Water jet technology is widely used in submerged buried pipes as a non-traditional trenching process,often invol-ving a complex sediment response.An important adjustable and influential engineering variable in this tec...Water jet technology is widely used in submerged buried pipes as a non-traditional trenching process,often invol-ving a complex sediment response.An important adjustable and influential engineering variable in this technol-ogy is represented by the impinging distance.In this study,the FLOW-3D software was used to simulate the jet scouring of sand beds in a submerged environment.In particular,four sets of experimental conditions were con-sidered to discern the relationship between the maximum scour depth and mass and the impinging distance.As shown by the results,a critical impinging distance h0 exists by which the static scour depth can be maximized;the scour mass ratio between dynamic and static conditions decreases as the impinging distance increases.Moreover,the profile contours are similar when the erosion parameter Ec is in the range 0.35<Ec<2.Empirical equations applicable for predicting the jet trenching contour under both dynamic and static scour modes are also provided in this study.展开更多
Scouring experiments were conducted using a three-dimensional laser scanning technology for angles of the jet spanning the interval from 0°to 30°,and the characteristics of the scour hole in equilibrium cond...Scouring experiments were conducted using a three-dimensional laser scanning technology for angles of the jet spanning the interval from 0°to 30°,and the characteristics of the scour hole in equilibrium conditions were investigated accordingly.The results indicate that the optimal scouring effects occur when the jet angle is in the ranges between 15°and 20°.Moreover,the dimensionless profiles of the scour hole exhibit a high degree of similarity at different jet angles.Numerical simulations conducted using the Flow-3D software to investigate the bed shear stress along the jet impingement surface have shown that this stress is influenced by both the resultant force and the jet impingement surface area.It reaches its maximum value when the jet is vertical,decreases rapidly as the jet starts to tilt,then increases slightly,and decreases again significantly when the angle exceeds 20°.展开更多
Refractory high-entropy alloys(RHEAs)have promising applications as the new generation of hightemperature alloys in hypersonic vehicles,aero-engines,gas turbines,and nuclear power plants.This study focuses on the micr...Refractory high-entropy alloys(RHEAs)have promising applications as the new generation of hightemperature alloys in hypersonic vehicles,aero-engines,gas turbines,and nuclear power plants.This study focuses on the microstructures and mechanical properties of the NbMoTaW(HfN)_(x)(x=0,0.3,0.7,and 1.0)RHEAs.The alloys consist of multiple phases of body-centered cubic(BCC),hafnium nitride(HfN),or multicomponent nitride(MN)phases.As the x contents increase,the grain size becomes smaller,and the strength gradually increases.The compressive yield strengths of the NbMoTaWHfN RHEA at ambient temperature,1000,1400,and 1800℃ were found to be 1682,1192,792,and 288 MPa,respectively.The high-temperature strength of this alloy is an inspiring result that exceeds the high temperature and strength of most known alloys,including high-entropy alloys,refractory metals,and superalloys.The HfN phase has a significant effect on strengthening due to its high structural stability and sluggish grain coarsening,even at ultra-high temperatures.Its superior properties endow the NbMoTaWHfN RHEA with potential for a wide range of engineering applications at ultra-high temperatures.This work offers a strategy for the design of high-temperature alloys and proposes an ultra-high-temperature alloy with potential for future engineering applications.展开更多
Water jets are widely used in seabed scouring and desilting applications.In the present work,dedicated tests have been conducted using a jet scour model test platform and sand beds containing grains with different siz...Water jets are widely used in seabed scouring and desilting applications.In the present work,dedicated tests have been conducted using a jet scour model test platform and sand beds containing grains with different sizes.The FLOW-3D simulation software has also been used to tackle the problem form a numerical point of view.The boundary conditions of the simulation have been optimized to reduce the gap between the numerical results and the outcomes of the experimental tests.Scour area calculation has been based on a RNG k-εTurbulence model.Moreover,the FAVOR(Fractional Area Volume Obstacle Representation)technology has been selected for grid division to make the simulation results more accurate.Jet scours with inclination angles of 10–20°have been simulated.It has been found that jet scouring is greatly affected by the environmental water flow,that is,water flow can weaken the scouring capacity of the jets.展开更多
Mitogen-activated protein kinase (MAPK) cascades play important roles in regulating plant innate immune responses. In a genetic screen to search for mutants with constitutive defense responses, we identified multipl...Mitogen-activated protein kinase (MAPK) cascades play important roles in regulating plant innate immune responses. In a genetic screen to search for mutants with constitutive defense responses, we identified multiple alleles of mpk4 and mekkl that exhibit cell death and constitutive defense responses. Bimolecular fluorescence complemen- tation (BiFC) analysis showed that both MPK4 and MEKK1 interact with MKK1 and MKK2, two closely related MAPK kinases, mkkl and mkk2 single mutant plants do not have obvious mutant phenotypes. To test whether MKK1 and MKK2 function redundantly, mkkl mkk2 double mutants were generated. The mkkl mkk2 double mutant plants die at seedling stage and the seedling-lethality phenotype is temperature-dependent. Similar to the mpk4 and mekkl mutants, the mkkl mkk2 double mutant seedlings accumulate high levels of H202, display spontaneous cell death, constitutively express Pathogenesis Related (PR) genes and exhibit pathogen resistance. In addition, activation of MPK4 by fig22 is impaired in the mkkl mkk2 double mutants, suggesting that MKK1 and MKK2 function together with MPK4 and MEKK1 in a MAP kinase cascade to negatively regulate innate immune responses in plants.展开更多
As the agricultural internet of things(IoT)technology has evolved,smart agricultural robots needs to have both flexibility and adaptability when moving in complex field environments.In this paper,we propose the concep...As the agricultural internet of things(IoT)technology has evolved,smart agricultural robots needs to have both flexibility and adaptability when moving in complex field environments.In this paper,we propose the concept of a vision-based navigation system for the agricultural IoT and a binocular vision navigation algorithm for smart agricultural robots,which can fuse the edge contour and the height information of rows of crop in images to extract the navigation parameters.First,the speeded-up robust feature(SURF)extracting and matching algorithm is used to obtain featuring point pairs from the green crop row images observed by the binocular parallel vision system.Then the confidence density image is constructed by integrating the enhanced elevation image and the corresponding binarized crop row image,where the edge contour and the height information of crop row are fused to extract the navigation parameters(θ,d)based on the model of a smart agricultural robot.Finally,the five navigation network instruction sets are designed based on the navigation angleθand the lateral distance d,which represent the basic movements for a certain type of smart agricultural robot working in a field.Simulated experimental results in the laboratory show that the algorithm proposed in this study is effective with small turning errors and low standard deviations,and can provide a valuable reference for the further practical application of binocular vision navigation systems in smart agricultural robots in the agricultural IoT system.展开更多
To study on the significance and basis of acidolysis index to China marine gas hydrate exploring, since 2006, 111 samples derived from Leg 164 and 204 of the Ocean Drilling Program (ODP) were analyzed in the experim...To study on the significance and basis of acidolysis index to China marine gas hydrate exploring, since 2006, 111 samples derived from Leg 164 and 204 of the Ocean Drilling Program (ODP) were analyzed in the experiment center of China Petroleum Exploration Research Institute to obtain data on acidolysis hydrocarbon index and methane carbon isotopes by the gas chromatography (GC) of PE AutoSystem XL and isotope mass spectrometer (IRMS) of Finnigan MAT25 I. Through these, we study the reliability of the acidolysis method and characterize the gas hydrate potential. The results show that the acidolysis hydrocarbon index has a stable correspondence with the Gas Hydrate Stability Zone (GHSZ) in the ODE and that there are clear abnormal signs in shallow samples that might reliably reflect the existence of authigenic carbonate caused by hydrocarbon migration from bottom hydrate. We therefore propose that the ability to characterize the acidolysis hydrocarbon is crucial to submarine gas hydrate exploration in China.展开更多
To improve the separation capacity of uranium in aqueous solutions, 3R-MoS2 nanosheets were prepared with molten salt electro- lysis and further modified with polypyrrole (PPy) to synthesize a hybrid nanoadsorbent (PP...To improve the separation capacity of uranium in aqueous solutions, 3R-MoS2 nanosheets were prepared with molten salt electro- lysis and further modified with polypyrrole (PPy) to synthesize a hybrid nanoadsorbent (PPy/3R-MoS2). The preparation conditions of PPy/3R- MoS2 were investigated and the obtained nanosheets were characterized with scanning electron microscope (SEM), high resolution transmis- sion electron microscope (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectro- scopy (XPS). The results showed that PPy/3R-MoS2 exhibited enhanced adsorption capacity toward U(VI) compared to pure 3R-MoS2 and PPy;the maximum adsorption was 200.4 mg/g. The adsorption mechanism was elucidated with XPS and FTIR: (1) negatively charged PPy/3R-MoS2 nanosheets attracted by an electrostatic interaction;(2) exposed C, N, Mo, and S atoms complexed with U(VI) through co- ordination;(3) Mo in the complex partly reduced the adsorbed U(VI) to U(IV), which further regenerated the adsorption point and continu- ously adsorbed U(VI). The design of the PPy/3R-MoS2 composite with a high adsorption capacity and chemical stability provides a new direc- tion for the removal of radionuclide.展开更多
The effects of oblique submerged scouring jets on sand beds with various particle sizes have been studied experimentally.In particular,a total of 25 experiments have been carried out to explore the influences of the j...The effects of oblique submerged scouring jets on sand beds with various particle sizes have been studied experimentally.In particular,a total of 25 experiments have been carried out to explore the influences of the jet angle and application time on the considered submerged sand beds.Test results conducted with a specially-designed device have shown that the scouring efficiency attains a maximum when the inclination angle is in the range between 15°and 20°and then it decreases when the inclination angle becomes higher.展开更多
We report an efficient and economical way for mass production of large-scale graphene films with high quality and uniformity.By using the designed scrolled copper-graphite structure,a continuous graphene film with typ...We report an efficient and economical way for mass production of large-scale graphene films with high quality and uniformity.By using the designed scrolled copper-graphite structure,a continuous graphene film with typical area of 200×39 cm^2 could be obtained in 15 min,and the production rate of the graphene film and space utilization rate of the CVD reactor can reach 520 cm 2⋅min−1 and 0.38 cm−1⋅min−1,respectively.Our method provides a guidance for the industrial production of graphene films,and may also accelerate its large-scale applications.展开更多
1. Introduction The increasing global demand for sustainable energy sources and emerging environmental issues have pushed the development of energy conversion and storage technologies to the forefront of chemical rese...1. Introduction The increasing global demand for sustainable energy sources and emerging environmental issues have pushed the development of energy conversion and storage technologies to the forefront of chemical research [1,2]. In particular, electrochemical CO_(2) reduction(CO_(2) R) to value-added fuels and chemicals presents a feasible pathway for renewable energy storage and could help mitigate the ever-increasing CO_(2) emissions [3].展开更多
The fast slewing rate and wide band of the VLBI2010 Global Observing System(VGOS) telescopes are beneficial to procure more observations and to obtain VLBI reference points(RPs) of high precisions.Meanwhile, with the ...The fast slewing rate and wide band of the VLBI2010 Global Observing System(VGOS) telescopes are beneficial to procure more observations and to obtain VLBI reference points(RPs) of high precisions.Meanwhile, with the development of synchronous tracking of fixed targets on telescopes during the observing, the RPs also can be determined in near real time based on a frame defined by other techniques. These opportunities provide us a possibility to explore the high geodetic resolution of VGOS telescopes. We design a thermal variation in RP as true values, and schedule a synchronous session of VGOS and target point(TP) series observing. Then VGOS delays and TP series are simulated and solved via piecewise functions. The results show that the accuracy of vertical component of the RP could be determined at an accuracy of 0.5 ± 0.3 mm in an hour using TP series, whereas the vertical components of RP solved by using VGOS delay measurements have a greater uncertainty due to the random error in the simulated atmosphere and bad radio source sky coverage in a shorter time interval. Some details in the data processing and accuracy evaluation are also introduced.展开更多
The aim is collecting uranium from groundwater in which uranium mainly exists in negative species,the amidoxime-functionalized hydrothermal carbon(AO-HTC)was synthesized.From the results of N2 adsorption-desorption an...The aim is collecting uranium from groundwater in which uranium mainly exists in negative species,the amidoxime-functionalized hydrothermal carbon(AO-HTC)was synthesized.From the results of N2 adsorption-desorption and SEM,AO-HTC is a small spherical surface;FT-IR and Elemental analysis showed that the amidoxime group was successfully grafted onto the surface of the material;Zeta-potential measurement showed that the amino nitrogen atom is protonated in the oxime group.The optimum pH value of AO-HTC for uranium adsorption is 6.0,and the adsorption equilibrium is reached within 80 min,which is in accordance with the pseudo-second order adsorption kinetic model.The adsorption of uranium by AO-HTC accords with the Langmuir isotherm adsorption model,and the single-layer saturated adsorption capacity is 254.13mg·g^-1.The thermodynamic parameters calculated by the adsorption isotherm indicate that AO-HTC adsorption of uranium is a spontaneous endothermic chemical process and Carbonate ion,calcium ion and humic acid concentration have great influence on uranium adsorption.The experiments results show that AO-HTC has the potential to elimination of U(Ⅳ)from groundwater.展开更多
Rodent pests not only cause severe agricultural loss but also spread zoonotic pathogens to human beings.Antico-agulant rodenticides are widely used to decrease the population densities of rodents but often lead to the...Rodent pests not only cause severe agricultural loss but also spread zoonotic pathogens to human beings.Antico-agulant rodenticides are widely used to decrease the population densities of rodents but often lead to the spillover of ectoparasites becausefleas and ticks may gather on surviving rodents.Therefore,it is necessary to killfleas and ticks before culling rodents to minimize the risk of pathogen transmission.In this study,we used a mixture of ivermectin(an antiparasitic drug)and bromadiolone(an anticoagulant rodenticide)to control both rodent andflea/tick abundances.We found that in a laboratory test,0.01%ivermectin bait was not lethal for greater long-tailed hamsters after 7 days of treatment,while 0.1%ivermectin bait was lethal for approximately 33%of treated rodents.In afield test,bait containing 0.001%,0.005%,0.01%,and 0.05%ivermectin decreased the number offleas per vole of Brandt’s voles to 0.42,0.22,0.12,and 0.2,respectively,compared with 0.77 in the control group,indicating that 0.01%ivermectin bait performed best in removingfleas.In another laboratory test,bait containing a 0.01%ivermectin and 0.005%bromadiolone mixture caused the death of all voles within 6–14 days after the intake of the bait.In thefield test,the bait containing 0.01%ivermectin and 0.005%bromadiolone reduced the average number offleas per vole to 0.35,which was significantly lower than the 0.77 of the control group.Our results indicate that a 0.01%ivermectin and 0.005%bromadiolone mixture could be used to control both rodents andfleas to minimize the spillover risk of disease transmission when using traditional rodenticides.展开更多
Pest rodents pose a serious threat to island biodiversity.Fertility control could be an alternative approach to control the impact of rodents on these islands.In this study,we examined the antifertility effects of EP-...Pest rodents pose a serious threat to island biodiversity.Fertility control could be an alternative approach to control the impact of rodents on these islands.In this study,we examined the antifertility effects of EP-1 baits containing quinestrol(E)and levonorgestrel(P)using a dose of 50 ppm E and P at three different ratios(E:P ratio=1:2,1:1,and 2:1)on Pacific rats(Rattus exulans)in the Xisha Islands,Hainan,China.Compared to the control group,all animals in EP-1 treatment groups showed significantly decreased food intake and body weight.In treated males,there were obvious abnormalities in testis structure and a significant decrease of relative seminal vesicle weight,but no significant effect on relative uterine and ovarian weights(g kg-1 body weight),or ovarian structure in females.Adding 8%sucrose to the original 50-ppm baits(E:P ratio=1:1)significantly increased bait palatability for males and females.This dose induced uterine edema and abnormalities of ovarian structure in females but had no significant negative effect on the relative testis,epididymis,and seminal vesicle weights(g kg-1 body weight)or sperm density in males.In summary,50-ppm EP-1(1:1)baits have the potential to disrupt the fertility of females,and 8%sucrose addition to the EP-1 baits(E:P ratio=1:1)could improve bait palatability.This dose disrupted the testis structure in males.Future studies are needed to improve bait acceptance and assess the antifertility effects of EP-1(1:1)on Pacific rats in captive breeding trials and underfield conditions.展开更多
Depending on the production process,copper(Cu)foils can be classified into two types,i.e.,rolled copper(r-Cu)foils and electrolytic copper(e-Cu)foils.Owing to their high electrical conductivity and ductility at low co...Depending on the production process,copper(Cu)foils can be classified into two types,i.e.,rolled copper(r-Cu)foils and electrolytic copper(e-Cu)foils.Owing to their high electrical conductivity and ductility at low cost,e-Cu foils are employed extensively in modern industries and account for more than 98%of the Cu foil market share.However,industrial e-Cu foils have never been single-crystallized due to their high density of grain boundaries,various grain orientations and vast impurities originating from the electrochemical deposition process.Here,we report a methodology of transforming industrial e-Cu foils into single crystals by facet copy from a single-crystal template.Different facets of both low and high indices are successfully produced,and the thickness of the single crystal can reach 500μm.Crystallographic characterizations directly recognized the single-crystal copy process,confirming the complete assimilation impact from the template.The obtained single-crystal e-Cu foils exhibit remarkably improved ductility(elongation-to-fracture of 105%vs.25%),fatigue performance(the average numbers of cycles to failure of 1600 vs.200)and electrical property(electrical conductivity of 102.6%of the international annealed copper standard(IACS)vs.98.5%)than original ones.This work opens up a new avenue for the preparation of single-crystal e-Cu foils and may expand their applications in high-speed,flexible,and wearable devices.展开更多
基金supported by the Research on the Prediction Mechanism of Corrosion for High Strength Steel in Deep Sea Service Driven by Multi-Scale,High-Dimension and Small-Sample Data(C2301002635)Research on the Influence of Nozzle Structure on the Scouring Effect of Submerged Water Jet(2023R411045)+1 种基金the Zhejiang Ocean University Outstanding Master’s Thesis Cultivation Project(ZJOUYJS20230018)the Scientific Research Project of Zhejiang Graduate Education Society in 2022(2022-021)which was gained by Chen.
文摘Water jet technology is widely used in submerged buried pipes as a non-traditional trenching process,often invol-ving a complex sediment response.An important adjustable and influential engineering variable in this technol-ogy is represented by the impinging distance.In this study,the FLOW-3D software was used to simulate the jet scouring of sand beds in a submerged environment.In particular,four sets of experimental conditions were con-sidered to discern the relationship between the maximum scour depth and mass and the impinging distance.As shown by the results,a critical impinging distance h0 exists by which the static scour depth can be maximized;the scour mass ratio between dynamic and static conditions decreases as the impinging distance increases.Moreover,the profile contours are similar when the erosion parameter Ec is in the range 0.35<Ec<2.Empirical equations applicable for predicting the jet trenching contour under both dynamic and static scour modes are also provided in this study.
基金supported by Research on the Influence of Nozzle Structure on the Scouring Effect of Submerged Water Jet(2023R411045)Design and Control Strategy Research of PEM Fuel Cell Hybrid Propulsion System for Ships(2024R411015)+1 种基金Zhejiang Ocean University Outstanding Master’s Thesis Cultivation Project(ZJOUYJS20230018)General Program of Education Department of Zhejiang Province(Y202250817)which was gained by Chen.
文摘Scouring experiments were conducted using a three-dimensional laser scanning technology for angles of the jet spanning the interval from 0°to 30°,and the characteristics of the scour hole in equilibrium conditions were investigated accordingly.The results indicate that the optimal scouring effects occur when the jet angle is in the ranges between 15°and 20°.Moreover,the dimensionless profiles of the scour hole exhibit a high degree of similarity at different jet angles.Numerical simulations conducted using the Flow-3D software to investigate the bed shear stress along the jet impingement surface have shown that this stress is influenced by both the resultant force and the jet impingement surface area.It reaches its maximum value when the jet is vertical,decreases rapidly as the jet starts to tilt,then increases slightly,and decreases again significantly when the angle exceeds 20°.
基金supported by the National Key Research and Development Program of China(2023YFE0201600 and 2018YFC1902400)the National Natural Science Foundation of China(51975582)a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions。
文摘Refractory high-entropy alloys(RHEAs)have promising applications as the new generation of hightemperature alloys in hypersonic vehicles,aero-engines,gas turbines,and nuclear power plants.This study focuses on the microstructures and mechanical properties of the NbMoTaW(HfN)_(x)(x=0,0.3,0.7,and 1.0)RHEAs.The alloys consist of multiple phases of body-centered cubic(BCC),hafnium nitride(HfN),or multicomponent nitride(MN)phases.As the x contents increase,the grain size becomes smaller,and the strength gradually increases.The compressive yield strengths of the NbMoTaWHfN RHEA at ambient temperature,1000,1400,and 1800℃ were found to be 1682,1192,792,and 288 MPa,respectively.The high-temperature strength of this alloy is an inspiring result that exceeds the high temperature and strength of most known alloys,including high-entropy alloys,refractory metals,and superalloys.The HfN phase has a significant effect on strengthening due to its high structural stability and sluggish grain coarsening,even at ultra-high temperatures.Its superior properties endow the NbMoTaWHfN RHEA with potential for a wide range of engineering applications at ultra-high temperatures.This work offers a strategy for the design of high-temperature alloys and proposes an ultra-high-temperature alloy with potential for future engineering applications.
基金This work is supported by National Nature Fund of China(52071091)the Key Laboratory of Expressway Construction Machinery of Shanxi Province which is gained by Zhang(300102259512).
文摘Water jets are widely used in seabed scouring and desilting applications.In the present work,dedicated tests have been conducted using a jet scour model test platform and sand beds containing grains with different sizes.The FLOW-3D simulation software has also been used to tackle the problem form a numerical point of view.The boundary conditions of the simulation have been optimized to reduce the gap between the numerical results and the outcomes of the experimental tests.Scour area calculation has been based on a RNG k-εTurbulence model.Moreover,the FAVOR(Fractional Area Volume Obstacle Representation)technology has been selected for grid division to make the simulation results more accurate.Jet scours with inclination angles of 10–20°have been simulated.It has been found that jet scouring is greatly affected by the environmental water flow,that is,water flow can weaken the scouring capacity of the jets.
文摘Mitogen-activated protein kinase (MAPK) cascades play important roles in regulating plant innate immune responses. In a genetic screen to search for mutants with constitutive defense responses, we identified multiple alleles of mpk4 and mekkl that exhibit cell death and constitutive defense responses. Bimolecular fluorescence complemen- tation (BiFC) analysis showed that both MPK4 and MEKK1 interact with MKK1 and MKK2, two closely related MAPK kinases, mkkl and mkk2 single mutant plants do not have obvious mutant phenotypes. To test whether MKK1 and MKK2 function redundantly, mkkl mkk2 double mutants were generated. The mkkl mkk2 double mutant plants die at seedling stage and the seedling-lethality phenotype is temperature-dependent. Similar to the mpk4 and mekkl mutants, the mkkl mkk2 double mutant seedlings accumulate high levels of H202, display spontaneous cell death, constitutively express Pathogenesis Related (PR) genes and exhibit pathogen resistance. In addition, activation of MPK4 by fig22 is impaired in the mkkl mkk2 double mutants, suggesting that MKK1 and MKK2 function together with MPK4 and MEKK1 in a MAP kinase cascade to negatively regulate innate immune responses in plants.
基金the National Natural Science Foundationof China(No.31760345).
文摘As the agricultural internet of things(IoT)technology has evolved,smart agricultural robots needs to have both flexibility and adaptability when moving in complex field environments.In this paper,we propose the concept of a vision-based navigation system for the agricultural IoT and a binocular vision navigation algorithm for smart agricultural robots,which can fuse the edge contour and the height information of rows of crop in images to extract the navigation parameters.First,the speeded-up robust feature(SURF)extracting and matching algorithm is used to obtain featuring point pairs from the green crop row images observed by the binocular parallel vision system.Then the confidence density image is constructed by integrating the enhanced elevation image and the corresponding binarized crop row image,where the edge contour and the height information of crop row are fused to extract the navigation parameters(θ,d)based on the model of a smart agricultural robot.Finally,the five navigation network instruction sets are designed based on the navigation angleθand the lateral distance d,which represent the basic movements for a certain type of smart agricultural robot working in a field.Simulated experimental results in the laboratory show that the algorithm proposed in this study is effective with small turning errors and low standard deviations,and can provide a valuable reference for the further practical application of binocular vision navigation systems in smart agricultural robots in the agricultural IoT system.
基金support from the Fluid Geochemical Site Detection Technology of Gas Hydrate(2006AA09204)In-situ Detection Technology of Gas Hydrate(2006AA09205) and (2007AA09Z307)
文摘To study on the significance and basis of acidolysis index to China marine gas hydrate exploring, since 2006, 111 samples derived from Leg 164 and 204 of the Ocean Drilling Program (ODP) were analyzed in the experiment center of China Petroleum Exploration Research Institute to obtain data on acidolysis hydrocarbon index and methane carbon isotopes by the gas chromatography (GC) of PE AutoSystem XL and isotope mass spectrometer (IRMS) of Finnigan MAT25 I. Through these, we study the reliability of the acidolysis method and characterize the gas hydrate potential. The results show that the acidolysis hydrocarbon index has a stable correspondence with the Gas Hydrate Stability Zone (GHSZ) in the ODE and that there are clear abnormal signs in shallow samples that might reliably reflect the existence of authigenic carbonate caused by hydrocarbon migration from bottom hydrate. We therefore propose that the ability to characterize the acidolysis hydrocarbon is crucial to submarine gas hydrate exploration in China.
基金the National Nat-ural Science Foundation of China(Nos.21906019,21906018,21561002,21866004,and 21866003)the Sci-ence&Technology Support Program of Jiangxi Province,China(No.2018ACB21007)+1 种基金the Jiangxi Program of Aca-demic and Technical Leaders of Major Disciplines,China(No.20182BCB22011)the Project of the Jiangxi Provincial Department of Education,China(Nos.GJJ160550,GJJ180385,and GJJ180400).
文摘To improve the separation capacity of uranium in aqueous solutions, 3R-MoS2 nanosheets were prepared with molten salt electro- lysis and further modified with polypyrrole (PPy) to synthesize a hybrid nanoadsorbent (PPy/3R-MoS2). The preparation conditions of PPy/3R- MoS2 were investigated and the obtained nanosheets were characterized with scanning electron microscope (SEM), high resolution transmis- sion electron microscope (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectro- scopy (XPS). The results showed that PPy/3R-MoS2 exhibited enhanced adsorption capacity toward U(VI) compared to pure 3R-MoS2 and PPy;the maximum adsorption was 200.4 mg/g. The adsorption mechanism was elucidated with XPS and FTIR: (1) negatively charged PPy/3R-MoS2 nanosheets attracted by an electrostatic interaction;(2) exposed C, N, Mo, and S atoms complexed with U(VI) through co- ordination;(3) Mo in the complex partly reduced the adsorbed U(VI) to U(IV), which further regenerated the adsorption point and continu- ously adsorbed U(VI). The design of the PPy/3R-MoS2 composite with a high adsorption capacity and chemical stability provides a new direc- tion for the removal of radionuclide.
基金The paper was supported by National Nature Fund of China(52071091)the Key Laboratory of Expressway Construction Machinery of Shanxi Province which is gained by Zhang(300102259512).
文摘The effects of oblique submerged scouring jets on sand beds with various particle sizes have been studied experimentally.In particular,a total of 25 experiments have been carried out to explore the influences of the jet angle and application time on the considered submerged sand beds.Test results conducted with a specially-designed device have shown that the scouring efficiency attains a maximum when the inclination angle is in the range between 15°and 20°and then it decreases when the inclination angle becomes higher.
基金Supported by the Beijing Natural Science Foundation(Grant No.JQ19004)the Key R&D Program of Guangdong Province(Grant Nos.2019B010931001,2020B010189001,2018B010109009 and 2018B030327001)+9 种基金Bureau of Industry and Information Technology of Shenzhen(Graphene platform 201901161512)the National Natural Science Foundation of China(Grant Nos.51991340,51991342 and 51522201)the National Key R&D Program of China(Grant Nos.2016YFA0300903 and 2016YFA0300804)the Beijing Excellent Talents Training Support(Grant No.2017000026833ZK11)the Beijing Municipal Science&Technology Commission(Grant No.Z191100007219005)the Beijing Graphene Innovation Program(Z181100004818003)the Guangdong Innovative and Entrepreneurial Research Team Program(Grant No.2016ZT06D348)the Science,Technology and Innovation Commission of Shenzhen Municipality(Grant No.KYTDPT20181011104202253)the National Postdoctoral Program for Innovative Talents(Grant No.BX20190016)China Postdoctoral Science Foundation(Grant Nos.2019M660280 and 2019M660281).
文摘We report an efficient and economical way for mass production of large-scale graphene films with high quality and uniformity.By using the designed scrolled copper-graphite structure,a continuous graphene film with typical area of 200×39 cm^2 could be obtained in 15 min,and the production rate of the graphene film and space utilization rate of the CVD reactor can reach 520 cm 2⋅min−1 and 0.38 cm−1⋅min−1,respectively.Our method provides a guidance for the industrial production of graphene films,and may also accelerate its large-scale applications.
基金supported by the National Natural Science Foundation of China(Grants 21872039,22072030 and 52025023)the Science and Technology Commission of Shanghai Municipality(Grants 18JC1411700 and 19DZ2270100)+3 种基金the Key R&D Program of Guangdong Province(Grant 2020B010189001)funding support from the original personalized project of Fudan Universityfunding support from China Postdoctoral Science Foundation(2021M700810)。
文摘1. Introduction The increasing global demand for sustainable energy sources and emerging environmental issues have pushed the development of energy conversion and storage technologies to the forefront of chemical research [1,2]. In particular, electrochemical CO_(2) reduction(CO_(2) R) to value-added fuels and chemicals presents a feasible pathway for renewable energy storage and could help mitigate the ever-increasing CO_(2) emissions [3].
基金supported by National Natural Science Foundation of China (1703067)
文摘The fast slewing rate and wide band of the VLBI2010 Global Observing System(VGOS) telescopes are beneficial to procure more observations and to obtain VLBI reference points(RPs) of high precisions.Meanwhile, with the development of synchronous tracking of fixed targets on telescopes during the observing, the RPs also can be determined in near real time based on a frame defined by other techniques. These opportunities provide us a possibility to explore the high geodetic resolution of VGOS telescopes. We design a thermal variation in RP as true values, and schedule a synchronous session of VGOS and target point(TP) series observing. Then VGOS delays and TP series are simulated and solved via piecewise functions. The results show that the accuracy of vertical component of the RP could be determined at an accuracy of 0.5 ± 0.3 mm in an hour using TP series, whereas the vertical components of RP solved by using VGOS delay measurements have a greater uncertainty due to the random error in the simulated atmosphere and bad radio source sky coverage in a shorter time interval. Some details in the data processing and accuracy evaluation are also introduced.
基金This work was financially supported by the National Natural Science Foundation of China(21561002,21866004,21866003).
文摘The aim is collecting uranium from groundwater in which uranium mainly exists in negative species,the amidoxime-functionalized hydrothermal carbon(AO-HTC)was synthesized.From the results of N2 adsorption-desorption and SEM,AO-HTC is a small spherical surface;FT-IR and Elemental analysis showed that the amidoxime group was successfully grafted onto the surface of the material;Zeta-potential measurement showed that the amino nitrogen atom is protonated in the oxime group.The optimum pH value of AO-HTC for uranium adsorption is 6.0,and the adsorption equilibrium is reached within 80 min,which is in accordance with the pseudo-second order adsorption kinetic model.The adsorption of uranium by AO-HTC accords with the Langmuir isotherm adsorption model,and the single-layer saturated adsorption capacity is 254.13mg·g^-1.The thermodynamic parameters calculated by the adsorption isotherm indicate that AO-HTC adsorption of uranium is a spontaneous endothermic chemical process and Carbonate ion,calcium ion and humic acid concentration have great influence on uranium adsorption.The experiments results show that AO-HTC has the potential to elimination of U(Ⅳ)from groundwater.
基金We are grateful to the grant supported by Science and Technology Service Network Initiative of the Chinese Academy of Sciences(KFJ-STS-ZDTP-2021-002).
文摘Rodent pests not only cause severe agricultural loss but also spread zoonotic pathogens to human beings.Antico-agulant rodenticides are widely used to decrease the population densities of rodents but often lead to the spillover of ectoparasites becausefleas and ticks may gather on surviving rodents.Therefore,it is necessary to killfleas and ticks before culling rodents to minimize the risk of pathogen transmission.In this study,we used a mixture of ivermectin(an antiparasitic drug)and bromadiolone(an anticoagulant rodenticide)to control both rodent andflea/tick abundances.We found that in a laboratory test,0.01%ivermectin bait was not lethal for greater long-tailed hamsters after 7 days of treatment,while 0.1%ivermectin bait was lethal for approximately 33%of treated rodents.In afield test,bait containing 0.001%,0.005%,0.01%,and 0.05%ivermectin decreased the number offleas per vole of Brandt’s voles to 0.42,0.22,0.12,and 0.2,respectively,compared with 0.77 in the control group,indicating that 0.01%ivermectin bait performed best in removingfleas.In another laboratory test,bait containing a 0.01%ivermectin and 0.005%bromadiolone mixture caused the death of all voles within 6–14 days after the intake of the bait.In thefield test,the bait containing 0.01%ivermectin and 0.005%bromadiolone reduced the average number offleas per vole to 0.35,which was significantly lower than the 0.77 of the control group.Our results indicate that a 0.01%ivermectin and 0.005%bromadiolone mixture could be used to control both rodents andfleas to minimize the spillover risk of disease transmission when using traditional rodenticides.
基金The research was supported by the specific re-search fund of The Innovation Platform for Academicians of Hainan Province(YSPTZX202112)The State Key Laboratory of Integrated Management of Pest Insects and Rodents(Grant No.IPM2103)the 2022 PhD Launch Fund to Jing Liu(RC2200002593).
文摘Pest rodents pose a serious threat to island biodiversity.Fertility control could be an alternative approach to control the impact of rodents on these islands.In this study,we examined the antifertility effects of EP-1 baits containing quinestrol(E)and levonorgestrel(P)using a dose of 50 ppm E and P at three different ratios(E:P ratio=1:2,1:1,and 2:1)on Pacific rats(Rattus exulans)in the Xisha Islands,Hainan,China.Compared to the control group,all animals in EP-1 treatment groups showed significantly decreased food intake and body weight.In treated males,there were obvious abnormalities in testis structure and a significant decrease of relative seminal vesicle weight,but no significant effect on relative uterine and ovarian weights(g kg-1 body weight),or ovarian structure in females.Adding 8%sucrose to the original 50-ppm baits(E:P ratio=1:1)significantly increased bait palatability for males and females.This dose induced uterine edema and abnormalities of ovarian structure in females but had no significant negative effect on the relative testis,epididymis,and seminal vesicle weights(g kg-1 body weight)or sperm density in males.In summary,50-ppm EP-1(1:1)baits have the potential to disrupt the fertility of females,and 8%sucrose addition to the EP-1 baits(E:P ratio=1:1)could improve bait palatability.This dose disrupted the testis structure in males.Future studies are needed to improve bait acceptance and assess the antifertility effects of EP-1(1:1)on Pacific rats in captive breeding trials and underfield conditions.
基金financially supported by Guangdong Major Project of Basic and Applied Basic Research(No.2021B0301030002)the National Natural Science Foundation of China(No.52025023)the Key R&D Program of Guangdong Province(No.2020B010189001).
文摘Depending on the production process,copper(Cu)foils can be classified into two types,i.e.,rolled copper(r-Cu)foils and electrolytic copper(e-Cu)foils.Owing to their high electrical conductivity and ductility at low cost,e-Cu foils are employed extensively in modern industries and account for more than 98%of the Cu foil market share.However,industrial e-Cu foils have never been single-crystallized due to their high density of grain boundaries,various grain orientations and vast impurities originating from the electrochemical deposition process.Here,we report a methodology of transforming industrial e-Cu foils into single crystals by facet copy from a single-crystal template.Different facets of both low and high indices are successfully produced,and the thickness of the single crystal can reach 500μm.Crystallographic characterizations directly recognized the single-crystal copy process,confirming the complete assimilation impact from the template.The obtained single-crystal e-Cu foils exhibit remarkably improved ductility(elongation-to-fracture of 105%vs.25%),fatigue performance(the average numbers of cycles to failure of 1600 vs.200)and electrical property(electrical conductivity of 102.6%of the international annealed copper standard(IACS)vs.98.5%)than original ones.This work opens up a new avenue for the preparation of single-crystal e-Cu foils and may expand their applications in high-speed,flexible,and wearable devices.