and sapwood diameters were equal at heights of approximately 6-m for dominant,5-m for intermediate and 3-m for suppressed trees.Dominant trees differed considerably from intermediate and suppressed trees in heartwood volume,while heartwood volume ratios were all below 30%,and near 90%in the stem section below 8-m height regardless of social status.Relationship analysis showed that DBH was the most important factor influencing heartwood in even-aged stands.The findings provide evidence for crop tree selection,thinning regimes and reasonable management of plantations of E.fordii.

A Novel Hidden Danger Prediction Method in CloudBased Intelligent Industrial Production Management Using Timeliness Managing Extreme Learning Machine

To prevent possible accidents,the study of data-driven analytics to predict hidden dangers in cloud service-based intelligent industrial production management has been the subject of increasing interest recently.A machine learning algorithm that uses timeliness managing extreme learning machine is utilized in this article to achieve the above prediction.Compared with traditional learning algorithms,extreme learning machine(ELM) exhibits high performance because of its unique feature of a high generalization capability at a fast learning speed.Timeliness managing ELM is proposed by incorporating timeliness management scheme into ELM.When using the timeliness managing ELM scheme to predict hidden dangers,newly incremental data could be added prior to the historical data to maximize the contribution of the newly incremental training data,because the incremental data may be able to contribute reasonable weights to represent the current production situation according to practical analysis of accidents in some industrial productions.Experimental results from a coal mine show that the use of timeliness managing ELM can improve the prediction accuracy of hidden dangers with better stability compared with other similar machine learning methods.

Analysis on Self-compatibility of Artificially Synthesized Brassica napus Lines from Different Cross Combinations

Brassica rapa cuhivars Qinghaidahuang and Menyuan small rape were used as female parents and separately interspecifically hybridized with Zhongchijie- lan to artificially synthesize a number of Brasica napus resources. Observation of meiosis, pollen fertility and pollen tube germination and analysis of self-compati- bility index of these artificial B. napus varieties were conducted. Results showed that pollen mother cells of artificial B. napus lines from two cross combinations all had normal chromosome behavior and high pollen fertility, but the selfing seed-setting and self-compatibility index varied extremely significantly; B. napus lines from cross combination Qinghaidahuang x Zhongchijidan are highly self-compatible, while B. napus lines from cross combination Menyuan small rape x Zhongchijielan are highly self-incompatible. This study analyzed the heredity laws of self-incompatibility trait in artificially synthesized lines and discussed applica- tion prospects of artificially synthesized self-incompatible B. napus lines in rapeseed production.

Effects of dual antiplatelet therapy de-escalation on the prognosis of acute coronary syndrome patients at high risk of ischemia who underwent percutaneous coronary intervention

To the Editor:Current guidelines recommend that for patients with acute coronary syndrome(ACS)undergoing percutaneous coronary intervention(PCI),dual antiplatelet therapy(DAPT),preferably involving powerful P2Y_(12) receptor inhibitors,including ticagrelor or prasugrel,should be used for at least 12 months.^([1–3])However,there is a lack of relevant evidence regarding the feasibility of de-escalation treatment and specific DAPT treatment regimens for ACS patient populations with high ischemic risk.

High-entropy(Sm_(0.2)Eu_(0.2)Gd_(0.2)Dy_(0.2)Er_(0.2))_(2)Hf_(2)O_(7) ceramic with superb resistance to radiation-induced amorphization

Nuclear engineering materials are required to possess outstanding extreme environmental tolerance and irradiation resistance.A promising novel pyrochlore-type of(Sm_(0.2)Eu_(0.2)Gd_(0.2)Dy_(0.2)Er_(0.2))2 Hf_(2)O_(7)high-entropy ceramic(HE-RE2 Hf_(2)O_(7))for control rod was prepared by solid-state reaction method.The ion irradiation of HE-RE_(2) Hf_(2)O_(7)with 400 keV Kr+at 400℃was investigated using a 400 kV ion implanter and compared with single-component pyrochlore Gd2 Hf_(2)O_(7)to evaluate the irradiation resistance.For HE-RE2 Hf_(2)O_(7),the phase transition from pyrochlore to defective fluorite is revealed after irradiation at 60 dpa.After irradiation at 120 dpa,it maintained crystalline,which is comparable to Gd2 Hf_(2)O_(7)but superior to the titanate pyrochlores previously studied.Moreover,the lattice expansion of HE-RE2 Hf_(2)O_(7)(_(0.2)2%)is much lower than that of Gd2 Hf_(2)O_(7)(0.62%),indicating excellent irradiation damage resistance.Nanoindentation tests displayed an irradiation-induced increase in hardness and a decrease in elastic modulus by about 2.6%.Irradiation-induced segregation of elements is observed on the surface of irradiated samples.In addition,HE-RE2 Hf_(2)O_(7)demonstrates a more sluggish grain growth rate than Gd2 Hf_(2)O_(7)at 1200℃,suggesting better high-temperature stability.The linear thermal expansion coefficient of HE-RE2 Hf_(2)O_(7)is 10.7×10-6 K-1 at 298–1273 K.In general,it provides a new strategy for the design of the next advanced nuclear engineering materials.

Deep eutectic solvent-based gel electrolytes for flexible electrochromic devices with excellent high/low temperature durability

With the increasing interest in the application of electrochromism to flexible and wearable electronics in recent years,flexible electrochromic devices(ECDs)that can function at extreme temperatures are required.However,the functionalities of flexible ECDs are severely hampered by the inadequate choice of electrolytes,which might ultimately result in performance fading during low-and high-temperature operations.Here,we develop a deep eutectic solvent(DES)-based gel electrolyte that can maintain its optical,electrical,and mechanical properties over a wide range of temperatures(-40 to 150℃),exhibiting an extremely high visible-range transmittance over 90%,ion conductivity of 0.63 mS cm^(-1),and fracture strain exceeding 2000%.Owing to the excellent processability of the DES-based electrolytes,provided by dynamic interactions such as the lithium and hydrogen bonding between the DES and polymer matrix,a directly written patterning in ECDs is realized for the first time.The fabricated ECDs exhibit an excellent electrochromic behavior superior to the behavior of the ECDs fabricated with traditional gel electrolytes.The introduction of such DES-based electrolytes is expected to pave the way for a widespread application of electrochromic products.