1,3-Propanediol is a promising renewable resource produced by microbial production. It is mainly used in many synthetic reactions, particularly applied to the polymer synthesis and cosmetics industry. We described her...1,3-Propanediol is a promising renewable resource produced by microbial production. It is mainly used in many synthetic reactions, particularly applied to the polymer synthesis and cosmetics industry. We described here the isolation of strain ZH-1, which has the ability of high production with 1,3-propanediol, from Fenhe River in China. It was classified as a member of K. pneumoniae after the study of phenotypic, physio-logical, biochemical and phylogenetic (16S rDNA). The initial glycerol concentration, fermentation time and pH value of strain ZH-1 were determined to be 50 g·L<sup>-1</sup>, 36 h and 8.0. Under these conditions, the practical yield of 1,3-PD was 18.53 g·L<sup>-1</sup> and a molar yield (mol<sub>1,3-PD</sub> mol<sub>Glycerol</sub>-1</sup> of 1,3-propanediol to glycerol of 0.497. In addition, we found that for the strain ZH-1, the optimum grown pH was 9.0, so we can deter-mine that it is a new member of alkali-resistant strains.展开更多
The uplift of the Tibetan Plateau significantly affected the global climate system.However,the timing of its uplift and the formation of its vast expanse are poorly understood.The occurrence of two types of leucograni...The uplift of the Tibetan Plateau significantly affected the global climate system.However,the timing of its uplift and the formation of its vast expanse are poorly understood.The occurrence of two types of leucogranites(the two-mica leucogranites and garnet-bearing leucogranites) identified in the Ailaoshan-Red River(ASRR) shear zone suggests an extension event in the southeastern Tibetan Plateau.The age of these leucogranites could be used to constrain the timing of uplift and southeastward expansion of the plateau.Petrography,geochronology and geochemistry investigations,including Sr-Nd isotope analysis,were conducted on the two-mica leucogranites and garnet-bearing leucogranites from the ASRR shear zone.LA-ICP-MS zircon U-Pb dating indicates that these rocks were emplaced at ~27 Ma,implying that the Tibetan Plateau had already achieved maximum uplift prior to the late Oligocene.It subsequently started to expand southeastward as a result of crustal flow.Compared to classic metapelite-derived leucogranites from Himalaya,the two-mica leucogranites show high K_2 O/Na_2 O(1.31-1.92),low Rb/Sr,CaO,lower ^(87)Sr/^(86)Sr ratios(0.7089-0.7164) and higher ε_(Nd)(t)(-8.83 to-3.10).This whole-rock geochemical characteristics likely indicates a mixing source origin,composed predominantly of amphibolite with subordinated metapelite,which is also evidenced by ^(87)Sr/^(86)Sr vs.ε_(Nd)(t) diagram.However,The garnetbearing leucogranites with high SiO_2 contents(72.25-74.12 wt.%) have high initial ^(87)Sr/^(86)Sr ratios(0.7332-0.7535) and low ε_(Nd)(t)(-16.36 to 18.98),indicating that they are derived from the source comprised of metapelite and results of fluexed muscovite melting under lower crustal level,which is also evidenced by the Rb-Sr-Ba systematics.These leucogranites formed from partial melting of the thickened lower crust,which resulted in the formation of granitic melt that weakened the crust.The weakened crust aided the left-lateral strikeslip movement of the ASRR shear zone,triggering the escape of the Indochina terrane in the southeastern Tibetan Plateau during the late Oligocene.展开更多
A series of supported molybdenum phosphide catalysts were prepared by impregnation method. XRD, TG-DTG, XPS and BET were used to study the phase, compositions and surface areas of the prepared catalysts. A model react...A series of supported molybdenum phosphide catalysts were prepared by impregnation method. XRD, TG-DTG, XPS and BET were used to study the phase, compositions and surface areas of the prepared catalysts. A model reactant containing thiophene, pyridine and cyclohexene was used for the measurements of catalytic activities. The effect of reduction temperature on catalytic activities was investigated. The analysis results by XRD and BET are very different when the reduction temperature is changed from 400 to 900 ℃. MoP/γ-Al2O3 catalysts and CoMoP/γ-Al2O3 catalysts prepared at the reduction temperature of 500 ℃ are the most active ones.展开更多
The Early Cretaceous Houyaoyu granite porphyries are located in the south margin of the North China Craton. Field observations, petrography, geochronology, major and trace elemental and Sr-Nd isotopic compositions are...The Early Cretaceous Houyaoyu granite porphyries are located in the south margin of the North China Craton. Field observations, petrography, geochronology, major and trace elemental and Sr-Nd isotopic compositions are reported to elucidate the genesis of the Houyaoyu granite porphyries. SIMS zircon U-Pb analyses for the Houyaoyu granite porphyries yield two concordant ages of 133.2±2.3 (2σ) and 131±1.1 (2σ) Ma, respectively. Major and trace elemental compositions indicate that these porphyries are high-K I-type granites with high contents of SiO2, K20, Rb, U, Pb, low Nb, Ta, Ti, and P. Initial S:Sr/S6Sr ratios range from 0.708 3 to 0.709 7, and εNd(t) values range from -9.13 to -12.3, with corresponding two-stage depleted-mantie Nd model ages (T2DM) varying from 1.57 to 1.91 Ga. This suggests that the Houyaoyu granite porphyries were predominantly derived from ancient lower conti- nental crust, with minor involvement of mantie-derived components. On the basis of the tectonic evolution of the Qinling Orogen and geochemical characteristics of the Houyaoyu granite porphyries, it is proposed that they were formed in an extensional tectonic setting related to lithospheric destruction of the North China Craton, and produced Mo and Pb-Zn mineralization in East Qinling Orogen. KEY WORDS: East Qinling, granite porphyries, ancient lower continental crust, destruction of North China Craton.展开更多
FERONIA(FER)is a member of the Catharanthus roseus receptor-like kinase 1-like(CrRLK1L)protein subfamily,which participates in reproduction,abiotic stress,biotic stress,cell growth,hormone response,and other molecular...FERONIA(FER)is a member of the Catharanthus roseus receptor-like kinase 1-like(CrRLK1L)protein subfamily,which participates in reproduction,abiotic stress,biotic stress,cell growth,hormone response,and other molecular mecha-nisms of plants.However,the mechanism by which a single RLK is capable of mediating multiple signals and activat-ing multiple cellular responses remains unclear.Here,we summarize research progress revealing the spatial–temporal expression of FER,along with its co-receptors and ligands determined the function of FER signaling pathway in multiple organs.The specificity of the FER signaling pathway is proposed to operate under a four-layered mechanism:(1)Spatial–temporal expression of FER,co-receptors,and ligands specify diverse functions,(2)Specific ligands or ligand combinations trigger variable FER signaling pathways,(3)Diverse co-receptors confer diverse FER perception and response modes,and(4)Unique downstream components that modify FER signaling and responses.Moreover,the regulation mechanism of the signaling pathway-appears to depend on the interaction among the ligands,RLK receptors,co-receptors,and downstream components,which may be a general mechanism of RLKs to maintain signal specificity.This review will provide a insight into understanding the specificity determination of RLKs signaling in both model and horticultural crops.展开更多
文摘1,3-Propanediol is a promising renewable resource produced by microbial production. It is mainly used in many synthetic reactions, particularly applied to the polymer synthesis and cosmetics industry. We described here the isolation of strain ZH-1, which has the ability of high production with 1,3-propanediol, from Fenhe River in China. It was classified as a member of K. pneumoniae after the study of phenotypic, physio-logical, biochemical and phylogenetic (16S rDNA). The initial glycerol concentration, fermentation time and pH value of strain ZH-1 were determined to be 50 g·L<sup>-1</sup>, 36 h and 8.0. Under these conditions, the practical yield of 1,3-PD was 18.53 g·L<sup>-1</sup> and a molar yield (mol<sub>1,3-PD</sub> mol<sub>Glycerol</sub>-1</sup> of 1,3-propanediol to glycerol of 0.497. In addition, we found that for the strain ZH-1, the optimum grown pH was 9.0, so we can deter-mine that it is a new member of alkali-resistant strains.
基金supported by the National Natural Science Foundation of China(Grant No.41702084)the Yunnan Department of Science and Technology Application and Basic Research Project(Grant No.2017FD063)Geology Discipline Construction Project of Yunnan University(Grant No.C176210227)。
文摘The uplift of the Tibetan Plateau significantly affected the global climate system.However,the timing of its uplift and the formation of its vast expanse are poorly understood.The occurrence of two types of leucogranites(the two-mica leucogranites and garnet-bearing leucogranites) identified in the Ailaoshan-Red River(ASRR) shear zone suggests an extension event in the southeastern Tibetan Plateau.The age of these leucogranites could be used to constrain the timing of uplift and southeastward expansion of the plateau.Petrography,geochronology and geochemistry investigations,including Sr-Nd isotope analysis,were conducted on the two-mica leucogranites and garnet-bearing leucogranites from the ASRR shear zone.LA-ICP-MS zircon U-Pb dating indicates that these rocks were emplaced at ~27 Ma,implying that the Tibetan Plateau had already achieved maximum uplift prior to the late Oligocene.It subsequently started to expand southeastward as a result of crustal flow.Compared to classic metapelite-derived leucogranites from Himalaya,the two-mica leucogranites show high K_2 O/Na_2 O(1.31-1.92),low Rb/Sr,CaO,lower ^(87)Sr/^(86)Sr ratios(0.7089-0.7164) and higher ε_(Nd)(t)(-8.83 to-3.10).This whole-rock geochemical characteristics likely indicates a mixing source origin,composed predominantly of amphibolite with subordinated metapelite,which is also evidenced by ^(87)Sr/^(86)Sr vs.ε_(Nd)(t) diagram.However,The garnetbearing leucogranites with high SiO_2 contents(72.25-74.12 wt.%) have high initial ^(87)Sr/^(86)Sr ratios(0.7332-0.7535) and low ε_(Nd)(t)(-16.36 to 18.98),indicating that they are derived from the source comprised of metapelite and results of fluexed muscovite melting under lower crustal level,which is also evidenced by the Rb-Sr-Ba systematics.These leucogranites formed from partial melting of the thickened lower crust,which resulted in the formation of granitic melt that weakened the crust.The weakened crust aided the left-lateral strikeslip movement of the ASRR shear zone,triggering the escape of the Indochina terrane in the southeastern Tibetan Plateau during the late Oligocene.
文摘A series of supported molybdenum phosphide catalysts were prepared by impregnation method. XRD, TG-DTG, XPS and BET were used to study the phase, compositions and surface areas of the prepared catalysts. A model reactant containing thiophene, pyridine and cyclohexene was used for the measurements of catalytic activities. The effect of reduction temperature on catalytic activities was investigated. The analysis results by XRD and BET are very different when the reduction temperature is changed from 400 to 900 ℃. MoP/γ-Al2O3 catalysts and CoMoP/γ-Al2O3 catalysts prepared at the reduction temperature of 500 ℃ are the most active ones.
基金jointly supported by the National Key R&D Program of China (No. 2016YFC0600405)the National Natural Foundation of China (Nos. 41425011, 41262004)
文摘The Early Cretaceous Houyaoyu granite porphyries are located in the south margin of the North China Craton. Field observations, petrography, geochronology, major and trace elemental and Sr-Nd isotopic compositions are reported to elucidate the genesis of the Houyaoyu granite porphyries. SIMS zircon U-Pb analyses for the Houyaoyu granite porphyries yield two concordant ages of 133.2±2.3 (2σ) and 131±1.1 (2σ) Ma, respectively. Major and trace elemental compositions indicate that these porphyries are high-K I-type granites with high contents of SiO2, K20, Rb, U, Pb, low Nb, Ta, Ti, and P. Initial S:Sr/S6Sr ratios range from 0.708 3 to 0.709 7, and εNd(t) values range from -9.13 to -12.3, with corresponding two-stage depleted-mantie Nd model ages (T2DM) varying from 1.57 to 1.91 Ga. This suggests that the Houyaoyu granite porphyries were predominantly derived from ancient lower conti- nental crust, with minor involvement of mantie-derived components. On the basis of the tectonic evolution of the Qinling Orogen and geochemical characteristics of the Houyaoyu granite porphyries, it is proposed that they were formed in an extensional tectonic setting related to lithospheric destruction of the North China Craton, and produced Mo and Pb-Zn mineralization in East Qinling Orogen. KEY WORDS: East Qinling, granite porphyries, ancient lower continental crust, destruction of North China Craton.
基金Open access funding provided by Shanghai Jiao Tong University.This work was supported by the grants from Shanghai Natural Science Foundation(Grant Number:21ZR1429300/BS1500016)Shanghai Collaborative Innovation Center of Agri-Seeds(Grant Number:ZXWH2150201/001)Shanghai Jiao Tong University(Agri-X program,Grant Number:AF1500088/002)to Jiangbo Fan.
文摘FERONIA(FER)is a member of the Catharanthus roseus receptor-like kinase 1-like(CrRLK1L)protein subfamily,which participates in reproduction,abiotic stress,biotic stress,cell growth,hormone response,and other molecular mecha-nisms of plants.However,the mechanism by which a single RLK is capable of mediating multiple signals and activat-ing multiple cellular responses remains unclear.Here,we summarize research progress revealing the spatial–temporal expression of FER,along with its co-receptors and ligands determined the function of FER signaling pathway in multiple organs.The specificity of the FER signaling pathway is proposed to operate under a four-layered mechanism:(1)Spatial–temporal expression of FER,co-receptors,and ligands specify diverse functions,(2)Specific ligands or ligand combinations trigger variable FER signaling pathways,(3)Diverse co-receptors confer diverse FER perception and response modes,and(4)Unique downstream components that modify FER signaling and responses.Moreover,the regulation mechanism of the signaling pathway-appears to depend on the interaction among the ligands,RLK receptors,co-receptors,and downstream components,which may be a general mechanism of RLKs to maintain signal specificity.This review will provide a insight into understanding the specificity determination of RLKs signaling in both model and horticultural crops.